3 resultados para BLOCK COPOLYIMIDES

em AMS Tesi di Laurea - Alm@DL - Università di Bologna


Relevância:

20.00% 20.00%

Publicador:

Resumo:

Il seguente elaborato si concentra sull'identifi�cazione strutturale di sistemi soggetti a sollecitazioni aeroelastiche e nello speci�fico l'attenzione viene rivolta ad impalcati da ponte. Si analizzano i concetti principali caratterizzanti il campo dell'aeroelasticità indagando i fattori dominanti che entrano in gioco sul piano teorico. In seguito, si considera il metodo di identifi�cazione strutturale chiamato Covariance Block Hankel Matrix (CBHM) utilizzato come strumento di derivazione dei coeffi�cienti aeroelastici propri della struttura. Infi�ne, si indaga il comportamento di questo metodo di identi�ficazione al variare di una serie di parametri chiave e all'interno di diversi scenari, visionando risultati ottenuti tramite una serie di test eff�ettuati per provare l'a�dattabilità del metodo stesso al variare delle condizioni che caratterizzano il sistema.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Random access (RA) protocols are normally used in a satellite networks for initial terminal access and are particularly effective since no coordination is required. On the other hand, contention resolution diversity slotted Aloha (CRDSA), irregular repetition slotted Aloha (IRSA) and coded slotted Aloha (CSA) has shown to be more efficient than classic RA schemes as slotted Aloha, and can be exploited also when short packets transmissions are done over a shared medium. In particular, they relies on burst repetition and on successive interference cancellation (SIC) applied at the receiver. The SIC process can be well described using a bipartite graph representation and exploiting tools used for analyze iterative decoding. The scope of my Master Thesis has been to described the performance of such RA protocols when the Rayleigh fading is taken into account. In this context, each user has the ability to correctly decode a packet also in presence of collision and when SIC is considered this may result in multi-packet reception. Analysis of the SIC procedure under Rayleigh fading has been analytically derived for the asymptotic case (infinite frame length), helping the analysis of both throughput and packet loss rates. An upper bound of the achievable performance has been analytically obtained. It can be show that in particular channel conditions the throughput of the system can be greater than one packets per slot which is the theoretical limit of the Collision Channel case.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Block copolymers of poly(lactide) and poly(carbonate) were synthetized in three different compositions and characterized by 1H-NMR and ATR analyses. The compatibilization effect of this copolymers on 80/20 (w/w%) PLA/PCL blend was evaluated. SEM micrographs show that all the blends exhibit the typical sea-island morphology characteristic of immiscible blends with PCL finely dispersed in droplets on a PLA matrix. Upon the addiction of the copolymers a reduction on PCL droplets size is observable. At the same time, a Tg depression of the PLA phase is detected when the copolymers are added in the blend. These results indicate that these copolymers are effective as compatibilizers. The copolymer that acts as the best compatibilizer is the one characterized by the same amount of PLA and PC as repeating units. As result, in the blend containing this copolymer PLA phase exhibits the highest spherulitic growth rate. An analyses on PLA phase crystallization behaviour from the glassy state within the blends was evaluated by DSC experiments. Isothermal cold crystallization of the PLA phase is enhanced up an order of magnitude upon the blending with PCL. Annealing experiments demonstrated that the crystallization of the PCL phase induces the formation of active nuclei in PLA when cooled above cooled below Tg. When the crystallization rate of PCL is retarded, a reduction on PLA nucleation is observed.