Stable isotope ratios and organic carbon accumulation rates of late Pleistocene sediments of ODP Hole 117-724C

Stable isotope records of coexisting benthic foraminifers Uvigerina spp. and Cibicidoides spp. and planktonic G. ruber (white variety) from Site 724 are used to study the late Pleistocene evolution of surface and intermediate water hydrography (593 m water depth) at the Oman Margin. Glacial-interglacial d18O amplitudes recorded by the benthic foraminifers are reduced when compared to the estimated mean ocean changes of d18Oseawater . Epibenthic d13C remains at its modern level or is increased during glacial times. This implies that Red Sea outflow waters which are enriched in d18Oseawater and d13C (Sum CO2) have been replaced during glacial periods by intermediate waters still positive in d13C (Sum CO2) but more negative in d18Oseawater. Glacial-interglacial amplitudes of the planktonic d18O record exceed those of the mean ocean d18Oseawater variation and imply decreased surface water temperatures (SST) during glacial times. Throughout most of the records these cooling events correlate with enhanced rates of carbon accumulation. However, both negative (colder) SST and positive Corg accumulation rate anomalies do not correlate with potential physical upwelling maxima as inferred from the orbital monsoon index. This is in conflict with the established hypothesis that upwelling in the estern Arabia Sea should be strongest during maxima of the southwest monsoon.

Ice rafte debris of ODP Hole 178-1101A

Sediment drifts on the continental rise west of the Antarctic Peninsula received fine-grained sediment and ice-rafted debris (IRD) directly from the continental shelf and thus indirectly record the history of West Antarctic glaciation. Site 1101 contains a 218-m-thick, nearly continuous section extending from the late Pliocene to the Holocene. To assess the presence of calving glaciers at sea level in the Antarctic Peninsula region, the mass accumulation rate (MAR) of IRD was calculated using the weight percent terrigenous sand fraction (250 µm to 2 mm). IRD MAR is cyclic throughout, with small peaks alternating with periods of low or no IRD. Many cycles have a sawtooth pattern that increases gradually to the peak then abruptly decreases to zero. This pattern is consistent with rapid disintegration of ice streams and release of icebergs from the continental shelf. Three unusually large peaks (three to five times the size of other peaks) occurred at approximately 2.8, 1.9, and 0.88 Ma and indicate periods of intense ice rafting. Lithofacies were described in detail using X-radiographs and core descriptions for the interval from 1.34 to 0.54 Ma. Glacial units are represented by thickly laminated mud deposited by distal turbidites and meltwater plumes. Less commonly, thinly laminated sediment formed by contour currents and diamicton by intense ice rafting. Interglacials are represented by foraminifer-bearing mud with IRD. Ice rafting appears to have increased in the later part of the glacial period and remained high in the interglacial period.

Eolian records from sediment core RC27-61 in the Arabian Sea

The modern Indian Ocean summer monsoon is driven by differential heating between the Asian continent and the Indian Ocean to the south. This differential heating produces a strong pressure gradient which drives southwest monsoon winds during June, July, and August. Satellite and meteorological observations, aerosol measurements, sediment trap studies, and mineralogical studies indicate an atmospheric mode of transport for modern lithogenic sediments in the northwest Arabian Sea. Analyses of lithogenic grain size and mass accumulation rate (MAR) records from the Owen Ridge indicate that eolian transport has been the primary mode of transport for the past 370 kyr. Visual inspection shows that the MAR record is positively correlated with global ice volume as indicated by the marine delta18O record. In contrast, the grain-size record varies at a much higher frequency, showing little correlation to either the MAR or the delta18O records. Spectral analyses confirm these relationships, indicating that the lithogenic grain-size and MAR records are coherent only over the precession band whereby the grain size leads the MAR by 124° (~8 kyr). We conclude that an eolian transport mechanism is the only mechanism that allows for this phase difference and at the same time is supported by comparison of the grain size and MAR with independent eolian records. We use lithogenic grain size as a paleoclimatic indicator of summer monsoon wind strength and lithogenic MAR as a paleoclimatic indicator of source-area aridity. These interpretations are supported by comparison of the lithogenic records to independent indicators of wind strength (Globigerina bulloides upwelling record) and aridity (a loess record from central China). Such comparisons indicate high coherence and zero phase relationships. Our work supports the findings of previous studies which have documented the link between monsoon strength and the Earth's axial precession cycles. Both the lithogenic MAR and the grain-size records have high coherency with precessional insolation. Maximum lithogenic MAR (source-area aridity) is in phase with delta18O (global ice volume) and leads maximum precessional insolation by 88° (~6 kyr). We attribute this lead to the influence of glacial conditions on the aridity, and therefore the deflation potential, of the source areas. Maximum lithogenic grain size (summer monsoon wind strength) lags maximum precession by 148° (~9 kyr). We attribute this lag both to the influence of global and/or local ice volume and to the availability of latent heat from the southern hemisphere Indian Ocean, the two of which combine to determine the strength of the Indian Ocean monsoon.

210Pb dates, radiocarbon ages and sedimentation and accumulation rates of sediment cores JM99-1198 and MD99-2297

The magnitude of Late Holocene climatic variations are less significant than those that took place during ice ages and deglaciations. However, detailed knowledge about this period is vital in order to understand and model future climate scenarios both as a result of natural climate variation and the effects of global warming. Oceanic heat flux is important for the sensitive climate regime of northern Europe. Our aim is to connect hydrographical changes, reflected by the dinoflagellates cyst (dinocysts) assemblages in the sediments in the Malangen fjord, to local and regional climatic phases. Previous studies have shown that dinocyst assemblages are influenced by temperature, salinity, and the availability of nutrients (e.g. de Vernal et al. 2005, doi:10.1016/j.quascirev.2004.06.014; de Vernal et al. 2001, doi:10.1002/jqs.659; Grosfjeld et al. this volume; Rochon et al. 2008, doi:10.1016/j.marmicro.2008.04.001; Solignac et al. this volume). Dinoflagellates are mostly unicellular organisms that make up one of the main groups of phytoplankton. They are able to regulate their depth within the photic zone and to concentrate along oceanic fronts, which provide nutrient-enriched waters. The dinoflagellate cysts are the hypnozygotes of dinoflagellates naturally produced during the life cycle. Their wall is composed of a highly resistant organic material, which has a high potential to fossilize. Because dinocysts species are linked to particular abiotic and biotic parameters, the dinocyst assemblages provide information about past surface water conditions. Since each fjord has its own hydrographic setting, it is necessary to establish a firm link between the dinocyst composition of the sediment surface samples and the surface water conditions. Indeed the modern dinocyst distribution in subarctic fjords is little known. Thus, in addition to detailing dinocyst results from two shallow cores, several sediment surface samples located along a transect running from the head to the mouth of the fjord, and extending onto the shelf, are also presented.

Nitrogen isotope variations along the northeast Pacific margin

Glacial-interglacial changes in sedimentary d15N over the last 120 kyr display a remarkably similar pattern in timing and amplitude in core records extending from the denitrification zone in the eastern tropical North Pacific (ETNP), where subsurface denitrification is active, to the Oregon margin, where no denitrification occurs today. Low d15N values (4-6 per mil) generally characterize glacial stages 2 and 4, and higher d15N values (7-10 per mil) are representative of the Holocene, millennial-scale periods within stage 3, and stage 5. The inferred synchroneity of d15N variations along the entire margin implies that the nitrate isotopic signal produced in the oxygen-poor subsurface waters in the ETNP is rapidly advected northward and recorded at sites far beyond the boundaries of the modern denitrification zone. Similar to d15N, primary production indicators (percent Corg, Ba/Al, and percent opal) show glacial-interglacial as well as millennial-scale variations along the NE Pacific margin, with higher primary production during warm periods. However, the relative phasing between d15N and paleoproduction tracers within individual records changes latitudinally. Whereas d15N and primary production vary approximately synchronously in the midlatitudes, production lags d15N in the ETNP by several kiloyears. This lag calls for a new understanding of the processes driving denitrification in the ETNP. We suggest that oxygen input by the Equatorial Undercurrent as well as local organic matter flux controls denitrification rates in the ETNP. Moreover, the differences in relative timing point to a time-transgressive development of upwelling-favorable winds along the NE Pacific margin after the last glaciation, with those in the north developing several kiloyears earlier.

Clay mineralogical assemblages, Sm-Nd concentrations, Sm and Nd isotopic ratios and oxygen isotope ratios, OIS number and the age model of ODP Site 105-646

We present 40 Sm-Nd isotope measurements of the clay-size (<2 µm) fractions of sediments from the Southern Greenland rise (ODP-646) that span the last 365 kyr. These data track changes in the relative supply of fine particles carried into the deep Labrador Sea by the Western Boundary Under Current (WBUC) back to the fourth glacial-interglacial cycles. Earlier studies revealed three general sources of particles to the core site: (i) Precambrian crustal material from Canada, Greenland, and/or Scandinavia (North American Shield - NAS), (ii) Palaeozoic or younger crustal material from East Greenland, NW Europe, and/or western Scandinavia (Young Crust - YC) and (iii) volcanic material from Iceland and the Mid-Atlantic Ridge (MAR). Clay-size fractions from glacial sediments have the lowest Nd isotopic ratios. Supplies of young crustal particles were similar during glacial oxygen isotope stages (OIS) 2, 6, and 10. In contrast the mean volcanic contributions decreased relative to old craton material from OIS 10 to OIS 6 and then from OIS 6 to OIS 2. The glacial OIS 8 interval displays a mean Sm/Nd ratio similar to those of interglacials OIS 1, 5, and 9. Compared with other interglacials, OIS 7 was marked by a higher YC contribution but a similar ~30% MAR supply. The overall NAS contribution dropped by a factor of 2 during each glacial/interglacial transition, with the MAR contribution broadly replacing it during interglacials. To decipher between higher supplies and/or dilution, particle fluxes from each end member were estimated. Glacial NAS fluxes were systematically higher than interglacial fluxes. During the time interval examined, fine particle supplies to the Labrador Sea were strongly controlled by proximal ice-margin erosion and thus echoed the glacial stage intensity. In contrast, the WBUC-carried MAR supplies from the eastern basins did not change significantly throughout the last 365 kyr, except for a marked increase in surface-sediments that suggests unique modern conditions. Distal WBUC-controlled inputs from the Northern and NE North Atlantic seem to have been less variable than proximal supplies linked with glacial erosion rate.

Grain size analysis and sedimentation rates of ODP Hole 175-1085A off the Namibian coast

Sediments from the ODP Site 1085A were studied to investigate the impacts of global cooling in the Middle and Late Miocene on the climate in Southwestern Africa. The size composition of the sediment was analysed emphasising the silt fraction. A comparison with the modern grain size distribution and suitable transport processes made it possible to assign specific transport processes to the grain size composition. Three processes are considered for transport of terrigeneous silt: while there was no evidence found for (1) transport by ocean currents, the analyses showed signals of (2) wind transport indicating dry conditions associated with a cool climate and (3) fluvial transport that points to humid and warm conditions. Three climatic phases were defined. The first phase from 13.8 to 11.8 Myr reveals a stable humid climate in Southwest Africa independent of the Antarctic glaciations. During the second phase from 11.8 to 10.4 Myr the regional climate cooled considerably but was not drier. Additionally, the climate during this phase reacted to the Antarctic glaciations. This cooling-trend continued during phase 3 from 10.4 to 9.0 Myr with a significant increase in dust input, pointing to overall drier conditions. However, fluvial transport still remained as the main source.

Sedimentation in the vicinity of Leg 92 Drill Sites: Studies of site survey cores

Surveys of the areas surrounding the sites drilled on the Leg 92 19°S transect showed that sedimentation at all except the oldest site is dominated by calcium carbonate deposition. The sediments in the area of the oldest site, west of the Austral Fracture Zone, are being deposited beneath the calcium carbonate compensation depth and are dominated by terrigenous and metal-rich hydrogenous and hydrothermal sediments. The noncarbonate sediments in all of the areas east of the Austral Fracture Zone are dominated by hydrothermal sediment similar in composition to that presently being deposited at the East Pacific Rise. Although no biogenic microfossils were present in smear slides of the sediment, geochemical partitioning suggests that a remnant signal of siliceous biogenic deposition may be preserved, especially in gravity core (GC) 8, which was collected from a high heat flow zone near Site 600. The siliceous sediment may also result from the deposition of amorphous hydrothermal silica from the higher concentrations of pore water SiO2 characteristic of the upwelling waters. Sedimentation on the broad plateaus that characterize each area is quite uniform and suggests that sites on these plateaus will be broadly representative of pelagic sedimentation in the area.

Abrupt vegetation change after the Late Quaternary megafaunal extinction in southeastern Australia

A substantial extinction of megafauna occurred in Australia between 50 and 45 kyr ago, a period that coincides with human colonization of Australia. Large shifts in vegetation also occurred around this time, but it is unclear whether the vegetation changes were driven by the human use of fire-and thus contributed to the extinction event-or were a consequence of the loss of megafaunal grazers. Here we reconstruct past vegetation changes in southeastern Australia using the stable carbon isotopic composition of higher plant wax n-alkanes and levels of biomass burning from the accumulation rates of the biomarker levoglucosan from a well-dated sediment core offshore from the Murray-Darling Basin. We find that from 58 to 44 kyr ago, the abundance of plants with the C-4 carbon fixation pathway was generally high-between 60 and 70%. By 43 kyr ago, the abundance of C-4 plants dropped to 30% and biomass burning increased. This transient shift lasted for about 3,000 years and came after the period of human arrival and directly followed megafauna extinction at 48.9-43.6 kyr ago. We conclude that the vegetation shift was not the cause of the megafaunal extinction in this region. Instead, our data are consistent with the hypothesis that vegetation change was the consequence of the extinction of large browsers and led to the build-up of fire-prone vegetation in the Australian landscape.

Late Cenozoic carbonate accumulation rates of ODP Leg 115 samples

The principal paleoceanographic objective of Ocean Drilling Program Leg 115 was to collect a suite of materials that would allow reconstruction of the dynamic features of the late Cenozoic carbonate system in the equatorial Indian Ocean. This goal was achieved with the recovery of sediments from a closely spaced depth transect (1541-4428 m) of five sites (Sites 707 through 711) from on and around the Mascarene Plateau that record the last 50 m.y. of pelagic deposition. More than 2200 measurements of carbonate content are combined here with a highly resolved bio- and magnetostratigraphy to produce the first detailed compilation of bulk, carbonate, and noncarbonate mass accumulation rates (MARs) from the Indian Ocean. These results allow us to recognize three major depositional intervals, each characterized by a distinct depth-dependent pattern of carbonate accumulation: (1) the Paleogene, a time of moderate accumulation rates (0.4-0.7 g/cm**2/1000 yr) and reduced between-site accumulation differences; (2) the early and middle Miocene, a period characterized by greatly reduced carbonate MARs (typically <0.2 g/cm**2/1000 yr) at all sites and a shallow carbonate compensation depth; and (3) the late Miocene to Holocene, a time span marked by the highest bulk and carbonate accumulation rates of the last 50 Ma (1.6-1.8 g/cm**2/1000 yr), and the first appearance of substantial contrasts in carbonate accumulation as a function of the water depth of the drill site. The fundamentally different character of the carbonate system during each of these intervals must represent a regional response to the complex evolution of late Cenozoic oceans and climate.

Geochemistry and foraminiferal stable isotoe record of sediment core SCS90-36

Changes in the Southeast Asia monsoon winds and surface circulation patterns since the last glaciation are inferred using multiple paleoceanographic indicators including planktic foraminifer faunal abundances, fauna and alkenones sea-surface temperature (SST) estimates, oxygen and carbon isotopes of planktic and benthic foraminifers, and sedimentary fluxes of carbonates and organic carbon obtained from deep-sea core SCS90-36 from the South China Sea (SCS) (17°59.70'N, 111°29.64'E at water depth 2050 m). All these paleoceanographic evidences indicate marked changes in the SCS ocean system over the last glacial toward the Holocene. Planktic foraminiferal faunal SST estimates show stable warm-season SST of 28.6°C, close to the modern value, throughout the glacial-interglacial cycle. In contrast, cold-season SST increases gradually from 23.6°C in the last glacial to a mean value of 26.4°C in the Holocene with a fluctuation of about 3°C during 13-16 ka. SST estimates by UK'37 method reveal less variability and are in average 1-3°C lower than the fauna-derived winter-season SST. These patterns reveal that the seasonality of the SST is not only higher by about 3-4°C in the glacial, but also a function of the winter season SST. Sedimentation rates decrease from the last glacial-deglacial stage to the Holocene due to a reduction in supply of terrigenous components, which led to an increase of carbonate contents. Total organic carbon (TOC) contents of primarily marine sources decrease from the last glacial-deglacial to the Holocene. The last deglaciation is also characterized by high surface productivity as indicated by increased ketones abundances and high mass accumulation rates (MAR) of the TOC and carbonates. The gradient of planktic foraminifer ocygen and carbon isotopes of between surface dwellers and deep dwellers increases significantly toward Termination I and Holocene, and is indiscernibly small in the carbon isotope gradient of between 14 and 24 ka, revealing a deep-mixing condition in surface layers prior to 10 ka. The glacial-interglacial fluctuation of the carbon isotope value of a benthic foraminifer is 0.61%. which is significantly larger than a global mean value. The large carbon isotope fluctuation indicates an amplification of marginal-sea effects which is most likely resulted from an increase in surface productivity in the northern SCS during the last glacial-deglacial stage. The multiple proxies consistently indicate that the last glacial-deglacial stage winter monsoon in the Southeast Asia was probably strengthened in the northern SCS, leading to a development of deep-mixing surface layer conditions and a more efficient nutrient cycling which supports more marine organic carbon production.

Concentrations and accumulation rates of platinum-group elements and rhenium in Pacific and Atlantic sediments, DSDP and ODP data

The nature of Re-platinum-group element (PGE; Pt, Pd, Ir, Os, Ru) transport in the marine environment was investigated by means of marine sediments at and across the Cretaceous-Tertiary boundary (KTB) at two hemipelagic sites in Europe and two pelagic sites in the North and South Pacific. A traverse across the KTB in the South Pacific pelagic clay core found elevated levels of Re, Pt, Ir, Os, and Ru, each of which is approximately symmetrically distributed over a distance of ~1.8 m across the KTB. The Re-PGE abundance patterns are fractionated from chondritic relative abundances: Ru, Pt, Pd, and Re contents are slightly subchondritic relative to Ir, and Os is depleted by ~95% relative to chondritic Ir proportions. A similar depletion in Os (~90%) was found in a sample of the pelagic KTB in the North Pacific, but it is enriched in Ru, Pt, Pd, and Re relative to Ir. The two hemipelagic KTB clays have near-chondritic abundance patterns. The ~1.8-m-wide Re-PGE peak in the pelagic South Pacific section cannot be reconciled with the fallout of a single impactor, indicating that postdepositional redistribution has occurred. The elemental profiles appear to fit diffusion profiles, although bioturbation could have also played a role. If diffusion had occurred over ~65 Ma, the effective diffusivities are ~10**?13 cm**2/s, much smaller than that of soluble cations in pore waters (~10**?6 cm**2/s). The coupling of Re and the PGEs during redistribution indicates that postdepositional processes did not significantly fractionate their relative abundances. If redistribution was caused by diffusion, then the effective diffusivities are the same. Fractionation of Os from Ir during the KTB interval must therefore have occurred during aqueous transport in the marine environment. Distinctly subchondritic Os/Ir ratios throughout the Cenozoic in the South Pacific core further suggest that fractionation of Os from Ir in the marine environment is a general process throughout geologic time because most of the inputs of Os and Ir into the ocean have Os/Ir ratios >/=1. Mass balance calculations show that Os and Re burial fluxes in pelagic sediments account for only a small fraction of the riverine Os (<10%) and Re (<0.1%) inputs into the oceans. In contrast, burial of Ir in pelagic sediments is similar to the riverine Ir input, indicating that pelagic sediments are a much larger repository for Ir than for Os and Re. If all of the missing Os and Re is assumed to reside in anoxic sediments in oceanic margins, the calculated burial fluxes in anoxic sediments are similar to observed burial fluxes. However, putting all of the missing Os and Re into estuarine sediments would require high concentrations to balance the riverine input and would also fail to explain the depletion of Os at pelagic KTB sites, where at most ~25% of the K-T impactor's Os could have passed through estuaries. If Os is preferentially sequestered in anoxic marine environments, it follows that the Os/Ir ratio of pelagic sediments should be sensitive to changes in the rates of anoxic sediment deposition. There is thus a clear fractionation of Os and Re from Ir in precipitation out of sea water in pelagic sections. Accordingly, it is inferred here that Re and Os are removed from sea water in anoxic marine depositional regimes.

Cenozoic record of continental mineral deposit on Broken and Ninetyeast Ridges, Indian Ocean

The mineral component of pelagic sediments recovered from the Indian Ocean provides both a history of eolian deposition related to climatic changes in southern Africa and a record of terrigenous input related to sediment delivery from the Himalayas. A composite Cenozoic dust flux record from four sites in the central Indian Ocean is used to define the evolution of the Kalahari and Namib desert source regions. The overall record of dust input is one of very low flux for much of the Cenozoic indicating a long history of climate stability and regional hyperaridity. The most significant reduction in dust flux occurred near the Paleocene/Eocene boundary and is interpreted as a shift from semiarid climates during the Paleocene to more arid conditions in the early Eocene. Further aridification is recorded as stepwise reductions in the input of dust material which occur from about 35 to 40 Ma, 27 to 32 Ma, and 13 to 15 Ma and correlate to significant enrichments in benthic foraminifer delta18O values. The mineral flux in sediments from the northern Indian Ocean, site 758, records changes in the terrigenous input apparently related to the erosion of the Himalayas and indicates a rapid late Cenozoic uplift history. Three major pulses of increased terrigeneous sediment flux are inferred from the depositional record. The initial increase began at about 9.5 Ma and continued for roughly 1.0 million years. A second pulse with approximately the same magnitude occurred from about 7.0 to 5.6 Ma. The largest pulse of enhanced terrigenous influx occurred during the Pliocene from about 3.9 to 2.0 Ma when average flux values were severalfold greater than at any other time in the Cenozoic.

Late Quaternary siliciclastic/carbonate sedimentation in the Cabricorn Channel

A model is presented for hemipelagic siliciclastic and carbonate sedimentation during the last glacial-interglacial cycle in the Capricorn Channel, southern Great Barrier Reef (GBR). Stable isotope ratios, grainsize, carbonate content and mineralogy were analysed for seven cores in a depth transect from 166 to 2892 m below sea level (mbsl). Results show variations in the flux of terrigenous, neritic and pelagic sediments to the continental slope over the last sea level cycle. During the glacial lowstand terrigenous sediment influenced all the cores down to 2000 mbsl. The percentages of quartz and feldspar in the cores decreased with water depth, while the percentage of clay increased. X-ray diffraction analysis of the glacial lowstand clay mineralogy suggests that the siliciclastic sediment was primarily sourced from the Fitzroy River, which debouched directly into the northwest sector of the Capricorn Channel at this time. The cores also show a decrease in pelagic calcite and an increase in aragonite and high magnesium calcite (HMC) during the glacial. The influx of HMC and aragonite is most likely from reworking of coral reefs exposed on the continental shelf during the glacial, and also from HMC ooids precipitated at the head of the Capricorn Channel at this time. Mass accumulation rates (MARs) are high (13.5 g/cm**/kyr) during the glacial and peak at ~20 g/cm** 3/kyr in the early transgression (16-14 ka BP). MARs then decline with further sea level rise as the Fitzroy River mouth retreats from the edge of the continental shelf after 13.5 ka BP. MARs remain low (4 g/cm**3/kyr) throughout the Holocene highstand. Data for the Holocene highstand indicate there is a reduction in siliciclastic influx to the Capricorn Channel with little quartz and feldspar below 350 mbsl. However, fine-grained fluvial sediments, presumably from the Fitzroy River, were still accumulating on the mid slope down to 2000 mbsl. The proportion of pelagic calcite in the core tops increases with water depth, while HMC decreases, and is present only in trace amounts in cores below 1500 mbsl. The difference in the percentage of HMC in the deeper cores between the glacial and Holocene may reflect differences in supply or deepening of the HMC lysocline during the glacial. Sediment accumulation rates also vary between cores in the Capricorn Channel and do not show the expected exponential decrease with depth. This may be due to intermediate or deep water currents reworking the sediments. It is also possible that present bathymetry data are too sparse to detect the potential role that submarine channels may play in the distribution and accumulation of sediments. Comparison of the Capricorn Channel MARs with those for other mixed carbonate/siliciclastic provinces from the northeast margin of Australia indicates that peak MARs in the early transgression in the Capricorn Channel precede those from the central GBR and south of Fraser Island. The difference in the timing of the carbonate and siliciclastic MAR peaks along the northeast margin is primarily related to differences in the physiography and climate of the provinces. The only common trend in the MARs from the northeast margin of Australia is the near synchronicity of the carbonate and siliciclastic MAR peaks in individual sediment cores, which supports a coeval sedimentation model.

Accumulation and composition of terrigenous material on Ceara rise over the past 55 Ma

Ceara Rise, located east the Amazon River mouth, is covered with a thick blanket of pelagic carbonate and hemipelagic terrigenous sediment. The terrigenous component has been extracted from 57 bulk sediment samples at Ocean Drilling Program (ODP) Sites 925 and 929 on Ceara Rise to obtain a Cenozoic record of riverine discharge from northern South America. From the early Eocene to early Miocene (55-20 Ma), terrigenous accumulation was dominated by moderate amounts of generally large-grained, gray to green sediment especially depleted in elements that are enriched in post-Archaean shale (e.g. Cs, Th, Yb). However, pulsed inputs of relatively small-grained, gray to green terrigenous sediment less depleted in the above elements occurred in the late Eocene and Oligocene. The accumulation of terrigenous sediment decreased significantly until 16.5 Ma. In the middle Miocene (16.5-13 Ma), terrigenous accumulation was dominated by small amounts of small-grained, tan sediment notably depleted in Na and heavy rare earth elements. The accumulation rate of terrigenous sediment increased markedly from the latest Miocene (10 Ma) to the present day, a change characterized by deposition of gray-green sediment enriched in elements that are enriched in post-Archaean shale. Observed changes in terrigenous sediment at Ceara Rise record tectonism and erosion in northern South America. The Brazil and Guyana shields supplied sediment to the eastern South American margin until the middle Miocene (20-16.5 Ma) when a period of thrusting, shortening and uplift changed the source region, probably first to highly weathered and proximal Phanerozoic sediments. By the late Miocene (9 Ma), there was a transcontinental connection between the Andes and eastern South America. Weathering products derived from the Andes have increasingly dominated terrigenous deposition at Ceara Rise since the Late Miocene and especially since the late Pliocene.