CFD Applications for Wave Energy Conversion Devices (MoonWEC) and Turbulent Fountains for Environmental Fluid Mechanics

This thesis is based on two studies that are related to floating wave energy conversion (WEC) devices and turbulent fountains. The ability of the open-source CFD software OpenFOAM® has been studied to simulate these phenomena. The CFD model has been compared with the physical experimental results. The first study presents a model of a WEC device, called MoonWEC, which is patented by the University of Bologna. The CFD model of the MoonWEC under the action of waves has been simulated using OpenFOAM and the results are promising. The reliability of the CFD model is confirmed by the laboratory experiments, conducted at the University of Bologna, for which a small-scale prototype of the MoonWEC was made from wood and brass. The second part of the thesis is related to the turbulent fountains which are formed when a heavier source fluid is injected upward into a lighter ambient fluid, or else a lighter source fluid is injected downward into a heavier ambient fluid. For this study, the first case is considered for laboratory experiments and the corresponding CFD model. The vertical releases of the source fluids into a quiescent, uniform ambient fluid, from a circular source, were studied with different densities in the laboratory experiments, conducted at the University of Parma. The CFD model has been set up for these experiments. Favourable results have been observed from the OpenFOAM simulations for the turbulent fountains as well, indicating that it can be a reliable tool for the simulation of such phenomena.

A framework for the environmental risk assessment of offshore carbon storage in CCS systems

Carbon capture and storage (CCS) represents an interesting climate mitigation option, however, as for any other human activity, there is the impelling need to assess and manage the associated risks. This study specifically addresses the marine environmental risk posed by CO2 leakages associated to CCS subsea engineering system, meant as offshore pipelines and injection / plugged and abandoned wells. The aim of this thesis work is to start approaching the development of a complete and standardized practical procedure to perform a quantified environmental risk assessment for CCS, with reference to the specific activities mentioned above. Such an effort would be of extreme relevance not only for companies willing to implement CCS, as a methodological guidance, but also, by uniformizing the ERA procedure, to begin changing people’s perception about CCS, that happens to be often discredited due to the evident lack of comprehensive and systematic methods to assess the impacts on the marine environment. The backbone structure of the framework developed consists on the integration of ERA’s main steps and those belonging to the quantified risk assessment (QRA), in the aim of quantitatively characterizing risk and describing it as a combination of magnitude of the consequences and their frequency. The framework developed by this work is, however, at a high level, as not every single aspect has been dealt with in the required detail. Thus, several alternative options are presented to be considered for use depending on the situation. Further specific studies should address their accuracy and efficiency and solve the knowledge gaps emerged, in order to establish and validate a final and complete procedure. Regardless of the knowledge gaps and uncertainties, that surely need to be addressed, this preliminary framework already finds some relevance in on field applications, as a non-stringent guidance to perform CCS ERA, and it constitutes the foundation of the final framework.

Polymerization of isatin towards polymers for anion exchange membranes and gas separation applications

In a world where the problem of energy resources, pollution and all aspects related to these issues become more and more dominant, a greater commitment is needed in the search for solutions. The goal of this project is to make a contribution to the research and development of new materials to reduce the environmental impact in some fields. First of all, we tried to synthesize and prepare an isatin-based membrane which has the potential for use in separating industrial gases. Furthermore, ion exchange membranes, specifically hydroxide exchange membranes (HEMs) derived from the same product can be developed for fuel cells (HEMFC) applications. These materials are essential for energy conversion and storage. The most difficult challenge is to guarantee their thermal stability and stability in corrosive environments such as alkali without losing efficiency. In recent years the poly- hydroxyalkylation catalysed with superacids, e.g. TFSA, has become increasingly studied. This reaction is exploited for the synthesis of the compounds of this thesis. After a preliminary optimization of the reaction conditions it was concluded that due to the rigidity and excessive reactivity of the system, it was not possible to obtain the isatin-based membrane to evaluate the gas separation properties. The synthesis of precursor materials for HEMs was successful by using 1-(4-bromobutyl)indoline-2,3-dione (BID) instead of isatin. A characterization of the obtained polymers was carried out using NMR, TGA and DSC analyses, and subsequently the membranes were functionalized with different ammonium-based cations. Unfortunately, this last step was not successful due to the appearance of side reactions. Future studies on the mechanism and kinetics of the reaction solve this obstacle.

Low Power instrument Transformer: technologies and applications

Instrument transformers serve an important role in the protection and isolation of AC electrical systems for measurements of different electrical parameters like voltage, current, power factor, frequency, and energy. As suggested by name these transformers are used in connection with suitable measuring instruments like an ammeter, wattmeter, voltmeter, and energy meters. We have seen how higher voltages and currents are transformed into lower magnitudes to provide isolation between power networks, relays, and other instruments. Reducing transient, suppressing electrical noises in sensitive devices, standardization of instruments and relays up to a few volts and current. Transformer performance directly affects the accuracy of power system measurements and the reliability of relay protection. We classified transformers in terms of purpose, insulating medium, Voltage ranges, temperature ranges, humidity or environmental effect, indoor and outdoor use, performance, Features, specification, efficiency, cost analysis, application, benefits, and limitations which enabled us to comprehend their correct use and selection criteria based on our desired requirements. We also discussed modern Low power instrument transformer products that are recently launched or offered by renowned companies like Schneider Electric, Siemens, ABB, ZIV, G&W etc. These new products are innovations and problem solvers in the domain of measurement, protection, digital communication, advance, and commercial energy metering. Since there is always some space for improvements to explore new advantages of Low power instrument transformers in the domain of their wide linearity, high-frequency range, miniaturization, structural and technological modification, integration, smart frequency modeling, and output prediction of low-power voltage transformers.

Comparison of different solutions for the hybridization of a motorcycle engine for Formula Student applications and evaluation of the effectiveness on the simulated lap time

Following the latest environmental concerns, the importance of minimising the detrimental effect of emissions of terrestrial vehicles has become a major goal for the whole automotive field. The key to achieve an emission-free long term future is the electrification of vehicle fleets; this huge step cannot be taken without intermediate technologies. In this context, hybrid vehicles are fundamental to reach this goal. Specifically, mild hybrid vehicles represent a trade-off between cost and emissions that could act now as a bridge towards electrification. Like the industry, also student engineering competitions are likely to take the same route: Combustion vehicles may well turn into hybrid vehicles. For this reason, a preliminary design overview is necessary to pinpoint the key performance indicators for the prototypes of the future.