The distribution of sulfur in oceanic crust with respect to oxidative diagenesis (Table 1)

A detailed geochemical-petrological examination of layer 2 basalts recovered during Leg 37 of the DSDP has revealed that the original distribution, form and abundance of igneous sulfide have been profoundly altered during low-grade oxidative diagenesis. The net result appears to have been a rather pervasive remobilization of igneous sulfide to form secondary pyrite accompanied by a bulk loss of sulfur equivalent to about 50-60% of the original igneous value, assuming initial saturation. It is suggested that during infiltration of seawater into the massive crystalline rock, igneous sulfide has experienced pervasive oxidation, under conditions of limited oxidation potential, to form a series of unstable, soluble sulfur species, primarily in the form of SO3[2-] and S2O3[2-]. Spontaneous decomposition of these intermediate compounds through disproportionation has resulted in partial reconstitution of the sulfur as secondary pyrite and the generation of SO4[2-] ion, which, due to its kinetic stability, has been lost from the basalt system and ultimately transferred to the ocean. This model not only satisfies the geochemical and petrological observations but also provides a suitable explanation for the highly variable delta34S values which characterize secondary sulfides in deep ocean floor basalts.

Primary production at time series station DYFAMED

Phytoplankton carbon assimilation has been measured near monthly using the 14C method at DYFAMED France JGOFS time-series station from 1993 to 1999. Data were obtained using the "LET GO" technique, which allowed in situ injection of bicarbonate and incubation in enclosures at 10 depths. Incubation duration was 4 h around noon, from which daily production was estimated. The seasonal variation of the depth-integrated carbon assimilation exhibits a marked cycle. Maximum values reach 1.8 g C/m**2/d in March or April; constant lower values were observed from August to January, in the range 100-300 mg C/m**2/d. The annual primary production vary in the range 86-232 g C/m**2/yr, in the upper range of older estimations. Primary production normalized to chlorophyll a shows maximum values in the period of oligotrophy. This increase of carbon assimilation rate per unit of chlorophyll a appears as linked to the period of phosphorus-limited ecosystem, and vertical distribution of taxonomic pigments suggests a possible role of cyanobacteria. Potential export production has been estimated from primary production data and Fp ratio based on pigments concentrations. These estimates (which imply biological steady state conditions) vary in a wide range, from 19 to 71 g C/m**2/yr. There is a decoupling between years with high potential export production and years with high measured particulate fluxes, which highlights the question of balance by resupply of the limiting nutrients and the role of dissolved organic carbon. A possible shift of primary production towards a more regeneration-dominated system is suggested for recent years.

Gravity potential spherical harmonic series

Time variable gravity fields, reflecting variations of mass distribution in the system Earth is one of the key parameters to understand the changing Earth. Mass variations are caused either by redistribution of mass in, on or above the Earth's surface or by geophysical processes in the Earth's interior. The first set of observations of monthly variations of the Earth gravity field was provided by the US/German GRACE satellite mission beginning in 2002. This mission is still providing valuable information to the science community. However, as GRACE has outlived its expected lifetime, the geoscience community is currently seeking successor missions in order to maintain the long time series of climate change that was begun by GRACE. Several studies on science requirements and technical feasibility have been conducted in the recent years. These studies required a realistic model of the time variable gravity field in order to perform simulation studies on sensitivity of satellites and their instrumentation. This was the primary reason for the European Space Agency (ESA) to initiate a study on ''Monitoring and Modelling individual Sources of Mass Distribution and Transport in the Earth System by Means of Satellites''. The goal of this interdisciplinary study was to create as realistic as possible simulated time variable gravity fields based on coupled geophysical models, which could be used in the simulation processes in a controlled environment. For this purpose global atmosphere, ocean, continental hydrology and ice models were used. The coupling was performed by using consistent forcing throughout the models and by including water flow between the different domains of the Earth system. In addition gravity field changes due to solid Earth processes like continuous glacial isostatic adjustment (GIA) and a sudden earthquake with co-seismic and post-seismic signals were modelled. All individual model results were combined and converted to gravity field spherical harmonic series, which is the quantity commonly used to describe the Earth's global gravity field. The result of this study is a twelve-year time-series of 6-hourly time variable gravity field spherical harmonics up to degree and order 180 corresponding to a global spatial resolution of 1 degree in latitude and longitude. In this paper, we outline the input data sets and the process of combining these data sets into a coherent model of temporal gravity field changes. The resulting time series was used in some follow-on studies and is available to anybody interested.

Seagrass time-series analysis products, in Moreton Bay, Australia, with links to GeoTIFFs

The spatial and temporal dynamics of seagrasses have been well studied at the leaf to patch scales, however, the link to large spatial extent landscape and population dynamics is still unresolved in seagrass ecology. Traditional remote sensing approaches have lacked the temporal resolution and consistency to appropriately address this issue. This study uses two high temporal resolution time-series of thematic seagrass cover maps to examine the spatial and temporal dynamics of seagrass at both an inter- and intra-annual time scales, one of the first globally to do so at this scale. Previous work by the authors developed an object-based approach to map seagrass cover level distribution from a long term archive of Landsat TM and ETM+ images on the Eastern Banks (~200 km**2), Moreton Bay, Australia. In this work a range of trend and time-series analysis methods are demonstrated for a time-series of 23 annual maps from 1988 to 2010 and a time-series of 16 monthly maps during 2008-2010. Significant new insight was presented regarding the inter- and intra-annual dynamics of seagrass persistence over time, seagrass cover level variability, seagrass cover level trajectory, and change in area of seagrass and cover levels over time. Overall we found that there was no significant decline in total seagrass area on the Eastern Banks, but there was a significant decline in seagrass cover level condition. A case study of two smaller communities within the Eastern Banks that experienced a decline in both overall seagrass area and condition are examined in detail, highlighting possible differences in environmental and process drivers. We demonstrate how trend and time-series analysis enabled seagrass distribution to be appropriately assessed in context of its spatial and temporal history and provides the ability to not only quantify change, but also describe the type of change. We also demonstrate the potential use of time-series analysis products to investigate seagrass growth and decline as well as the processes that drive it. This study demonstrates clear benefits over traditional seagrass mapping and monitoring approaches, and provides a proof of concept for the use of trend and time-series analysis of remotely sensed seagrass products to benefit current endeavours in seagrass ecology.

Grain size distribution of Oligocene and Miocene sediments from the Indus Fan

The Owen Ridge south of Oman represents oceanic crust that was uplifted by compressional tectonic forces in the early Miocene. Build-out of the Indus Fan led to deposition of a thick sequence of turbidites over the site of the Ridge during the late Oligocene and early Miocene. Early Miocene uplift of the Ridge led to a pelagic cap of nannofossil chalks. Two short sequences of turbidites from the pre- and syn-uplift phases were chosen for detailed grain size analysis. The upper Oligocene section at Site 731 is composed of thin (centimeter-decimeter scale) graded mud turbidites separated by relatively thick (decimeter-meter scale) intervals of homogeneous, non-bioturbated clayey siltstones. These finer intervals are unusually silt-rich (about 60%) for ungraded material and were probably deposited as undifferentiated muds from a series of turbidity current tails. By contrast, the lower Miocene section at Site 722 is comprised of a sequence of interbedded turbidites and hemipelagic carbonates. Sharp-based silt turbidites are overlain by burrow-mottled marly nannofossil chalks. The Oligocene sequence may have accumulated in an overbank setting on the middle fan - the local topographic position favoring frequent deposition from turbidity current tails and occasional deposition from the body of a turbidity flow. Uplift of the Ridge in the early Miocene led to pelagic carbonate deposition interrupted only by turbidity currents capable of overcoming a topographic barrier. Further uplift eventually led to entirely pelagic carbonate deposition.

Abundance and biomass of planktic ciliates at time series station DYNAPROC

The composition and vertical distribution of planktonic ciliates within the surface layer was monitored over four diel cycles in May 95, during the JGOFS-France DYNAPROC cruise in the Ligurian Sea (NW Mediterranean). Ciliates were placed into size and trophic categories: micro- and nano-heterotrophic ciliates, mixotrophic ciliates, tintinnids and the autotrophic Mesodinium rubrum. Mixotrophic ciliates (micro and nano) represented an average of 46% of oligotrich abundance and 39% of oligotrich biomass; nano-ciliates (hetero and mixotrophic) were abundant, representing about 60 and 17% of oligotrich abundance and biomass, respectively. Tintinnid ciliates were a minor part of heterotrophic ciliates. The estimated contribution of mixotrophs to chlorophyll a concentration was modest, never exceeding 9% in discrete samples. Vertical profiles of ciliates showed that chlorophyll-containing ciliates (mixotrophs and autotrophs) were mainly concentrated and remained at the chlorophyll a maximum depth. In contrast, among heterotrophic ciliates, a portion of the population appeared to migrate from 20-30 m depth during the day to the surface at night or in the early morning. Correlation analyses of ciliate groups and phytoplankton pigments showed a strong relationship between nano-ciliates and zeaxanthin, and between chlorophyll-containing ciliates and chlorophyll a, as well as other pigments that were maximal at the chlorophyll a maximum depth. Total surface layer concentrations showed minima of ciliates during nightime/early morning hours.

Hydrochemical Atlas of the Sea of Okhotsk 2001, International Ocean Atlas Series, Volume 3

Presented is a spatial distribution of Temperature, Salinity, Oxygen, Nitrate, Ammonia Nitrogen, Organic Nitrogen, Phosphate, Organic Phosphate, and Silicate data from the Sea of Okhotsk during the 1990 - 1997 period for the months of June - August.

Mapped distribution of tidal flats across China, Manchuria and Korea (1952-1964)

A map of the tidal flats of China, Manchuria and Korea depicted in US Army Map Service Series L500, L542 and L552 topographic maps (compiled between 1950 and 1964). The topographic maps were georeferenced against prominent topographical features in L1T processed Landsat imagery and the foreshore flat class was manually delineated. For further information refer to Murray et. al. (2014).

Dissolved organic carbon measured on water bottle samples at time series station DYFAMED

Dissolved organic carbon (DOC) distribution and dynamics are investigated at the DYFAMED site (central Ligurian Sea, NW Mediterranean) in relation to hydrological and biological contexts, using a 4-year time-series dataset (1991-1994). The DYFAMED site is regarded as a one-dimensional station where simple hydrological mechanisms prevail and where the ecosystem is quite well understood. An average vertical profile of DOC concentration ([DOC]) indicates that maximal concentrations and variability are concentrated in the surface layers. For depths >800 m, the annual variations are on average similar to the analytical standard deviation (~2 µM). The "composite" [DOC] distribution (average distribution over a typical year, integrating about 40 monthly profiles) for surface waters (0-200 m) is closely related to hydrological and phytoplanktonic forcings. It exhibits summer DOC accumulation in surface waters, due to spring-summer stratification and successive phytoplanktonic events such as spring and summer blooms, and winter DOC removal to deeper waters, due to intense vertical mixing. The analysis of vertical [DOC] gradient at 100-m depth as a function of the integrated DOC content in the 0-100-m layer makes it possible to objectively distinguish three specific periods: the winter vertical mixing period, the period of stratification and spring phytoplankton bloom, and the period of stratification re-inforcement and summer-fall phytoplankton bloom. We recalculate the vertical DOC fluxes to deep waters using a larger original dataset, after the first direct calculation (Deep-Sea Res. 40 (10) (1993) 1963, 1972) that was reproduced for other oceanic areas. The seasonal variations of the "composite" [DOC] distribution in surface waters are significantly correlated to the apparent oxygen utilization distribution, but the biogeochemical significance of such a correlation is still under examination. The global significance of our local findings is presented and the role of the oceanic DOC in the global carbon cycle is emphasized, especially with respect to several current issues, such as the oceanic "missing sink" and the equivalence between new production and exported production.