An assessment of the concentrations of pharmaceutical compounds in wastewater treatment plants on the island of Gran Canaria(Spain)

[EN] An assessment of the concentrations of thirteen different therapeutic pharmaceutical compounds was conducted on water samples obtained from different wastewater treatment plants (WWTPs) using solid phase extraction and high- and ultra-high-performance liquid chromatography with mass spectrometry detection (HPLC-MS/MS and UHPLC-MS/MS), was carried out. The target compounds included ketoprofen and naproxen (anti-inflammatories), bezafibrate (lipid-regulating), carbamazepine (anticonvulsant), metamizole (analgesic), atenolol (?-blocker), paraxanthine (stimulant), fluoxetine (antidepressant), and levofloxacin, norfloxacin, ciprofloxacin, enrofloxacin and sarafloxacin (fluoroquinolone antibiotics). The relative standard deviations obtained in method were below 11%, while the detection and quantification limits were in the range of 0.3 ? 97.4 ng·L-1 and 1.1 ? 324.7 ng·L-1, respectively. The water samples were collected from two different WWTPs located on the island of Gran Canaria in Spain over a period of one year. The first WWTP (denoted as WWTP1) used conventional activated sludge for the treatment of wastewater, while the other plant (WWTP2) employed a membrane bioreactor system for wastewater treatment. Most of the pharmaceutical compounds detected in this study during the sampling periods were found to have concentrations ranging between 0.02 and 34.81 ?g·L-1.

Determinación de hormonas esteroideas en aguas depuradas de la isla de Gran Canaria

[ES]La comunidad científica internacional ha mostrado su preocupación en las últimas décadas sobre la presencia de hormonas esteroideas en el medio ambiente, las cuales han sido catalogadas como “compuestos disruptores endocrinos” (EDCs). Las hormonas pueden llegar al medio a través de diferentes vías, siendo la fuente principal la descarga al medio de los efluentes de las estaciones depuradoras de aguas residuales (EDARs), debido a la eliminación incompleta de estos compuestos que se produce en ellas. Las concentraciones de hormonas presentes en el medio acuático suelen ser del orden de ng·L-1, por lo que se necesitan metodologías analíticas sensibles y selectivas para su determinación