Dissolved and dissolvable iron concentrations and ligand characteristics in samples taken during POLARSTERN expedition ARK-XXII/2 to the Arctic Ocean

The speciation of iron was investigated in three shelf seas and three deep basins of the Arctic Ocean in 2007. The dissolved fraction (<0.2 µm) and a fraction < 1000 kDa were considered here. In addition, unfiltered samples were analyzed. Between 74 and 83% of dissolved iron was present in the fraction < 1000 kDa at all stations and depth, except at the chlorophyll maximum (42-64%). Distinct trends in iron concentrations and ligand characteristics were observed from the shelf seas toward the central deep basins, with a decrease of total dissolvable iron ([TDFe] > 3 nM on the shelves and [TDFe] < 2 nM in the Makarov Basin). A relative enrichment of particulate Fe toward the bottom was revealed at all stations, indicating Fe export toward the deep ocean. In deep waters, dissolved ligands became less saturated with Fe (increase of [Excess L]/[Fe]) from the Nansen Basin via the Amundsen Basin toward the Makarov Basin. This trend was explained by the reactivity of the ligands, higher (log alpha > 13.5) in the Nansen and Amundsen basins than in the Makarov Basin (log alpha <13) where the sources of Fe and ligands were limited. The ligands became nearly saturated with depth in the Amundsen and Nansen Basins, favoring Fe removal in the deep ocean, whereas in the deep Makarov Basin, they became unsaturated with depth. Still here scavenging occurred. Although scavenging of Fe was attenuated by the presence of unsaturated organic ligands, their low reactivity in combination with a lack of sources of Fe in the Makarov Basin might be the reason of a net export of Fe to the sediment.

Geochemistry of basalts of the Indian Ocean

Indian Ocean crust formed at Sites 765 and 766 is geochemically comparable to that presently forming in the Red Sea. In both cases, we interpret the crust as reflecting high degrees of mantle melting that are associated with an enhanced thermal gradient below recently rifted continental lithosphere. Asthenospheric melts formed in this environment are rich in CaO and FeO, poor in Na2O and Al2O3, and characterized by depleted rare earth element (REE) profiles ([La/Sm]n approximately 0.5-0.6). Both the Red Sea basalts and the basalts at Sites 765 and 766 are distinct from those erupted at the present Mid-Indian Ocean Ridge. The isotope characteristics of the Site 765 basalts define a geochemical signature similar to that of the present-day Mid-Indian Ocean Ridge basalts (MIORB). The Indian Ocean mantle domain is distinct from that of the Atlantic and Pacific oceans, and this distinction has persisted since Jurassic time, when the Site 765 oceanic crust was formed.

(Table 1) Chlorophyll concentrations in the Southwest Indian Ocean

Results are examined of determinations of chlorophyll in seawater suspension by fluorescent and spectrophometric methods in the Southwest Indian Ocean near the African coast and in the Seychelles-Mauritius Plateau area in July-November 1977. During the study period near the African coast, the most productive regions, where the weighted average particulate chlorophyll concentration in the photic zone was greater than 0.5 µg/l, were off the Mozambique coast (near the mouth of the Zambezi River and in Delagoa Bay) and also off the coast of Tanzania, near the the Pemba and Zanzibar Islands. The most favorable conditions for growth of phytoplankton, i.e., a combination of distinct water stratification with intense upwelling, were observed in the equatorial divergence zone in the region of the Seychelles and Amirante Islands, where chlorophyll concentration in the layer of the maximum was as high as 3.4 µg/l. This region can be considered as one of the most productive regions of the Indian Ocean.

Sedimentology and gas hydrates of IODP Expedition 311 samples

Expedition 311 of the Integrated Ocean Drilling Program (IODP) to northern Cascadia recovered gas-hydrate bearing sediments along a SW-NE transect from the first ridge of the accretionary margin to the eastward limit of gas-hydrate stability. In this study we contrast the gas gas-hydrate distribution from two sites drilled ~ 8 km apart in different tectonic settings. At Site U1325, drilled on a depositional basin with nearly horizontal sedimentary sequences, the gas-hydrate distribution shows a trend of increasing saturation toward the base of gas-hydrate stability, consistent with several model simulations in the literature. Site U1326 was drilled on an uplifted ridge characterized by faulting, which has likely experienced some mass wasting events. Here the gas hydrate does not show a clear depth-distribution trend, the highest gas-hydrate saturation occurs well within the gas-hydrate stability zone at the shallow depth of ~ 49 mbsf. Sediments at both sites are characterized by abundant coarse-grained (sand) layers up to 23 cm in thickness, and are interspaced within fine-grained (clay and silty clay) detrital sediments. The gas-hydrate distribution is punctuated by localized depth intervals of high gas-hydrate saturation, which preferentially occur in the coarse-grained horizons and occupy up to 60% of the pore space at Site U1325 and > 80% at Site U1326. Detailed analyses of contiguous samples of different lithologies show that when enough methane is present, about 90% of the variance in gas-hydrate saturation can be explained by the sand (> 63 µm) content of the sediments. The variability in gas-hydrate occupancy of sandy horizons at Site U1326 reflects an insufficient methane supply to the sediment section between 190 and 245 mbsf.

Middle and late Miocene calcareous nannofossil biostratigraphy from equatorial Indian and Pacific Oceans

Selected calcareous nannofossils were investigated by means of quantitative methods in middle and upper Miocene sediments from the tropical Indian Ocean (ODP Leg 115) and equatorial Pacific Ocean (DSDP Leg 85, ODP Legs 130 and 138). Our goal was to test the reliability of the classic biohorizons used in the standard zonations of Martini (1971) and Bukry (1973) and, possibly, to improve biostratigraphic resolution in the Miocene. In a time interval of about 8 m.y., from the last occurrence (LO) of S. heteromorphus (~13.6 Ma) to the LO of D. quinqueramus (~5.5 Ma), a total 37 events were investigated, using both the conventional and some additional markers proposed in the literature. At least 17 of these events proved to be distinct biostratigraphic correlation lines between the two considered areas. This integrated biostratigraphic framework increases the biostratigraphic resolution in the middle-upper Miocene interval (of the order of about 0.5 m.y). All the investigated events were tied to the geomagnetic polarity time scale (GPTS) and compared to biomagnetostratigraphy from mid-latitude North Atlantic Site 94-608 (Olafsson, 1991; Gartner, 1992), thus obtaining further information about the biostratigraphic and biochronologic reliability of the investigated events and a significant improvement of the available nannofossil biomagnetostratigraphic model for the middle and late Miocene.

Paleomagnetic and rock magnetic properties of IODP Expedition 318 cores

The Integrated Ocean Drilling Program Expedition 318 to the Wilkes Land margin of Antarctica recovered a sedimentary succession ranging in age from lower Eocene to the Holocene. Excellent stratigraphic control is key to understanding the timing of paleoceanographic events through critical climate intervals. Drill sites recovered the lower and middle Eocene, nearly the entire Oligocene, the Miocene from about 17 Ma, the entire Pliocene and much of the Pleistocene. The paleomagnetic properties are generally suitable for magnetostratigraphic interpretation, with well-behaved demagnetization diagrams, uniform distribution of declinations, and a clear separation into two inclination modes. Although the sequences were discontinuously recovered with many gaps due to coring, and there are hiatuses from sedimentary and tectonic processes, the magnetostratigraphic patterns are in general readily interpretable. Our interpretations are integrated with the diatom, radiolarian, calcareous nannofossils and dinoflagellate cyst (dinocyst) biostratigraphy. The magnetostratigraphy significantly improves the resolution of the chronostratigraphy, particularly in intervals with poor biostratigraphic control. However, Southern Ocean records with reliable magnetostratigraphies are notably scarce, and the data reported here provide an opportunity for improved calibration of the biostratigraphic records. In particular, we provide a rare magnetostratigraphic calibration for dinocyst biostratigraphy in the Paleogene and a substantially improved diatom calibration for the Pliocene. This paper presents the stratigraphic framework for future paleoceanographic proxy records which are being developed for the Wilkes Land margin cores. It further provides tight constraints on the duration of regional hiatuses inferred from seismic surveys of the region.

Maastrichtian calcareous nannofossils of the Indian Ocean and Shatsky Rise

The biotic effects of volcanism have long been the unknown factors in creating biotic stress, and the contribution of the Deccan volcanism to the K-T mass extinction remains largely unknown. Detailed studies of the volcanic-rich sediments of Indian Ocean Ninetyeast Ridge Sites 216 and 217 and Wharton Basin Site 212 reveal that the biotic effects of late Maastrichtian volcanism on planktic foraminifera and calcareous nannofossils are locally as severe as those of the K-T mass extinction. The biotic expressions of these high stress environments are characterized by the Lilliput effect, which includes reduced diversity by eliminating most K-strategy species, and reduction in specimen size (dwarfing), frequently to less than half their normal adult size of both r-strategy and surviving K-strategy species. In planktic foraminifera, the most extreme biotic stress results are nearly monospecific assemblages dominated by the disaster opportunist Guembelitria, similar to the aftermath of the K-T mass extinction. The first stage of improving environmental conditions results in dominance of dwarfed low oxygen tolerant Heterohelix species and the presence of a few small r-strategy species (Hedbergella, Globigerinelloides). Calcareous nannofossil assemblages show similar biotic stress signals with the dominance of Micula decussata, the disaster opportunist, and size reduction in the mean length of subordinate r-strategy species particularly in Arkhangelskiella cymbiformis and Watznaueria barnesiae. These impoverished and dwarfed late Maastrichtian assemblages appear to be the direct consequences of mantle plume volcanism and associated environmental changes, including high nutrient influx leading to eutrophic and mesotrophic waters, low oxygen in the water column and decreased watermass stratification.

At surface behaviour, dive depth and dive duration and associated hydrographic data of adult male southern elephant seals from King George Island from expedition JUB2010 with links to datasets

Understanding the distribution and foraging ecology of major consumers within pelagic systems, specifically in relation to physical parameters, can be important for the management of bentho-pelagic systems undergoing rapid change associated with global climate change and other anthropogenic disturbances such as fishing (i.e., the Antarctic Peninsula and Scotia Sea). We tracked 11 adult male southern elephant seals (Mirounga leonina), during their five-month post-moult foraging migrations from King George Island (Isla 25 de Mayo), northern Antarctic Peninsula, using tags capable of recording and transmitting behavioural data and in situ temperature and salinity data. Seals foraged mostly within the Weddell-Scotia Confluence, while a few foraged along the western Antarctic Peninsula shelf of the Bellingshausen Sea. Mixed model outputs suggest that the at-sea behaviour of seals was associated with a number of environmental parameters, especially seafloor depth, sea-ice concentrations and the temperature structure of the water column. Seals increased dive bottom times and travelled at slower speeds in shallower areas and areas with increased sea-ice concentrations. Changes in dive depth and durations, as well as relative amount of time spent during the bottom phases of dives, were observed in relation to differences in overall temperature gradient, likely as a response to vertical changes in prey distribution associated with temperature stratification in the water column. Our results illustrate the likely complex influences of bathymetry, hydrography and sea ice on the behaviour of male southern elephant seals in a changing environment and highlight the need for region-specific approaches to studying environmental influences on behaviour.