Sedimentology and stable carbon and oxygen isotope record of the Central Arctic

Stable oxygen and carbon isotope and sedimentological-paleontological investigations supported by accelerator mass spectrometry 14C datings were carried out on cores from north of 85°N in the eastern central Arctic Ocean. Significant changes in accumulation rates, provenance of ice-rafted debris (IRD), and planktic productivity over the past 80,000 years are documented. During peak glacials, i.e., oxygen isotope stages 4 and 2, the Arctic Ocean was covered by sea ice with decreased seasonal variation, limiting planktic productivity and bulk sedimentation rates. In early stage 3 and during Termination I, major deglaciations of the circum-Arctic regions caused lowered salinities and poor oxygenation of central Arctic surface waters. A meltwater spike and an associated IRD peak dated to ~14-12 14C ka can be traced over the southern Eurasian Basin of the Arctic Ocean. This event was associated with the early and rapid deglaciation of the marine-based Barents Sea Ice Sheet. A separate Termination Ib meltwater event is most conspicuous in the central Arctic and is associated with characteristic dolomitic carbonate IRD. This lithology suggests an origin of glacial ice from northern Canada and northern Greenland where lower Paleozoic platform carbonates crop extensively out.

Age determinations, biomarker analyses, and accumulation rates of three sediment cores from the Fram Strait

A reconstruction of Holocene sea ice conditions in the Fram Strait provides insight into the palaeoenvironmental and palaeoceanographic development of this climate sensitive area during the past 8,500 years BP. Organic geochemical analyses of sediment cores from eastern and western Fram Strait enable the identification of variations in the ice coverage that can be linked to changes in the oceanic (and atmospheric) circulation system. By means of the sea ice proxy IP25, phytoplankton derived biomarkers and ice rafted detritus (IRD) increasing sea ice occurrences are traced along the western continental margin of Spitsbergen throughout the Holocene, which supports previous palaeoenvironmental reconstructions that document a general cooling. A further significant ice advance during the Neoglacial is accompanied by distinct sea ice fluctuations, which point to short-term perturbations in either the Atlantic Water advection or Arctic Water outflow at this site. At the continental shelf of East Greenland, the general Holocene cooling, however, seems to be less pronounced and sea ice conditions remained rather stable. Here, a major Neoglacial increase in sea ice coverage did not occur before 1,000 years BP. Phytoplankton-IP25 indices ("PIP25-Index") are used for more explicit sea ice estimates and display a Mid Holocene shift from a minor sea ice coverage to stable ice margin conditions in eastern Fram Strait, while the inner East Greenland shelf experienced less severe to marginal sea ice occurrences throughout the entire Holocene.

AMS 14C and calibrated ages of sediment core GeoB10426-1

Newly acquired bathymetric and seismic reflection data have revealed mass-transport deposits (MTDs) on the northeastern Cretan margin in the active Hellenic subduction zone. These include a stack of two submarine landslides within the Malia Basin with a total volume of approximately 4.6 km**3 covering an area of about 135 km**2. These two MTDs have different geometry, internal deformations and transport structures. The older and stratigraphic lower MTD is interpreted as a debrite that fills a large part of the Malia Basin, while the second, younger MTD, with an age of at least 12.6 cal. ka B.P., indicate a thick, lens-shaped, partially translational landslide. This MTD comprises multiple slide masses with internal structure varying from highly deformed to nearly undeformed. The reconstructed source area of the older MTD is located in the westernmost Malia Basin. The source area of the younger MTD is identified in multiple headwalls at the slope-basin-transition in 450 m water depth. Numerous faults with an orientation almost parallel to the southwest-northeast-trending basin axis occur along the northern and southern boundaries of the Malia Basin and have caused a partial steepening of the slope-basin-transition. The possible triggers for slope failure and mass-wasting include (i) seismicity and (ii) movement of the uplifting island of Crete from neotectonics of the Hellenic subduction zone, and (iii) slip of clay-mineral-rich or ash-bearing layers during fluid involvement.

A high-resolution sedimentology and age determination of core PS2185 from the central Arctic Ocean

A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets.

Age determinations and stable isotope records of four sediment profiles off Nova Scotia

Continental margin sediments off Nova Scotia accumulate at high rates (up to 360 cm/kyr) and contain a history of millennial-scale environmental changes which are dominated by the proximity of the Laurentide ice sheet during the latest Quaternary. Using stable isotope ratios of oxygen, accelerator mass spectrometer radiocarbon dating, micropaleontology, and sedimentology, we document these changes in six piston cores ranging in water depth from ab. 450 to ab. 4300 m. We find that maximum d18O in N. pachyderma occurred about 15 ka and preceded the maximum abundance of this species in these cores by ab. 1000 years. Between 13 and 14 ka we find a second peak in abundance of N. pachyderma, minimum d18O, and two pulses of ice rafting. The sediment lithology supports terrestrial studies which indicate that there was a general withdrawal of ice beyond the upper Paleozoic and Mesozoic red beds by 14 ka in southeastern Canada, so the ice rafting events between 13 and 14 ka probably reflect ice stream activity in the St. Lawrence valley. The Younger Dryas event is recognized as a peak in abundance of N. pachyderma and ice rafting (dated as ab. 11.3 ka), but meltwater discharge to the Gulf of St. Lawrence was either too small or occurred over too long a time to leave a distinct d18O minimum off Nova Scotia. At 7.1 ka, in the middle of Holocene warming, we find a third peak in abundance of N. pachyderma and another d18O minimum but no ice rafting. We interpret these data as evidence of a late-occurring meltwater event which, if correct, could have originated in the Great Lakes, in the Labrador-Ungava region, or in both. The final millennial-scale phenomenon off Nova Scotia is the onset of "Neoglaciation," marked by increased ice rafting and increased % N. pachyderma beginning about 5 kyr ago.

(Table 1) Age determination of North Atlantic sediment cores

High-resolution sediment cores from the Vøring Plateau, the North Iceland shelf, and the East Greenland shelf have been studied to investigate the stability of major surface currents in the Nordic Seas during the Holocene. Results from diatom assemblages and reconstructed sea-surface temperatures (SSTs) indicate a division of the Holocene into three periods: the Holocene Climate Optimum (9500-6500 calendar (cal) years BP), the Holocene Transition Period (6500-3000 cal years BP) and the Cool Late Holocene Period (3000-0 cal years BP). The overall climate development is in step with the decreasing insolation on the Northern Hemisphere, but regional differences occur regarding both timing and magnitude of SST changes. Sites under the direct influence of the Norwegian Atlantic Current and the Irminger Current indicate SST cooling of 4-5°C from early Holocene to present, compared to 2°C recorded under the East Greenland Current. Superimposed on the general Holocene cooling trend, there is a high-frequency SST variability, which is in the order of 1-1.5°C for the Vøring Plateau and the East Greenland shelf and 2.5-3°C on the North Iceland shelf.

Age determination and paleotemperatures of western Mediterranean Sea sediments

Sea surface temperature (SST) profiles over the last 25 kyr derived from alkenone measurements are studied in four cores from a W-E latitudinal transect encompassing the Gulf of Cadiz (Atlantic Ocean), the Alboran Sea, and the southern Tyrrhenian Sea (western Mediterranean). The results document the sensitivity of the Mediterranean region to the short climatic changes of the North Atlantic Ocean, particularly those involving the latitudinal position of the polar front. The amplitude of the SST oscillations increases toward the Tyrrhenian Sea, indicating an amplification effect of the Atlantic signal by the climatic regime of the Mediterranean region. All studied cores show a shorter cooling phase (700 years) for the Younger Dryas (YD) than that observed in the North Atlantic region (1200 years). This time diachroneity is related to an intra-YD climatic change documented in the European continent. Minor oscillations in the southward displacement of the North Atlantic polar front may also have driven this early warming in the studied area. During the Holocene a regional diachroneity propagating west to east is observed for the SST maxima, 11.5-10.2 kyr B.P. in the Gulf of Cadiz, 10-9 kyr B.P. in the Alboran Sea, and 8.9-8.4 kyr B.P. in the Thyrrenian Sea. A general cooling trend from these SST maxima to present day is observed during this stage, which is marked by short cooling oscillations with a periodicity of 730±40 years and its harmonics.

Carbonate preservation of sediment cores from the Great Bahama Bank

The oceanic carbon cycle mainly comprises the production and dissolution/ preservation of carbonate particles in the water column or within the sediment. Carbon dioxide is one of the major controlling factors for the production and dissolution of carbonate. There is a steady exchange between the ocean and atmosphere in order to achieve an equilibrium of CO2; an anthropogenic rise of CO2 in the atmosphere would therefore also increase the amount of CO2 in the ocean. The increased amount of CO2 in the ocean, due to increasing CO2-emissions into the atmosphere since the industrial revolution, has been interpreted as "ocean acidification" (Caldeira and Wickett, 2003). Its alarming effects, such as dissolution and reduced CaCO3 formation, on reefs and other carbonate shell producing organisms form the topic of current discussions (Kolbert, 2006). Decreasing temperatures and increasing pressure and CO2 enhance the dissolution of carbonate particles at the sediment-water interface in the deep sea. Moreover, dissolution processes are dependent of the saturation state of the surrounding water with respect to calcite or aragonite. Significantly increased dissolution has been observed below the aragonite or calcite chemical lysocline; below the aragonite compensation depth (ACD), or calcite compensation depth (CCD), all aragonite or calcite particles, respectively, are dissolved. Aragonite, which is more prone to dissolution than calcite, features a shallower lysocline and compensation depth than calcite. In the 1980's it was suggested that significant dissolution also occurs in the water column or at the sediment-water interface above the lysocline. Unknown quantities of carbonate produced at the sea surface, would be dissolved due to this process. This would affect the calculation of the carbonate production and the entire carbonate budget of the world's ocean. Following this assumption, a number of studies have been carried out to monitor supralysoclinal dissolution at various locations: at Ceara Rise in the western equatorial Atlantic (Martin and Sayles, 1996), in the Arabian Sea (Milliman et al., 1999), in the equatorial Indian Ocean (Peterson and Prell, 1985; Schulte and Bard, 2003), and in the equatorial Pacific (Kimoto et al., 2003). Despite the evidence for supralysoclinal dissolution in some areas of the world's ocean, the question still exists whether dissolution occurs above the lysocline in the entire ocean. The first part of this thesis seeks answers to this question, based on the global budget model of Milliman et al. (1999). As study area the Bahamas and Florida Straits are most suitable because of the high production of carbonate, and because there the depth of the lysocline is the deepest worldwide. To monitor the occurrence of supralysoclinal dissolution, the preservation of aragonitic pteropod shells was determined, using the Limacina inflata Dissolution Index (LDX; Gerhardt and Henrich, 2001). Analyses of the grain-size distribution, the mineralogy, and the foraminifera assemblage revealed further aspects concerning the preservation state of the sediment. All samples located at the Bahamian platform are well preserved. In contrast, the samples from the Florida Straits show dissolution in 800 to 1000 m and below 1500 m water depth. Degradation of organic material and the subsequent release of CO2 probably causes supralysoclinal dissolution. A northward extension of the corrosive Antarctic Intermediate Water (AAIW) flows through the Caribbean Sea into the Gulf of Mexico and might enhance dissolution processes at around 1000 m water depth. The second part of this study deals with the preservation of Pliocene to Holocene carbonate sediments from both the windward and leeward basins adjacent to Great Bahama Bank (Ocean Drilling Program Sites 632, 633, and 1006). Detailed census counts of the sand fraction (250-500 µm) show the general composition of the coarse grained sediment. Further methods used to examine the preservation state of carbonates include the amount of organic carbon and various dissolution indices, such as the LDX and the Fragmentation Index. Carbonate concretions (nodules) have been observed in the sand fraction. They are similar to the concretions or aggregates previously mentioned by Mullins et al. (1980a) and Droxler et al. (1988a), respectively. Nonetheless, a detailed study of such grains has not been made to date, although they form an important part of periplatform sediments. Stable isotopemeasurements of the nodules' matrix confirm previous suggestions that the nodules have formed in situ as a result of early diagenetic processes (Mullins et al., 1980a). The two cores, which are located in Exuma Sound (Sites 632 and 633), at the eastern margin of Great Bahama Bank (GBB), show an increasing amount of nodules with increasing core depth. In Pliocene sediments, the amount of nodules might rise up to 100%. In contrast, nodules only occur within glacial stages in the deeper part of the studied core interval (between 30 and 70 mbsf) at Site 1006 on the western margin of GBB. Above this level the sediment is constantly being flushed by bottom water, that might also contain corrosive AAIW, which would hinder cementation. Fine carbonate particles (<63 µm) form the matrix of the nodules and do therefore not contribute to the fine fraction. At the same time, the amount of the coarse fraction (>63 µm) increases due to the nodule formation. The formation of nodules might therefore significantly alter the grain-size distribution of the sediment. A direct comparison of the amount of nodules with the grain-size distribution shows that core intervals with high amounts of nodules are indeed coarser than the intervals with low amounts of nodules. On the other hand, an initially coarser sediment might facilitate the formation of nodules, as a high porosity and permeability enhances early diagenetic processes (Westphal et al., 1999). This suggestion was also confirmed: the glacial intervals at Site 1006 are interpreted to have already been rather coarse prior to the formation of nodules. This assumption is based on the grain-size distribution in the upper part of the core, which is not yet affected by diagenesis, but also shows coarser sediment during the glacial stages. As expected, the coarser, glacial deposits in the lower part of the core show the highest amounts of nodules. The same effect was observed at Site 632, where turbidites cause distinct coarse layers and reveal higher amounts of nodules than non-turbiditic sequences. Site 633 shows a different pattern: both the amount of nodules and the coarseness of the sediment steadily increase with increasing core depth. Based on these sedimentological findings, the following model has been developed: a grain-size pattern characterised by prominent coarse peaks (as observed at Sites 632 and 1006) is barely altered. The greatest coarsening effect due to the nodule formation will occur in those layers, which have initially been coarser than the adjacent sediment intervals. In this case, the overall trend of the grain-size pattern before and after formation of the nodules is similar to each other. Although the sediment is altered due to diagenetic processes, grain size could be used as a proxy for e.g. changes in the bottom-water current. The other case described in the model is based on a consistent initial grain-size distribution, as observed at Site 633. In this case, the nodule reflects the increasing diagenetic alteration with increasing core depth rather than the initial grain-size pattern. In the latter scenario, the overall grain-size trend is significantly changed which makes grain size unreliable as a proxy for any palaeoenvironmental changes. The results of this study contribute to the understanding of general sedimentation processes in the periplatform realm: the preservation state of surface samples shows the influence of supralysoclinal dissolution due to the degradation of organic matter and due to the presence of corrosive water masses; the composition of the sand fraction shows the alteration of the carbonate sediment due to early diagenetic processes. However, open questions are how and when the alteration processes occur and how geochemical parameters, such as the rise in alkalinity or the amount of strontium, are linked to them. These geochemical parameters might reveal more information about the depth in the sediment column, where dissolution and cementation processes occur.

Sedimentary record of the western Amundsen Sea Embayment after the last glacial maximum

Reliable dating of glaciomarine sediments deposited on the Antarctic shelf since the Last Glacial Maximum (LGM) is very challenging because of the general absence of calcareous (micro-) fossils and the recycling of fossil organic matter. As a consequence, radiocarbon (14C) ages of the acid-insoluble organic fraction (AIO) of the sediments bear uncertainties that are very difficult to quantify. In this paper we present the results of three different chronostratigraphic methods to date a sedimentary unit consisting of diatomaceous ooze and diatomaceous mud that was deposited following the last deglaciation at five core sites on the inner shelf in the western Amundsen Sea (West Antarctica). In three cores conventional 14C dating of the AIO in bulk sediment samples yielded age reversals down-core, but at all sites the AIO 14C ages obtained from diatomaceous ooze within the diatom-rich unit yielded similar uncorrected 14C ages ranging from 13,517±56 to 11,543±47 years before present (yr BP). Correction of these ages by subtracting the core-top ages, which are assumed to reflect present-day deposition (as indicated by 21044 Pb dating of the sediment surface at one core site), yielded ages between ca. 10,500 and 8,400 calibrated years before present (cal yr BP). Correction of the AIO ages of the diatomaceous ooze by only subtracting the marine reservoir effect (MRE) of 1,300 years indicated deposition of the diatom-rich sediments between 14,100 and 11,900 cal yr BP. Most of these ages are consistent with age constraints between 13.0 and 8.0 ka BP for the diatom-rich unit, which we obtained by correlating the relative palaeomagnetic intensity (RPI) records of three of the sediment cores with global and regional reference curves for palaeomagnetic intensity. As a third dating technique we applied conventional 53 radiocarbon dating of the AIO included in acid-cleaned diatom hard parts that were extracted from the diatomaceous ooze. This method yielded uncorrected 14C ages of only 5,111±38 and 5,106±38 yr BP, respectively. We reject these young ages, because they are likely to be overprinted by the adsorption of modern atmospheric carbon dioxide onto the surfaces of the extracted diatom hard parts prior to sample graphitisation and combustion for 14C dating. The deposition of the diatom-rich unit in the western Amundsen Sea suggests deglaciation of the inner shelf before ca. 13 ka BP. The deposition of diatomaceous oozes on other parts of the Antarctic shelf around the same time, however, seems to be coincidental rather than directly related.

(Table 1) Age determination of composite sediment record LO09-14

A sediment core from Reykjanes Ridge has been studied at 10- to 50-year time resolution to document variability of Holocene surface water conditions in the western North Atlantic and to evaluate effects of Holocene ice-rafting episodes. Diatom assemblages are converted to quantitative sea surface temperatures (SST) using three different transfer functions. Spectral and scale-space methods are also applied on the records to explore variability at different timescales. Diatom assemblage and SST records clearly show that decaying remnants of the Laurentide ice sheet strongly influenced early Holocene climate in the western North Atlantic. This overrode the predominance of Milankovitch forcing, which played a key role in the development of Holocene climate in the eastern North Atlantic and Nordic Seas. Superimposed on general Holocene climate change is high-frequency SST variability on the order of 1°-3°C. The record also documents climatic oscillations with 600- to 1000-, ~1500-, and 2500-year periodicities, with a time-dependent dominance of different periodicities through the Holocene; a clear change in variability occurred about 5 ka BP. The SST record also provides evidence for Holocene cooling events (HCE) that, in some cases, correlate to documented southward intrusions of ice into the North Atlantic.

Multi-proxy records of Two-Yurts Lake

Within the scope of Russian-German palaeoenvironmental research, Two-Yurts Lake (TYL, Dvuh-Yurtochnoe in Russian) was chosen as the main scientific target area to decipher Holocene climate variability on Kamchatka. The 5x2 km large and 26 m deep lake is of proglacial origin and situated on the eastern flank of Sredinny Ridge at the northwestern end of the Central Kamchatka Valley, outside the direct influence of active volcanism. Here, we present results of a multi-proxy study on sediment cores, spanning about the last 7000 years. The general tenor of the TYL record is an increase in continentality and winter snow cover in conjunction with a decrease in temperature, humidity, and biological productivity after 5000-4500 cal yrs BP, inferred from pollen and diatom data and the isotopic composition of organic carbon. The TYL proxy data also show that the late Holocene was punctuated by two colder spells, roughly between 4500 and 3500 cal yrs BP and between 1000 and 200 cal yrs BP, as local expressions of the Neoglacial and Little Ice Age, respectively. These environmental changes can be regarded as direct and indirect responses to climate change, as also demonstrated by other records in the regional terrestrial and marine realm. Long-term climate deterioration was driven by decreasing insolation, while the short-term climate excursions are best explained by local climatic processes. The latter affect the configuration of atmospheric pressure systems that control the sources as well as the temperature and moisture of air masses reaching Kamchatka.

(Table 1) AMS 14C dates from sediment cores RC12-10 and GYRE97-6PV-20

Proxy records from two piston cores in the Gulf of Mexico (GOM) provide a detailed (50-100 year resolution) record of climate variability over the last 14,000 years. Long-term (millennial-scale) trends and changes are related to the transition from glacial to interglacial conditions and movement of the average position of the Intertropical Convergence Zone (ITCZ) related to orbital forcing. The d18O of the surface-dwelling planktic foraminifer Globigerinoides ruber show negative excursions between 14 and 10.2 ka (radiocarbon years) that reflect influx of meltwater into the western GOM during melting of the Laurentide Ice Sheet. The relative abundance of the planktic foraminifer Globigerinoides sacculifer is related to transport of Caribbean water into the GOM. Maximum transport of Caribbean surface waters and moisture into the GOM associated with a northward migration of the average position of the ITCZ occurs between about 6.5 and 4.5 ka. In addition, abundance variations of G. sacculifer show century-scale variability throughout most of the Holocene. The GOM record is consistent with records from other areas, suggesting that century-scale variability is a pervasive feature of Holocene climate. The frequency of several cycles in the climate records is similar to cycles identified in proxy records of solar variability, indicating that at least some of the century-scale climate variability during the Holocene is due to external (solar) forcing.

(Table 2) Radiocarbon content and 14C AMS ages of planktonic foraminifera from sediment cores Louis_1900 and Louis_2023

North American freshwater runoff records have been used to support the case that climate flickers were caused by shutdowns of the ocean thermohaline circulation (THC) resulting from reversals of meltwater discharges. Inconsistencies in the documentation of these meltwater switches, however, continue to fuel the debate on the cause/s of the oscillatory nature of the deglacial climate. New oxygen and carbon isotope records from the northern Gulf of Mexico depict in exceptional detail the succession of meltwater floods and pauses through the southern routing during the interval 16 to 8.9 ka (14C years BP; ka, kiloannum). The records underscore the bimodal role played by the Gulf of Mexico as a destination of meltwater discharges from the receding Laurentide Ice Sheet. The evidence indicates that the Gulf of Mexico acted as the principal source of superfloods at 13.4, 12.6, and 11.9 ka that reached the North Atlantic and contributed significantly to density stratification, disruption of ocean ventilation, and cold reversals. Gulf of Mexico lapsed into a "relief valve" position in post-Younger Dryas time, when meltwater discharges were rerouted south at 9.9, 9.7, 9.4, and 9.1 ka, thus temporarily interrupting North Atlantic-bound freshwater discharges from Lake Agassiz. The history of meltwater events in the Gulf of Mexico contradicts the model that meltwater flow via the eastern outlets into the North Atlantic disrupted the ocean THC, causing cooling, while diversions to the Gulf of Mexico via the Mississippi River enhanced THC and warming.

AMS radiocarbon dates on ten monospecific samples of planktonic foraminifer Globigerinoides ruber of sediment core GeoB8509-2 (Table 1)

Aeolian and fluvial sediment transport to the Atlantic Ocean offshore Mauritania were reconstructed based on grain-size distributions of the carbonate-free silt fraction of three marine sediment records of Cap Timiris Canyon to monitor the climatic evolution of present-day arid north-western Africa. During the late Pleistocene, predominantly coarse-grained particles, which are interpreted as windborne dust, characterise glacial dry climate conditions with a low sea level and extended sand seas that reach onto the exposed continental shelf off Mauritania. Subsequent particle fining and the abrupt decrease in terrigenous supply are attributed to humid climate conditions and dune stabilisation on the adjacent African continent with the onset of the Holocene humid period. Indications for an ancient drainage system, which was discharging fluvial mud offshore via Cap Timiris Canyon, are provided by the finest end member for early to mid Holocene times. However, in comparison to the Senegal and Niger River further south, the river system connecting Cap Timiris Canyon with the Mauritanian hinterland was starved during the late Holocene and is non-discharging under present-day arid climate conditions.