Atmospheric corrosion of quaternary bronzes (Cu-Sn-Zn-Pb): laboratory tests (accelerated ageing in wet & dry conditions)and field studies (the Bottego monument in Parma, Italy).

The interactions between outdoor bronzes and the environment, which lead to bronze corrosion, require a better understanding in order to design effective conservation strategies in the Cultural Heritage field. In the present work, investigations on real patinas of the outdoor monument to Vittorio Bottego (Parma, Italy) and laboratory studies on accelerated corrosion testing of inhibited (by silane-based films, with and without ceria nanoparticles) and non-inhibited quaternary bronzes are reported and discussed. In particular, a wet&dry ageing method was used both for testing the efficiency of the inhibitor and for patinating bronze coupons before applying the inhibitor. A wide range of spectroscopic techniques has been used, for characterizing the core metal (SEM+EDS, XRF, AAS), the corroded surfaces (SEM+EDS, portable XRF, micro-Raman, ATR-IR, Py-GC-MS) and the ageing solutions (AAS). The main conclusions were: 1. The investigations on the Bottego monument confirmed the differentiation of the corrosion products as a function of the exposure geometry, already observed in previous works, further highlighting the need to take into account the different surface features when selecting conservation procedures such as the application of inhibitors (i.e. the relative Sn enrichment in unsheltered areas requires inhibitors which effectively interact not only with Cu but also with Sn). 2. The ageing (pre-patination) cycle on coupons was able to reproduce the relative Sn enrichment that actually happens in real patinated surfaces, making the bronze specimens representative of the real support for bronze inhibitors. 3. The non-toxic silane-based inhibitors display a good protective efficiency towards pre-patinated surfaces, differently from other widely used inhibitors such as benzotriazole (BTA) and its derivatives. 4. The 3-mercapto-propyl-trimethoxy-silane (PropS-SH) additivated with CeO2 nanoparticles generally offered a better corrosion protection than PropS-SH.

Italia e Spagna alle prese con lo "spread": riflessioni sugli anglicismi nel lessico della crisi economica

Este trabajo se concentra sobre el papel que los anglicismos desempeñan en la lengua italiana. Se compara el uso de anglicismos en la lengua italiana con su uso en la lengua española, y se reflexiona sobre las razones de una presencia mayor en italiano de anglicismos no adaptados, y una tendencia en español a traducir los préstamos a la hora de importarlos, produciendo calcos. Se utilizarán los informativos televisivos como fuentes, en cuanto, por un lado, son espejo de la lengua hablada, y, por otro, influencian el proceso de interferencia, o sea, la manera en la que los anglicismos entran en la lengua de llegada. Se proponen ejemplos de palabras que los telediarios italianos utilizan en forma no adaptada, acompañados de su equivalente en español y un ejemplo práctico de su uso en informativos españoles. El objetivo de este trabajo es observar la proliferación de anglicismos en italiano, analizando el campo de la economía en informativos destinados a un público no especializado, comparando esta tendencia de la lengua italiana con la del español y reflexionar sobre la necesidad de uso de los anglicismos recogidos en el corpus del trabajo y/o su posible sustitución por equivalentes de las lenguas analizadas.