Stable oxygen isotope record and Mg/Ca ratios at the Mid-Pleistocene Climate Transition, ODP Site 181-1123

Earth's climate underwent a fundamental change between 1250 and 700 thousand years ago, the Mid-Pleistocene Transition (MPT), when the dominant periodicity of climate cycles changed from 41,000 to 100,000 years in the absence of significant change in orbital forcing. Over this time, an increase occurred in the amplitude of change of deep ocean foraminiferal oxygen isotopic ratios, traditionally interpreted as defining the main rhythm of ice ages although containing large effects of changes in deep-ocean temperature. We have separated the effects of decreasing temperature and increasing global ice volume on oxygen isotope ratios. Our results suggest that the MPT was initiated by an abrupt increase in Antarctic ice volume at 900 ka. We see no evidence of a pattern of gradual cooling but near-freezing temperatures occur at every glacial maximum.

Sediment wave layer summary in ODP Site 172-1062

Abyssal mud waves (or fine-grained sediment waves) are often cited as evidence for deep current activity because subbottom profiles show that the wave form has migrated with time. The migration history of a fine-grained sediment wave on the Blake-Bahama Outer Ridge (ODP Site 1062) has been studied through the analysis of multiple ODP holes spaced across the wave. Additional information about wave migration patterns comes from 3.5-kHz records and watergun seismic profiles. These data suggest that wave migration has varied during the last not, vert, similar ~10 Myr, although the only sediments sampled are younger than 4.8 Ma. Seismic profiles suggest wave migration was initiated about 8-10 Ma, and wave migration was pronounced from about 5 Ma to about 1 Ma (with an episode of wave reorganization about 4.5 Ma). Analysis of ODP cores suggests that migration rates have been somewhat lower and more variable during the last 1 Myr. Intervals of no wave migration are observed for several time intervals and appear to characterize deglaciations, especially during the last 500 kyr. Comparisons between seismic profiles and the core record show that most of the seismic horizons correlate closely with time horizons, and thus that the seismic profiles give a reasonable representation of sediment wave migration. Models suggest that wave migration is more pronounced during periods of higher bottom current flow and less pronounced during periods of lower current flow. Thus the migration record is consistent with generally higher bottom flow speeds at this site prior to 1 Ma and lower bottom flow speeds after 1 Ma. The Mid-Pleistocene Transition from a dominant climatic periodicity of 40 kyr to a dominant climatic periodicity of 100 kyr starts at about this time, suggesting an overall reduction in bottom flow speed at this site coincident with changing climate patterns. These changes in flow speed could be related to changes in the depth of the Western Boundary Undercurrent as well as to changes in the speed of thermohaline circulation.

Pleistocene sedimentation in the Benguela Current, southeastern Atlantic

We infer variations in paleoproductivity and eolian input at ODP Site 1082 in the Walvis Basin from stable oxygen isotope compositions of the planktonic foraminifera Globorotalia inflata, total organic carbon mass accumulation rates (TOC MAR), and X-ray fluorescence analyses of Fe content. The most pronounced paleoclimatic changes correspond to the time at about 0.9 Ma, when glacial conditions in the northern hemisphere (NH) led to the onset of pronounced 100-kyr glacial-interglacial cycles. We used Fe intensity as a proxy for eolian terrigenous input, and TOC MAR as a paleoproductivity indicator. Paleoproductivity and eolian input show generally higher-amplitude variations of glacial-interglacial cyclicity from 1.5 to 0.58 Ma, indicating pronounced variations in upwellingfavorable winds in this area. At 0.58 Ma, paleoproductivity and eolian input shifted abruptly to lower-amplitude variations with a periodicity of 100 kyr while delta18O values show a trend toward more negative isotope values for the past 0.65 Myr. Especially during glacial periods, oxygen isotope values indicate increasingly warmer sea-surface temperatures toward the end of the Pleistocene. To evaluate the relative influences of NH glaciation and southern hemisphere (SH) insolation as potential forcing mechanisms for variations of eolian input and productivity in the northern Benguela system, we filtered our proxy records at orbital frequencies. The filtered records of Fe intensity and TOC MAR indicate a strong influence of the 100-kyr and 41-kyr frequency bands, supporting our assumption that strong ice buildup in the NH is the dominant trigger for climate changes on the continent and probably in trade-wind intensity. SH insolation and low-latitude precession-related insolation changes were important for paleoproductivity variations in the northern Benguela system, modifying the nutrient supply by southern ocean intermediate waters and the zonal direction of upwelling-inducing trades by the African monsoon system, respectively.

Strontium and rubidium isotopes in serpentinites from ODP Site 195-1200

Subduction of the Pacific plate beneath the Mariana forearc releases fluids to the overlying mantle wedge that ascend, producing serpentinite "mud" that discharges on the ocean floor. As part of Leg 195 of the Ocean Drilling Program cores were obtained from drill-holes into the mud volcanoes. We report the isotopic composition of Sr in water squeezed from intervals of the cores, in the serpentinite mud, in leaches of the serpentinite mud, and in entrained small harzburgitic clasts. Except in the upper few meters below the seawater-mud interface, where pore water approaches seawater Sr concentration and isotopic ratio, Sr concentration and isotopic composition remain constant at 3-6 µmol/kg and ~0.7054. Because the elemental chemistry of the pore water is unlike seawater, this isotopic composition reflects fluids derived from the subducted slab, probably modified by reaction with mantle material during ascent. Higher Sr isotopic ratios, up to 0.7087, - but not with higher Sr concentrations in pore water - occur superimposed on an advection profile at 13-16 mbsf surrounding a thin layer of foraminiferal sand. Since the upward seepage velocity of slab fluids in the mud volcano vents is a few cm/yr, exchange of Sr between these carbonates and the rising fluids must have occurred within a maximum of a few hundred years, essentially instantaneously given the millions, or tens of millions, of years the mud volcanoes have been in existence. In contrast, the strontium isotopic compositions of leached serpentinite mud, and of small harzburgite clasts entrained in the mud, are always significantly greater than that of the pore water. In small harzburgite clasts the ratio reaches 0.7088, almost as high as the seawater value of 0.7092 and much higher than the value of typical mantle-derived strontium of ~0.704. The serpentinite muds and harzburgite clasts clearly equilibrated with seawater Sr when they were initially deposited at the surface of the seamount, but following burial they have not fully equilibrated with strontium in the pore water now discharging through the vents. These variations in the strontium isotopic composition of solids and pore waters are more consistent with episodic expulsion of fluids in the subduction zone than steady state flow. Whereas strontium in carbonates equilibrates isotopically within a few hundred years, strontium in buried harzburgite clasts does not equilibrate in the same time, assuming steady state rates of upward fluid flow. By inference, the harzburgite clasts and associated serpentinite mud must have been near the seafloor, unburied, for a yet undetermined but much longer period of time to have equilibrated from ~0.704 to 0.709 prior to subsequent burial. It may be possible to characterize at least the periodicity of fluid release in the mud volcano setting by investigating the zonation of strontium isotopic composition of hartzburgite clasts throughout the 60-meter deep composite cores.

Pollen record and calculated holocene vegetation and climate dynamics from Sihailongwan Maar Lake, NE China

High-resolution palynological analysis on annually laminated sediments of Sihailongwan Maar Lake (SHL) provides new insights into the Holocene vegetation and climate dynamics of NE China. The robust chronology of the presented record is based on varve counting and AMS radiocarbon dates from terrestrial plant macro-remains. In addition to the qualitative interpretation of the pollen data, we provide quantitative reconstructions of vegetation and climate based on the method of biomization and weighted averaging partial least squares regression (WA-PLS) technique, respectively. Power spectra were computed to investigate the frequency domain distribution of proxy signals and potential natural periodicities. Pollen assemblages, pollen-derived biome scores and climate variables as well as the cyclicity pattern indicate that NE China experienced significant changes in temperature and moisture conditions during the Holocene. Within the earliest phase of the Holocene, a large-scale reorganization of vegetation occurred, reflecting the reconstructed shift towards higher temperatures and precipitation values and the initial Holocene strengthening and northward expansion of the East Asian summer monsoon (EASM). Afterwards, summer temperatures remain at a high level, whereas the reconstructed precipitation shows an increasing trend until approximately 4000 cal. yr BP. Since 3500 cal. yr BP, temperature and precipitation values decline, indicating moderate cooling and weakening of the EASM. A distinct periodicity of 550-600 years and evidence of a Mid-Holocene transition from a temperature-triggered to a predominantly moisture-triggered climate regime are derived from the power spectra analysis. The results obtained from SHL are largely consistent with other palaeoenvironmental records from NE China, substantiating the regional nature of the reconstructed vegetation and climate patterns. However, the reconstructed climate changes contrast with the moisture evolution recorded in S China and the mid-latitude (semi-)arid regions of N China. Whereas a clear insolation-related trend of monsoon intensity over the Holocene is lacking from the SHL record, variations in the coupled atmosphere-Pacific Ocean system can largely explain the reconstructed changes in NE China.

Age models and stable isotope analysis on sediment core Site 199-1218 from the equatorial Pacific

A 13-million-year continuous record of Oligocene climate from the equatorial Pacific reveals a pronounced "heartbeat" in the global carbon cycle and periodicity of glaciations. This heartbeat consists of 405,000-, 127,000-, and 96,000-year eccentricity cycles and 1.2-million-year obliquity cycles in periodically recurring glacial and carbon cycle events. That climate system response to intricate orbital variations suggests a fundamental interaction of the carbon cycle, solar forcing, and glacial events. Box modeling shows that the interaction of the carbon cycle and solar forcing modulates deep ocean acidity as well as the production and burial of global biomass. The pronounced 405,000-year eccentricity cycle is amplified by the long residence time of carbon in the oceans.

Calculated sea level records and deep ocean temperatures from DSDP and ODP sites

During the mid-Pleistocene transition the dominant 41 ka periodicity of glacial cycles transitioned to a quasi-100 ka periodicity for reasons not yet known. This study investigates the potential role of deep ocean hydrography by examining oxygen isotope ratios in benthic foraminifera. Oxygen isotope records from the Atlantic, Pacific and Indian Ocean basins are separated into their ice volume and local temperature/hydrography components using a piece-wise linear transfer function and a temperature calibration. Although our method has certain limitations, the deep ocean hydrography reconstructions show that glacial deep ocean temperatures approached freezing point as the mid-Pleistocene transition progressed. Further analysis suggests that water mass reorganisation could have been responsible for these temperature changes, leading to such stable conditions in the deep ocean that some obliquity cycles were skipped until precessional forcing triggered deglaciation, creating the apparent quasi-100 ka pattern. This study supports previous work that suggests multiples of obliquity cycles dominate the quasi-100 ka glacial cycles with precession components driving deglaciations.

Ice rafted debris distribution in sediment core CRP-1

Lonestone abundances in CRP-1 were investigated using three methods: core examination at Cape Roberts Camp, analysis of digital core images and follow-up core examination. For all images of split-core, we determined size and depth of every detectable lonestone larger than 3 mm. Lonestone abundance decreases exponentially with clast size. Although no significant depth-dependent variations in lonestone size distribution were detected, a strong 0.5-0.7 m abundance periodicity, of unknown origin, is evident within diamicts. Lonestone volume percentage was estimated from size distribution: most size classes contribute approximately the same volume to the total. Sizes >16 mm have rare enough lonestones that their counts are nonrepresentative when based on short intervals of split core. This problem does not affect total counts significantly, but the volume analysis needs to be confined to <= 6 mm lonestones to avoid instability induced by rare and nonrepresentative larger lonestones. If lonestone abundance can be used as an indicator of glacial proximity, then our CRP-1 lonestone abundance logs confirm the overall character of previously inferred variations in relative distance to the ice margin. Large-scale changes in lonestone abundance also reflect the CRP-1 sequence stratigraphy, with individual sequences generally characterised by basal lonestone-rich diamict overlain by lonestone-poor sands and muds. The relationship between glacial proximity and lonestone abundance within diamicts and within sand-mud intervals is, however, less certain. For example, two or three gradual lonestone increases may indicate regressions during glacial advances, in contrast to the more common CRP-l pattern of dominantly transgressive sequences.

Matlab scripts for modeled obliquity amplitude modulations

The start of the Mesozoic Era is marked by roughly five million years (myr) of Earth system upheavals, including unstable biotic recovery, repeated global warming, ocean anoxia, and perturbations in the global carbon cycle. Intervals between crises were comparably hospitable to life. The causes of these upheavals are unknown, but are thought to be linked to recurrent Siberian volcanism. Here, two marine sedimentary successions at Chaohu and Daxiakou, South China are evaluated for paleoclimate change from astronomical forcing. In these sections, gamma-ray variations indicative of terrestrial weathering reveal enhanced obliquity cycling over prolonged intervals, characterized by a periodicity of 32.8 kiloyear and strong 1.2 myr modulations. This suggests a 22-hour length-of-day and 1.2 myr interaction between the orbital inclinations of Earth and Mars. The 1.2 myr obliquity modulation cycles in these sections are compared with Early Triassic records of global sea-level, temperature, redox and biotic evolution. The evidence collectively suggests that long-term astronomical forcing was involved in the repeated climatic and biotic upheavals that took place throughout the Early Triassic.

Magnetic susceptibility (MS) measurements on the Sancerre (France) drill-core

The Toarcian Oceanic Anoxic Event (T-OAE) of the early Jurassic period involves one of the largest perturbations of the carbon cycle in the past 250 Ma, recorded by a pronounced negative carbon-isotope excursion (CIE). Numerous studies have focused on potential causes of the T-OAE and CIE, but are hampered by an uncertain timescale. Here we present high-resolution (~2 kyr) magnetic susceptibility (MS) measurements from the marine marls of the Sancerre-Couy drill-core, southern Paris Basin, spanning the entire Toarcian Stage. The MS variations document a rich series of sub-Milankovitch to Milankovitch frequencies (precession, obliquity and eccentricity) with the periodic g2-g5 (405 kyr) and quasi-periodic g4-g3 (~2.4 Myr Cenozoic mean periodicity) eccentricity terms being the most prominent. The MS-related g4-g3 variation reflects third-order eustatic sequences, and constrains the sequence stratigraphic framework of the Toarcian Stage. In addition, MS variations reveal a modulation of g2-g5 by g4-g3 eccentricity related cycles, suggesting that sea-level change was the main control on the deposition of the Toarcian Sancerre marls, in tune with the astro-climatic frequencies. The stable 405 kyr cyclicity constrains a minimum duration of the Toarcian Stage to ~8.3 Myr, and the well documented CIE, associated with the T-OAE, to ~300 to 500 kyr. The 405 kyr MS timescale calibrates the periodicity of the prominent high-frequency d13C cycles that occur in the decreasing part of the CIE to 30 to 34 kyr, consistent with the Toarcian obliquity period predicted for an Earth experiencing sustained tidal dissipation.