10 resultados para ALUMINUM CONTENT

em Repositório Institucional UNESP - Universidade Estadual Paulista "Julio de Mesquita Filho"


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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Cubic phase group III-nitrides were grown using RF plasma assisted Molecular Beam Epitaxy on GaAs (001) substrates. High-resolution X-ray diffraction, photoluminescence, cathodoluminescence and photoreflectance measurements were employed to characterize the structural and optical properties of GaN/AlxGa1-xN Multi Quantum Well (MQW) structures, in which both Aluminum content and well widths were varied. The observed quantized states are in agreement with first-principles based theoretical calculations.

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Pós-graduação em Engenharia Civil e Ambiental - FEB

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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The effects on soil chemical properties brought about by cover crops vary considerably. This study was conducted to evaluate nutrient uptake by five cover crops used for grain, seed and forage production at different seed densities per hectare, as well as uptake by spontaneous vegetation, and their effect on the chemical properties of two Oxisols when grown in rotation with soybean and corn. The experiments were set up in Votuporanga, SP, Brazil and Selvíria, MS, Brazil in March 2008 after conventional soil tillage. A randomized complete block experimental design was used with four replications with the following cover crops at different seed densities: Sorghum bicolor at 6, 7 and 8 kg ha-1; Pennisetum americanum at 10, 15 and 20 kg ha-1; Sorghum sudanense at 12, 15 and 18 kg ha-1; hybrid of Sorghum bicolor with Sorghum sudanense at 8, 9 and 10 kg ha-1; and Urochloa ruziziensis at 8, 12 and 16 kg ha-1. We also used a spontaneous vegetation control. After management of the cover crops, in the first year of study, soybean was sown in no-tillage system and, in the second year, corn was sown, also in a no-tillage system. We evaluated the dry matter yield of different cover crops, nutrient uptake by the cover crops, and the chemical changes in the soil. It was found that in clayey soils with high aluminum content, as in Selvíria, sudan grass at a seed density of 18 kg ha-1, and sorghum at a seed density of 6 kg ha-1, in combination with liming, contributed to reduction of aluminum content and high potential acidity and an increase in base saturation. The different seed densities of each cover crop did not affect the dry matter yield of the cover crop itself, but affected nitrogen uptake of the hybrid Sorghum bicolor with Sorghum sudanense at a seed density of 10 kg ha-1, with lower uptake than at a seed density of 8 kg ha-1. Seed density also affected the organic matter content in the soil with sudan grass, with the seed density of 15 kg ha-1 providing more organic matter content than a seed density of 18 kg ha-1.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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The kinetic of mullite crystallization from sol–gel method, with different water content, was investigated under non-isothermal conditions using DTA. The sols were obtained from Al(NO3)3.9H2O (ANN) and Si(OC2H5)4 (TEOS) mixtures by varying the water–alcohol content of the system. The crystalline phase changes were verified by X-ray diffraction (XRD). For a sample prepared using ethanol-based alkoxide solution (M0), only Al-poor mullite (p-mullite) crystallizes at 1000 °C; for the one synthesized with low water concentration (M6) Al-rich mullite (r-mullite) and spinel crystallize together; and for a sample prepared using a water-based alkoxide solution only spinel is formed. Thus, the variation of water contents during the synthesis caused great variations in the course of mullitization process. The average value of the apparent activation energy determined for p-mullite, r-mullite and spinel phase crystallization were found to be E = (899 ± 61) kJ mol−1, E = (1015 ± 272) kJ mol−1 and E = (980 ± 196) kJ mol−1, respectively. These results showed that sample M(0) was a monophasic gel, where aluminum and silicon atoms are mixed at a molecular level while sample M(100) was a diphasic gel, where silicon and aluminum atoms are distributed in a nanometric level. The fast reaction between TEOS and water molecules is responsible for this great difference in the sample's homogeneity. The kinetic model of the crystallization process was determined using Malek's procedure. It was established that the crystallization of p-mullite, r-mullite and spinel phase can be described by Šesták–Berggren autocatalytic model.