Annotated record and illustrations of Mn nodules retrieved during cruise KH-73-4 of the R/V Hakuho Maru and cruises GH76-1 and GH77-1 of the R/V Hakurei Maru

Deep sea manganese nodules from the Central Pacific Basin are mainly composed of 10Å manganite and d-MnO2 Two zones equivalent to the minerals are evidently distinguishable according to their optical properties. Microscopic and microprobe analyses revealed quite different chemical compositions and textnral characteristics of the two zones. These different feature of the two zones of nodules suggest the different conditions under which they were formed. Concentrations of 11 metal elements in the zones and inter-element relationships show that the 10Å manganite zone is a monomineralic oxide phase containing a large amount of manganese and minor amounts of useful metals, and that the d-MnO2 zone which is apparently homogeneous under the microscope is a mixture of three or more different minerals. The chemical characteristics of the two zones can explain the variation of bulk composition of deep sea manganese nodules and inter-element relationships previously reported, suggesting that the bulk compositions are attributable to the mixing of the 10Å manganite and d-MnO2 zones in various ratios. Characteristic morphology and surface structure of some types of nodules and their relationships to chemistry are also attribut able to the textural and chemical features of the above mentioned two phases. Synthesis of hydrated manganese oxides was carried out in terms of the formation of manganese minerals in the ocean. The primary product which is an equivalent to d-MnO2 was precipitated from Mn 2+ -bearing alkaline solution under oxigenated condition by air bubbling at one atmospheric pressure and room temperature. The primary product was converted to a l0Å manganite equivalent by contact with Ni 2+, Cu 2++ or CO2+ chloride solutions. This reaction caused the decrease of Ni2+, Cu2+ or CO2+ concentrations and the increase of Na+ concentration in the solution. The reaction also proceeded even in diluted solutions of nickel chloride and resulted in a complete removal of Ni2+ from the solution. Reaction products were exclusively 10Å manganite equivalents and their chemical compositions were very similar to those of 10Å manganite in manganese nodules. The maximum value of(Cu+Ni+Co)/Mn ratio of 10Å manganite zones in manganese nodules is 0.16, and the Ni/Mn ratio of synthetic 10Å manganite ranges from 0.15 to 0.18 with the average of 0.167.

(Table 3, page 373) Chemical composition of manganese nodules from the Komahashi-Daini Seamount in the Northern Philippine Sea

Petrological, mineralogical and chemical investigations of marine manganese nodules from the West Pacific revealed the intimate relation between the chemical and mineral compositions and the remarkable preferential partitioning of metal elements in the ferromanganese minerals. The microscopic observations of textures of manganese nodules tell the growth history of manganese nodules and the formation conditions of ferromanganese minerals. Chemical compositions of nodules from Komahashi-Daini Seamount are very similar to those of the nodules from marginal banks and seamounts. Compositional variations in the bulk composition of nodules collected from the same dredge haul are considerably small, suggesting the similarity of the growth history of individual nodules, although the contents of metal elements vary remarkably from layer to layer in a single nodule.

Mineralogy and petrology of Black Sea Basin sediments

The origin and modes of transportation and deposition of inorganic sedimentary material of the Black Sea were studied in approximately 60 piston, gravity, and Kasten cores. The investigation showed that the sediment derived from the north and northwest (especially from the Danube) has a low calcite-dolomite ratio and a high quartz-feldspar ratio. Rock fragments are generally not abundant; garnet is the principal heavy mineral and illite is the predominant clay mineral. This sedimentary material differs markedly from that carried by Anatolian rivers, which is characterized by a high calcite-dolomite ratio and a low quartz-feldspar ratio. Rock fragments are abundant; pyroxene is the principal heavy mineral and montmorillonite is the predominant clay mineral. In generel, the clay fraction is large in all sediments (27.6-86.9 percent), and the lateral distributian indicates an increase in clay consent from the coasts toward two centers in the western and eastern Black Sea basin. Illite is the most common clay mineral in the Black Sea sediments. The lateral changes in composition of the clay mineral can easily be traced to the petrologic character of northern (rich in illite) and southern (rich in montmorillonite) source areas. In almost all cores, a rhythmic change of the montmorillonite-illite ratio with depth was observed. These changes may be related to the changing influence of the two provinces during the Holocene and late Pleistocene. Higher montmorillonite content seems to indicate climctic changes, probably stages of glaciation end permafrost in the northern area, at which time the illite supply was diminished to a large extent. The composition of the sand fraction is relatad to the different petrologic and morphologic characteristics of two major source provimces: (1) a northern province (rich in quartz, feldspars, and garnet) characterized by a low elevation, comprising the Danube basin area and the rivers draining the Russian platform; and (2) a southern province (rich in pyroxene and volcanic and metamorphic rocks) in the mountainous region of Anatolia and the Caucasus, characterized by small but extremely erosive rivers. The textural properties (graded bedding) of the deep-sea send layers clearly suggest deposition from turbidity currents. The carbonate content of the contemporary sediments ranges from 5 to 65 percent. It increases from the coast to a maximum in two centers in the western and eastern basin. This pattern reflects the distribution of the <2-µm fraction. The contemporary mud sedimentation is governed by two important factors: (1) the deposition of terrigenous allochthonous material of low carbonate content originating from the surrounding hinterland (northern and southern source areas), and (2) the autochthonous production of large quantities of biogenic calcite by coccolithophores during the last period of about 3,000-4,000 years.

Location and ages of terrestrial peatlands located on continental shelves and in coastal sediments

This synthesis dataset contains records of freshwater peat and lake sediments from continental shelves and coastal areas. Information included is site location (when available), thickness and description of terrestrial sediments as well as underlying and overlying sediments, dates (when available), and references.

(Table 8, page 38) Spectrographic analyses of deep sea manganese nodules from the Pacific and Indian Oceans

In an earlier paper by two of the authors the conclusion was reached that the 33 recognized species of oxides of Mn could be separated into 3 groups: 1) those which appeared to be persistently supergene in origin, 2) those which appeared to be persistently hypogene, and 3) those which were supergene in some localities and hypogene in other localities. When that paper was written, there were available about 250 X-ray diffraction analyses of mineral specimens, also 35 complete and about 150 partial chemical analyses. The conclusions of that paper were based upon the interpretation of the geologic conditions under which these specimens occurred. Late in the preparation of that paper, it seemed worthwhile to make numerous semiquantitative analyses of specimens, largely from 9 western [U.S.A] states, selected carefully from 5 groups of geologic environments, in the hope that the frequency and percentages of some elements might be distinctive of the several geologic groups. For this purpose, 95 specimens were selected from the 5 groups, as follows: 19 specimens interpreted as supergene oxides by the geologists who collected them, 35 specimens of hypogene vein oxides, 22 specimens of Mn-bearing hot spring aprons, 9 specimens of stratified oxides, and 10 specimens of deep-sea nodules. The spectrographic analyses here recorded indicate that a group of elements - W, Ba, Sr, Be, As, Sb, Tl, and Ge - are present more commonly, and largely in higher percentages, in the hypogene oxide than in the supergene oxides and thus serve to indicate different sources of the Mn. Also, the frequency and percentages of some of these elements indicate a genetic relation of the manganese oxides in hypogene veins, hot spring aprons, and stratified deposits. The analyses indicate a declining percentage of some elements from depth to the surface in these 3 related groups and increasing percentages of some other elements. It is concluded that some of the elements in deep-sea nodules indicate that sources other than rocks decomposed on the continents, probably vulcanism on the floors of the seas, have contributed to their formation.

Annotated record of the detailed examination of Mn deposits from R/V Bosei Maru Cruise GH72-2 stations

In 1972, the five years program 'Basic investigations for exploration of deep sea mineral resources' was laid out by the Agency of Industrial Science and Technology, Ministry of International Trade and Industry. The Geological Survey of Japan and the National Research Institute of Pollution and Resources undertook the first survey project. The survey team consisted of four geologists and a surveyor of the Geological Survey of Japan, and a mechanical, engineer and four mining engineers of National Research Institute of Polution and Resources. The survey started on November 11 using the "Bosei Maru" survey vessel (1100 tons) chartered from Tokai University. The cruise departed from Shimizu harbor to the Ponape and Guam islands, and terminated at the harbor of departure on December 11. The surveyed area was mainly covered the Mariana basin and the Magellan seamounts, and fifteen bottom samples were collected during the cruise. Ferromanganese nodules were obtained at several stations at a depth over 5000m.

Corel Geological Drafting Kit (CGDK) - an extensible CorelDRAW VBA program for geological drafting

Corel Geological Drafting Kit (CGDK), a program written in VBA, has been designed to assist geologists and geochemists with their drafting work. It obtains geological data from a running Excel application directly, and uses the data to plot geochemical diagrams and to construct stratigraphic columns. The software also contains functions for creating stereographic projections and rose diagrams, which can be used for spatial analysis, on a calibrated geological map. The user-friendly program has been tested to work with CorelDRAW 13 - 14 - 15 and Excel 2003 - 2007.

Bacteriological investigations in the Persian Gulf

While the R.V. "Meteor" was in the eastern Persian Gulf, during the time between March 31 and April 14, 1965, bacteriological investigations of the water and sediment were performed. The content of saprophytic bacteria in the water decreases from the coasts outward to the middle of the gulf. This shows a good correlation with the turbidity values. In a sediment core from the southern part of the gulf, the bacterial counts in all the horizonts were much higher than those from the northern part of the Persian Gulf. This agrees with the findings of the geologists, according to which the proportion of carbon compounds in the sediments decreases from south to north. Luminous bacteria were found in many samples of water. Their proportion of the saprophytic flora becomes less from south to north. Most of the water samples also contained pigmented bacteria. On freshwater medium, relatively few bacteria were able to develop. The proportion of these non-halophilic forms amounted up to 7 % (average about 1 %) of the total saprophytic count, in 22 samples examined. In this group the pigmented forms played a very large role. A comparison of the distribution of saprophytic bacteria in the eastern Persian Gulf with that in other inland seas such as the North Sea and the Baltic Sea shows, that the saprophytic counts in the subtropical Persian Gulf (arid region) lie clearly below those in corresponding sea areas of the temperate zones (humid region). This is to be attributed above all to the greater flow of organic nutrients into the latter.

Annotated record of the detailed examination of Mn deposits from R.R.S. "Discovery" Cruise 2 stations

This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.