Decadal-to-centennial scale variations during the Holocene reconstructed from sediment core D13902

Sea surface temperature (SST), marine productivity, and fluvial input have been reconstructed for the last 11.5 calendar (cal) ka B.P. using a high-resolution study of C37 alkenones, coccolithophores, iron content, and higher plant n-alkanes and n-alkan-1-ols in sedimentary sequences from the inner shelf off the Tagus River Estuary in the Portuguese Margin. The SST record is marked by a continuous decrease from 19C, at 10.5 and 7 ka, to 15C at present. This trend is interrupted by a fall from 18C during the Roman and Medieval Warm Periods to 16C in the Little Ice Age. River input was very low in the early Holocene but increased in the last 3 cal ka B.P. in association with an intensification of agriculture and deforestation and possibly the onset of the North Atlantic Oscillation/Atlantic Multidecadal Oscillation modes of variability. River influence must have reinforced the marine cooling trend relative to the lower amplitude in similar latitude sites of the eastern Atlantic. The total concentration of alkenones reflects river-induced productivity, being low in the early Holocene but increasing as river input became more important. Rapid cooling, of 1-2C occurring in 250 years, is observed at 11.1, 10.6, 8.2, 6.9, and 5.4 cal ka B.P. The estimated age of these events matches the ages of equivalent episodes common in the NE Atlantic- Mediterranean region. This synchronicity reveals a common widespread climate feature, which considering the twentieth century analog between colder SSTs and negative North Atlantic Oscillation (NAO), is likely to reflect periods of strong negative NAO.

Planktic foraminifera analyses of surface sediments and satellite data in the Canary Islands region

The Canary Islands region occupies a key position with respect to biogeochemical cycles, with the zonal transition from oligotrophic to nutrient-rich waters and the contribution of Saharan dust to the particle flux. We present the distribution of geochemical proxies (TOC, carbonate, d15N, d13Corg, C/N-ratio) and micropaleontological parameters (diatoms, dinoflagellates, foraminifera, pteropods), in 80 surface-sediment samples in order to characterise the influence of coastally upwelled water on the domain of the subtropical gyre. Results of the surface-sediment analyses confirmed the high biomass gradient from the coast to the open ocean inferred from satellite data of surface chlorophyll or SST. The distribution of total dinoflagellate cysts, the planktic foraminifera species Globigerina bulloides, the diatom resting spore Chaetoceros spp., and TOC concentration coincided well with the areas of strong filament production off Cape Ghir and Cape Yubi. The warm-water planktic foraminifera Globigerinoides ruber (white), the diatom Nitzschia spp., and the d15N-values showed the opposite trend with high values in the open ocean. Factor analyses on the planktic foraminifera species distribution indicated three major assemblages in the Canary Islands region that represent the present surface-water conditions from the upwelling influenced region via a mixing area towards the subtropical gyre.

Sea surface temperature reconstruction for the middle Pleistocene from sediment core MD03-2699

Past sea surface water conditions of the western Iberian Margin were reconstructed based on biomarker analyses of a marine deep sea core MD03-2699 from the Estremadura Spur north off Lisbon, providing new insights into orbital and suborbital-scale climate variability between marine isotope stage (MIS) 15 to MIS 9 (580 to 300 ka). We use biomarker-based proxy records such as the alkenone unsaturated index to estimate sea surface temperature (SST), the total alkenone concentration to reconstruct phytoplankton productivity, and terrestrial biomarkers to evaluate the continental input. The results extend the existing biomarker record, namely the SST for the Iberian Margin, back to the sixth climatic cycle (580 ka). A general trend of stable interglacials contrasts with glacial periods and glacial inceptions which are marked by high-frequency variability. Thus, several short-lived climatic coolings were identified by large SST decreases, the occurrence of ice-rafted detritus and high percentages of the tetraunsaturated alkenone C 37:4. Some of these events were extremely cold and similar in their general trends to the well-known Heinrich events of the last glaciation. We identified eight Heinrich-type events between 580 and 300 ka. The general deglaciation pattern detected between MIS 15 and MIS 9 is similar in their general trends to that characterizing the more recent climatic cycles, i.e., marked by two coolings separated by a short warming episode which may reflect the southward, northward, and southward migration of the Polar Front.

Distribution of surface sediment properties along the Portuguese western margin

Organic matter contained in surface sediments from four regions on the western Portuguese shelf, which are influenced by coastal upwelling and fluvial input, was analysed with respect to elemental organic carbon (Corg) and nitrogen (Ntotal) content and isotopic carbon and nitrogen ratios (d13Corg, d15N). Corg/Ntotal weight ratios and d13Corg values are interpreted in terms of terrigenous or marine organic matter sources, supported by CaCO3 content. Organic matter in the shelf sediments is mainly of marine origin, with increasing terrigenous components only close to rivers and estuaries. In the northern shelf region the data indicates significant terrigenous supply by the Douro River. North of the Nazaré Canyon organic matter composition implies a mainly marine origin, with a higher terrestrial influence close to the canyon head. Organic matter composition in the central shelf region, which is dominated by the Tagus Estuary and the Tagus prodelta, reveals a change from a continental-type signature within the estuary to a more marine-type signature further to the west and south of the estuary mouth. In the southern region near Cape Sines the geochemical properties clearly reflect the marine origin of sedimentary organic matter. Sedimentary d15N values are interpreted to reflect various degrees of assimilation of seasonally upwelled nitrate, in relation to the upwelling centres. In the estuarine environment, inputs of agriculturally influenced dissolved inorganic nitrogen are reflected in the sediments. No evidence for N2-fixation or denitrification is found. On the central shelf north of the Nazaré canyon, sedimentary d15N values are close to marine d15NO3- and thus indicate a complete NO3- assimilation and N-limitation of marine production. Light d15N values in distal sediments off the Douro River mouth and in samples south of C. Sines reflect high NO3- supply and a close proximity to the seasonal upwelling centres. Particularly in sediments form the Sines region, light d15N values in southern samples reflect stronger upwelling further south.

Sea surface temperature and export productivity reconstructions of sediments off the western Iberian margin

Present day hydrographic conditions along the western Iberian margin are characterized by seasonal upwelling with filaments that can penetrate more than 200 km into the open ocean and constitute areas of cold and highly productive waters. In order to investigate spatial and temporal gradients in temperature and productivity conditions during the last 150 ky, high-resolution proxy records were generated in 3 cores (SU92-03, MD95-2040, MD95-2042), located along the Iberian coast between 43°12'N and 37°48'N and forming a N-S profile. In all cores, planktonic foraminifera census counts are used to reconstruct summer sea surface temperature (SSTsu) and export productivity (Pexpsu) using the modern analog technique SIMMAX 28. SSTsu and Pexpsu values similar to the present are observed throughout the Holocene and MIS 5e periods for each site, respectively, indicating fairly stable conditions equivalent to the modern ones. On glacial/interglacial timescales, SSTsu increases by 2-3 °C from the northern to southernmost site. Pexpsu, on the other hand, shows a decrease of 30-40 gC/m**2/yr from North to South at present time and during interglacial periods, and no significant variation (90-100 gC/m**2/yr) during glacial periods. The northernmost core SU92-03 reveals the coldest conditions with records more similar to MD95-2040 than to MD95-2042, the later of which is, as at present, more affected by subtropical waters. Core SU92-03 shows higher interglacial productivity similar to open ocean mid- to high latitude sites, while the other two cores monitor higher glacial productivity conform with other upwelling sites off NW Africa. A boundary between differences in glacial/interglacial productivity appears to be present in our study between 43°12'N and 40°35'N. Especially north of 40°N, coldest SSTsu and lowest Pexpsu are found during Heinrich events (H)1-H8 and H10-H11. In contrast, lowest Pexpsu do not coincide with these events at site MD95-2042, but appear to be related to the presence of relatively warm and nutrient-poor subtropical Eastern North Atlantic Central Water advected with the Azores Current.