2 resultados para Voies internes de signalisation
em AMS Tesi di Dottorato - Alm@DL - Università di Bologna
Resumo:
Ce travail a pour objectif dâanalyser la production narrative et poétique de lâécrivain tunisien Abdelwahab Meddeb, en comparaison avec les ouvrages du Moyen Age arabe et persan. Lâauteur reprend en effet, par le biais de pratiques intertextuelles, les ouvrages des philosophes et des écrivains orientaux qui plus ont marqué le monde musulman, en arrivant à en faire une synthèse originale. Cette perspective multiculturelle ouvre la voie à une instance narrative polyphonique, où les textes se confondent et se mélangent. En un premier moment, lâétude porte sur les théories intertextuelles et leur application chez Meddeb ; dans la deuxième partie, lâanalyse se concentre sur les correspondances internes à lâÅuvre meddebienne, pour laisser la place, dans la dernière partie, aux aspects intertextuels que le texte francophone entretient avec les autres auteurs.
Resumo:
Sensors are devices that have shown widespread use, from the detection of gas molecules to the tracking of chemical signals in biological cells. Single walled carbon nanotube (SWCNT) and graphene based electrodes have demonstrated to be an excellent material for the development of electrochemical biosensors as they display remarkable electronic properties and the ability to act as individual nanoelectrodes, display an excellent low-dimensional charge carrier transport, and promote surface electrocatalysis. The present work aims at the preparation and investigation of electrochemically modified SWCNT and graphene-based electrodes for applications in the field of biosensors. We initially studied SWCNT films and focused on their topography and surface composition, electrical and optical properties. Parallel to SWCNTs, graphene films were investigated. Higher resistance values were obtained in comparison with nanotubes films. The electrochemical surface modification of both electrodes was investigated following two routes (i) the electrografting of aryl diazonium salts, and (ii) the electrophylic addition of 1, 3-benzodithiolylium tetrafluoroborate (BDYT). Both the qualitative and quantitative characteristics of the modified electrode surfaces were studied such as the degree of functionalization and their surface composition. The combination of Raman, X-ray photoelectron spectroscopy, atomic force microscopy, electrochemistry and other techniques, has demonstrated that selected precursors could be covalently anchored to the nanotubes and graphene-based electrode surfaces through novel carbon-carbon formation.