Age model, stable isotopes, major element proportions and endmember unmixing results from four western tropical Atlantic cores

We investigate changes in the delivery and oceanic transport of Amazon sediments related to terrestrial climate variations over the last 250 ka. We present high-resolution geochemical records from four marine sediment cores located between 5 and 12° N along the northern South American margin. The Amazon River is the sole source of terrigenous material for sites at 5 and 9° N, while the core at 12° N receives a mixture of Amazon and Orinoco detrital particles. Using an endmember unmixing model, we estimated the relative proportions of Amazon Andean material ("%-Andes", at 5 and 9° N) and of Amazon material ("%-Amazon", at 12° N) within the terrigenous fraction. The %-Andes and %-Amazon records exhibit significant precessional variations over the last 250 ka that are more pronounced during interglacials in comparison to glacial periods. High %-Andes values observed during periods of high austral summer insolation reflect the increased delivery of suspended sediments by Andean tributaries and enhanced Amazonian precipitation, in agreement with western Amazonian speleothem records. Increased Amazonian rainfall reflects the intensification of the South American monsoon in response to enhanced land-ocean thermal gradient and moisture convergence. However, low %-Amazon values obtained at 12° N during the same periods seem to contradict the increased delivery of Amazon sediments. We propose that reorganizations in surface ocean currents modulate the northwestward transport of Amazon material. In agreement with published records, the seasonal North Brazil Current retroflection is intensified (or prolonged in duration) during cold substages of the last 250 ka (which correspond to intervals of high DJF or low JJA insolation) and deflects eastward the Amazon sediment and freshwater plume.

Stable isotopes, Mg/Ca ratios and sea surface temperatures on foraminifera from sediment cores off equatorial Peru during the last ~17kyr

The complex deglacial to Holocene oceanographic development in the Gulf of Guayaquil (Eastern Equatorial Pacific) is reconstructed for sea surface and subsurface ocean levels from (isotope) geochemical proxies based on marine sediment cores. At sea surface, southern sourced Cold Coastal Water and tropical Equatorial Surface Water/Tropical Surface Water are intimately related. In particular since ~10 ka, independent sea surface temperature proxies capturing different seasons emphasize the growing seasonal contrast in the Gulf of Guayaquil, which is in contrast to ocean areas further offshore. Cold Coastal Water became rapidly present in the Gulf of Guayaquil during the austral winter season in line with the strengthening of the Southeast Trades, while coastal upwelling off Peru gradually intensified and expanded northward in response to a seasonally changing atmospheric circulation pattern affecting the core locations intensively since 4 ka BP. Equatorial Surface Water, instead, was displaced and Tropical Surface Water moved northward together with the Equatorial Front. At subsurface, the presence of Equatorial Under Current-sourced Equatorial Subsurface Water was continuously growing, prominently since ~10-8 ka B.P. During Heinrich Stadial 1 and large parts of the Bølling/Allerød, and similarly during short Holocene time intervals at ~5.1-4 ka B.P. and ~1.5-0.5 ka B.P., the admixture of Equatorial Subsurface Water was reduced in response to both short-term weakening of Equatorial Under Current strength from the northwest and emplacement by tropical Equatorial Surface Water, considerably warming the uppermost ocean layers.

Benthic foraminiferal stable isotope stratigraphy of ODP Site 138-846 in the tropical Pacific Ocean

A stable-isotope stratigraphy at Site 846 (tropical Pacific, 3°06'S, 90°49'W, 3307 m water depth), based on the benthic foraminifers Cibicides wuellerstorfi and Uvigerina peregrina, yields a high-resolution record of deep-sea delta18O and delta13C over the past 1.8 Ma, with an average sampling interval of 3 k.y. Variance in the delta18O and delta13C records is concentrated in the well-known orbital periods of 100, 41, and 23 k.y. In the 100-k.y. band, both isotopic signals grow from relatively low amplitudes prior to 1.2 Ma, to high amplitudes in the late Quaternary since 0.7 Ma. The amplitude of delta18O and especially of delta13C decreases in the 41-k.y. band as it grows in the 100-k.y. band, consistent with a transfer of energy into an orbitally-paced internal oscillation. A weak 30-k.y. rhythm, present in both delta18O and delta13C, may reflect nonlinear interaction between the 41-k.y. and 100-k.y. bands in the evolving climate system. In the 23-k.y. and 19-k.y. bands associated with orbital precession, delta18O and delta13C are not coherent with each other on long time scales, and do not evolve like the 100-k.y. and 41-k.y. bands. This suggests that the source of the growing 100-k.y. oscillation is not a nonlinear response to precession, in contrast to predictions of some climate models. Sedimentation rates at this site also vary with a strong 100-k.y. cycle. Unlike the isotope records, the amplitude of 100-k.y. variations in sedimentation rate is relatively constant over the past 1.8 Ma, ranging from about 15 to 70 m/m.y. Prior to 0.9 Ma, sedimentation rates co-vary with orbital eccentricity, rather than with global climate as reflected by delta18O or delta13C. A source of this 100-k.y. cycle of sedimentation rate in the absence of similar ice volume fluctuations may be precessional heating of equatorial land masses, which in an energy balance climate model drives variations of monsoonal climates with a 100-k.y. rhythm. For the interval younger than 0.9 Ma, high sedimentation rates in the 100-k.y. band are consistently associated with glacial stages. This change of pattern suggests that when the amplitude of glacial cycles become large enough, their global effects overpower a local monsoon-driven variation in sedimentation rate at Site 846.

Petrology and carbon and oxygen stable isotopic composition of macrofossils and sediments from the Blake-Bahama Formation, DSDP Hole 93-603B

Strata that record the evolutionary history of the North American continental margin in a region that serves as the basin margin interface between allochthonous sedimentation from the continent and pelagic sedimentation from the oceanic realm were recovered at Deep Sea Drilling Project Site 603, on the lower continental rise. The lowermost unit recovered at this site is composed of upper Berriasian-Aptian interbedded laminated limestone and bioturbated limestone with sandstone to claystone turbidites. This unit can be correlated with the Blake-Bahama Formation in the western North Atlantic. Studies of the laminated and bioturbated limestones were used to determine the depositional environment. Geochemical and petrographic studies suggest that the laminated limestones were deposited from the suspended particulate loads of the nepheloid layer associated with weak bottom-current activity as well as moderate to poorly oxygenated bottom-water conditions. Fragments of macrofossils are also found in the Blake-Bahama Formation drilled at Site 603. Twelve specimens and their host sediment were analyzed for their carbon and oxygen isotopic composition. The macrofossil samples chosen for analysis consist of nine samples of Inoceramus, two ammonite aptychi, and one belemnite sample. Depletion in 18O is observed in recrystallized specimens. The ammonite aptychi have been diagenetically altered and/or exhibit evidence of isotopic fractionation by the organism. Oxygen isotope paleotemperatures obtained from five well-preserved specimens - four of Inoceramus and one of a belemnite - suggest that bottom-water temperatures in the North Atlantic Basin during the Early Cretaceous were very warm, at least 11°C.

Geochemical analysis of nine sections from the Nama Group, Namibia

The first appearance of skeletal metazoans in the late Ediacaran (~550 million years ago; Ma) has been linked to the widespread development of oxygenated oceanic conditions, but a precise spatial and temporal reconstruction of their evolution has not been resolved. Here we consider the evolution of ocean chemistry from ~550 to ~541 Ma across shelf-to-basin transects in the Zaris and Witputs Sub-Basins of the Nama Group, Namibia. New carbon isotope data capture the final stages of the Shuram/Wonoka deep negative C-isotope excursion, and these are complemented with a reconstruction of water column redox dynamics utilising Fe-S-C systematics and the distribution of skeletal and soft-bodied metazoans. Combined, these inter-basinal datasets provide insight into the potential role of ocean redox chemistry during this pivotal interval of major biological innovation. The strongly negative d13C values in the lower parts of the sections reflect both a secular, global change in the C-isotopic composition of Ediacaran seawater, as well as the influence of 'local' basinal effects as shown by the most negative d13C values occurring in the transition from distal to proximal ramp settings. Critical, though, is that the transition to positive d13C values postdates the appearance of calcified metazoans, indicating that the onset of biomineralization did not occur under post-excursion conditions. Significantly, we find that anoxic and ferruginous deeper water column conditions were prevalent during and after the transition to positive d13C that marks the end of the Shuram/Wonoka excursion. Thus, if the C isotope trend reflects the transition to global-scale oxygenation in the aftermath of the oxidation of a large-scale, isotopically light organic carbon pool, it was not sufficient to fully oxygenate the deep ocean. Both sub-basins reveal highly dynamic redox structures, where shallow, inner ramp settings experienced transient oxygenation. Anoxic conditions were caused either by episodic upwelling of deeper anoxic waters or higher rates of productivity. These settings supported short-lived and monospecific skeletal metazoan communities. By contrast, microbial (thrombolite) reefs, found in deeper inner- and mid-ramp settings, supported more biodiverse communities with complex ecologies and large skeletal metazoans. These long-lived reef communities, as well as Ediacaran soft-bodied biotas, are found particularly within transgressive systems, where oxygenation was persistent. We suggest that a mid-ramp position enabled physical ventilation mechanisms for shallow water column oxygenation to operate during flooding and transgressive sea-level rise. Our data support a prominent role for oxygen, and for stable oxygenated conditions in particular, in controlling both the distribution and ecology of Ediacaran skeletal metazoan communities.

1000 year ice-core records from Berkner Island, Antarctica

Two medium-depth ice cores were retrieved from Berkner Island by a joint project between the Alfred-Wegener-Institut and the British Antarctic Survey in the 1994/95 field season. A 151m deep core from the northern dome (Reinwarthhöhe) of Berkner Island spans 700 years, while a 181m deep core from the southern dome (Thyssenhöhe) spans approximately 1200 years. Both cores display clear seasonal cycles in electrical conductivity measurements, allowing dating by annual-layer counting and the calculation of accumulation profiles. Stable-isotope measurements (both d18O and dD), together with the accumulation data, allow us to estimate changes in climate for most of the past millennium: the data show multi-decadal variability around a generally stable long-term mean. In addition, a full suite of major chemistry measurements is available to define the history of aerosol deposition at these sites: again, there is little evidence that the chemistry of the sites has changed over the past six centuries. Finally, we suggest that the southern dome, with an ice thickness of 950 m, is an ideal site from which to gain a climate history of the late stages of the last glacial and the deglaciation for comparison with the records from the deep Antarctic ice cores, and with other intermediate-depth cores such asTaylor Dome and Siple Dome.

Galápagos coral reef persistence after ENSO warming across an acidification gradient

Anthropogenic CO2 is causing warming and ocean acidification. Coral reefs are being severely impacted, yet confusion lingers regarding how reefs will respond to these stressors over this century. Since the 1982-1983 El Niño-Southern Oscillation warming event, the persistence of reefs around the Galápagos Islands has differed across an acidification gradient. Reefs disappeared where pH<8.0 and aragonite saturation state (Omega arag)<=3 and have not recovered, whereas one reef has persisted where pH>8.0 and Omega arag>3. Where upwelling is greatest, calcification by massive Porites is higher than predicted by a published relationship with temperature despite high CO2, possibly due to elevated nutrients. However, skeletal P/Ca, a proxy for phosphate exposure, negatively correlates with density (R=-0.822, p<0.0001). We propose that elevated nutrients have the potential to exacerbate acidification by depressing coral skeletal densities and further increasing bioerosion already accelerated by low pH.

Stable isotope record of Globorotalia inflata

We sampled the upper water column for living planktic foraminifera along the SW-African continental margin. The species Globorotalia inflata strongly dominates the foraminiferal assemblages with an overall relative abundance of 70-90%. The shell delta18O and delta13C values of G. inflata were measured and compared to the predicted oxygen isotope equilibrium values (delta18O(eq)) and to the carbon isotope composition of the total dissolved inorganic carbon (delta13C(DIC)) of seawater. The delta18O of G. inflata reflects the general gradient observed in the predicted delta18O(eq) profile, while the delta13C of G. inflata shows almost no variation with depth and the reflection of the delta13C(DIC) in the foraminiferal shell seems to be covered by other effects. We found that offsets between delta18O(shell) and predicted delta18O(eq) in the surface mixed layer do not correlate to changes in seawater [CO3[2-]]. To calculate an isotopic mass balance of depth integrated growth, we used the oxygen isotope composition of G. inflata to estimate the fraction of the total shell mass that is grown within each plankton tow depth interval of the upper 500 m of the water column. This approach allows us to calculate the DELTA delta13C(interval added-DIC); i.e. the isotopic composition of calcite that was grown within a given depth interval. Our results consistently show that the DELTA delta13C(IA-DIC) correlates negatively with in situ measured [CO3[2-]] of the ambient water. Using this approach, we found DELTA delta13C(IA-DIC)/[CO3[2-]] slopes for G. inflata in the large size fraction (250-355 µm) of -0.013 per mil to 0.015 per mil (µmol/kg)**-1 and of -0.013 per mil to 0.017 per mil (µmol/kg)**-1 for the smaller specimens (150-250 µm). These slopes are in the range of those found for other non-symbiotic species, such as Globigerina bulloides, from laboratory culture experiments. Since the DELTA delta13C(IA-DIC)/[CO3[2-]] slopes from our field data are nearly identical to the slopes established from laboratory culture experiments we assume that the influence of other effects, such as temperature, are negligibly small. If we correct the delta13C values of G. inflata for a carbonate ion effect, the delta13C(shell) and delta13C(DIC) are correlated with an average offset of 2.11.

Stable isotope record of planktonic foraminifera from the western Iberian margin during marine isotope stage 2

The surface water hydrography along the western Iberian margin, as part of the North Atlantic's eastern boundary upwelling system, consists of a complex, seasonally variable system of equatorward and poleward surface and subsurface currents and seasonal upwelling. Not much information exists to ascertain if the modern current and productivity patterns subsisted under glacial climate conditions, such as during marine isotope stage (MIS) 2, and how North Atlantic meltwater events, especially Heinrich events, affected them. To help answer these questions we are combining stable isotope records of surface to subsurface dwelling planktonic foraminifer species with sea surface temperature and export productivity data for four cores distributed along the western and southwestern Iberian margin (MD95-2040, MD95-2041, MD99-2336, and MD99-2339). The records reveals that with the exception of the Heinrich events and Greenland Stadial (GS) 4 hydrographic conditions along the western Iberian margin were not much different from the present. During the Last Glacial Maximum (LGM), subtropical surface and subsurface waters penetrated poleward to at least 40.6°N (site MD95-2040). Export productivity was, in general, high on the western margin during the LGM and low in the central Gulf of Cadiz, in agreement with the modern situation. During the Heinrich events and GS 4, on the other hand, productivity was high in the Gulf of Cadiz and suppressed in the upwelling regions along the western margin where a strong halocline inhibited upwelling. Heinrich event 1 had the strongest impact on the hydrography and productivity off Iberia and was the only period when subarctic surface waters were recorded in the central Gulf of Cadiz. South of Lisbon (39°N), the impact of the other Heinrich events was diminished, and not all of them led to a significant cooling in the surface waters. Thus, climatic impacts of Heinrich events highly varied with latitude and the prevailing hydrographic conditions in this region.