Geochemistry of ODP Hole 128-798B

The capability of determining elemental concentrations through geochemical logging has recently been established. However, the quality of these data obtained in some environments has yet to be quantified. We assess the quality of geochemical logs compared with XRF results from a suite of core samples from Hole 798B. The resulting core/log correlations are only fair, because the tool has been adversely affected by the very high porosity of the formation. The results, however, do fall within the statistical uncertainties predicted by the processing. The recent application of a modified boron sleeve to the Ocean Drilling Program's geochemical logging tool is shown to reduce interference of borehole chlorine on the resultant chemistry.

Geochemistry of sediments and interstitial waters of ODP Sites 128-798 and128-799

Interstitial waters in sediments below 400 (Site 798) and 435 meters below seafloor (Site 799) have chloride concentrations of 516-527 and 501-515 mM, respectively, lower than the 540 mM of the modern-day Japan Sea. The chemical composition of interstitial waters, bulk sediments, clay-size sediment fraction, and carbonate nodules from Oki Ridge (Site 798) and Kita-Yamato Trough (Site 799), Japan Sea, reflect in-situ diagenetic processes superimposed on geochemical signals that may indicate freshening of Miocene local marginal basin waters. Interstitial waters at both sites exhibit changes in chemical composition which coincide with the occurrence of low-porosity and high-bulk density layers composed of dolomite and opal-CT, which impede diffusive communication with the overlying interstitial waters. Based on interstitial water stable isotope evidence and mass-balance calculations of chloride dilution, diagenetic reactions that involve the release of structural bound water from opal-A and/or clay minerals contribute to the observed geochemical signals, but cannot account for all the measured chloride dilution.

Pleistocene planktonic foraminifera at ODP Site 128-798

ODP Site 798 on the Oki Ridge in the Southern Japan Sea yielded the first continuous and well-preserved record of Pleistocene planktonic foraminifers in the Northwestern Pacific Ocean region. Quantitative analysis of planktonic foraminifers completed for 122 samples from the 200-m-thick Pleistocene section cored at ODP Site 798 provides a proxy record of variations in sea-surface temperature, productivity, and circulation during the past 1.6 m.y. in an area beneath the track of the Tsushima Current. Faunal census data allow recognition of five distinct assemblages: (1) type A assemblages dominated by sinistrally coiling forms of Neogloboquadrina pachyderma representing polar-subpolar surface temperatures, (2) type B assemblages dominated by Globigerina bulloides and thought to represent periods of increased surface productivity and upwelling, (3) type C assemblages marked by significant abundances of dextrally coiling forms of N. pachyderma thought to represent the warm transitional waters of the Tsushima Current, (4) type D assemblages distinguished by relatively high percentages of dextral N. pachyderma and Globorotalia inflata that also represent warmer surface temperatures and increased flow of the Tsushima Current, and (5) type E assemblages marked by relatively large numbers of the delicate species Globigerina quinqueloba and Globigerinita spp., indicative of exceptional preservation conditions and/or episodic high production of these taxa. Early and middle Pleistocene coiling patterns of Neogloboquadrina pachyderma at Site 798 can be correlated with Pleistocene coiling trends and planktonic foraminiferal datums established in the onshore Oga Peninsula sequence of Northern Honshu and open-ocean N. pachyderma coiling dominance shifts in the North Pacific region. A sustained early Pleistocene warm period recognized in both the Oga Peninsula sequence and the Northern Pacific can clearly be recognized at Site 798. In addition, the late Pleistocene planktonic foraminiferal record at Site 798 shows good correlation with glaciation/deglaciation events for the Northern Hemisphere as delineated by oxygen isotopes and represents the first detailed analysis of Pleistocene sea-surface temperature changes in the Northwestern Pacific Ocean region.

Total organic carbon, bitumen ratio, hopane and sterane parameters of ODP Sites 128-798 and 128-799

Notable compositional changes of organic matter are observed below the silica transition zone in thermally immature sediments. The increase of bitumen ratio, and hopane and sterane isomerization parameters indicate an acceleration of the kinetics of the chemical reactions which transform the organic matter. This phenomenon is probably due to the numerous mineral and textural changes induced by the transformation of amorphous biogenic silica into crystalline authigenic silica.

Biochemical investigation of multicorer sediment profile PS74/128-2

To detect and track the impact of large-scale environmental changes in a the transition zone between the northern North Atlantic and the central Arctic Ocean, and to determine experimentally the factors controlling deep-sea biodiversity, the Alfred- Wegener-Institute for Polar and Marine Research (AWI) established the deep-sea long-term observatory HAUSGARTEN, which constitutes the first, and until now only open-ocean long-term station in a polar region. Virtually undisturbed sediment samples have been taken using a video-guided multiple corer (MUC) at 13 HAUSGARTEN stations along a bathymetric (1,000 - 4,000 m water depth) and a latitudinal transect in 2,500 m water depth as well as two stations at 230 and 1,200 m water depth within the framework of the KONGHAU project. Various biogenic sediment compounds were analyzed to estimate the input of organic matter from phytodetritus sedimentation, benthic activities (e.g. bacterial exoenzymatic activity), and the total biomass of the smallest sediment-inhabiting organisms (size range: bacteria to meiofauna).

(Table 1) Peak intensities and stable carbon and oxygen isotope ratios of various diagenetic carbonates of ODP Site 128-799

Abundant and various diagenetic carbonates were recovered from a 1084-m-thick, Quaternary to lower Miocene section at ODP Site 799 in the Japan Sea. Petrographic, XRD, SEM, EDS-chemical, and isotopic analyses revealed wide variations in occurrence and textural relations and complex mineralogy and chemistry. Diagenetic carbonates include calcite, calcium-rich rhodochrosite, iron- and manganese-rich magnesite, iron- and manganese-rich dolomite and ankerite, and iron- and manganeserich lansfordite (hydrous Mg-carbonate). Rhodochrosite commonly occurs as small, solid nodules and semi-indurated, thin layers in bioturbated, mottled sediments of Units I and II (late Miocene to Quaternary). Lansfordite occurs as unindurated nodules and layers in Unit II (late Miocene and Pliocene), whereas magnesite forms indurated beds a few centimeters thick in slightly bioturbated-to-faintly laminated sediments of Unit III (middle and late Miocene). Some rhodochrosite nodules have dark-colored, pyritic cores, and some pyrite-rhodochrosite nodules are overgrown by and included within magnesite beds. Dolomite and ankerite tend to form thick beds (>10 cm) in bedded to laminated sediments of Units III, IV, and V (early to late Miocene). Calcite occurs sporadically throughout the Site 799 sediments. The d18O values of carbonates and the interstitial waters, and the measured geothermal gradient indicate that almost all of the Site 799 carbonates are not in isotopic equilibrium with the ambient waters, but were precipitated in the past when the sediments were at shallower depths. Depths of precipitation obtained from the d18O of carbonates span from 310 to 510 mbsf for magnesite and from 60 to 580 mbsf for dolomite-ankerite. Rhodochrosite and calcite are estimated to have formed within sediments at depths shallower than 80 mbsf. Diagenetic history in the Site 799 sediments have been determined primarily by the environment of deposition; in particular, by the oxidation-reduction state of the bottom waters and the alkalinity level of the interstitial waters. Under the well-oxygenated bottom-water conditions in the late Miocene and Pliocene, manganese initially accumulated on the seafloor as hydrogenous oxides and subsequently was mobilized and reprecipitated as rhodochrosite within the shallow sulfate-reduction, sub-oxic zone. Precipitation of lansfordite occurred in the near-surface sediments with abundant organic carbon and an extremely high alkalinity during the latest Miocene and Pliocene. The lansfordite was transformed to magnesite upon burial in the depth interval 310 to 510 mbsf. Dolomite first precipitated at shallow depths in Mn-poor, anoxic, moderately biocalcareous sediments of early to late Miocene. With increasing temperature and depth, the dolomite recrystallized and reequilibrated with ambient waters at depths below about 400 mbsf.