Caracterização de filmes finos polimerizados por plasma a partir dos monômeros hexametildisilazano e acetileno e posteriormente expostos à descarga por barreira dielétrica

Pós-graduação em Engenharia Mecânica - FEG

ZTD em tempo quase real via Estações GNSS Terrestres: estratégia de processamento para o GIPSY-OASIS II e combinação das séries temporais

Pós-graduação em Ciências Cartográficas - FCT

Efeitos da contaminação in situ por níquel em peixes da espécie Oreochromisniloticus (Cichlidae)

A contaminação de rios com metais pesados vêm aumentando nas últimas décadas em resposta ao crescimento do setor industrial e seus dejetos, que frequentemente são despejados no ambiente sem que o tratamento adequado seja realizado. As implicações ambientais da contaminação dos ecossistemas naturais de água doce com níquel ainda são mal compreendidas, entretanto, a demanda global por este metal e as descargas antrópicas provenientes do setor industrial só aumentam. Embora o níquel não seja considerado altamente tóxico como outros metais, ele tem a capacidade de ser bioacumulativo e é, portanto, potencialmente perigoso para os peixes. Assim, é importante que seja desenvolvida uma compreensão mais profunda da fisiologia básica do níquel em peixes, tanto como um nutriente essencial quanto como um agente tóxico. Desse modo, o presente estudo teve como objetivo a análise do potencial genotóxico e mutagênico do níquel em peixes da espécie Oreochromis niloticus (Cichlidae), e a comparação das concentrações utilizadas deste metal nos bioensaios com a concentração limite, estabelecida pelo Conselho Nacional do Meio Ambiente (CONAMA). A resolução 357/05 do CONAMA, para controlar e taxar os limites máximos de contaminantes na água define que o limite máximo da concentração total de níquel permitida em corpos de água doce é de 0,025 mg/L Ni. Assim, os organismos-teste foram expostos a três diferentes concentrações de cloreto de níquel diluído, sendo que, a primeira concentração foi de 0,0125 mg/L, ou seja, metade da concentração máxima definida pelo CONAMA. A segunda concentração utilizada, 0,025 mg/L é o próprio limite de concentração estabelecido pela resolução. Por fim, a terceira concentração utilizada foi de 0,050 mg/L, que consiste no dobro da concentração máxima total de níquel permitida em corpos de água doce... (Resumo completo, clicar acesso eletrônico abaixo)

Proposta de implementação da ISO 14001 em uma empresa química

Due to environmental concerns and the current legal requirements, companies are looking for ways to reconcile economic growth with environmental preservation. The purpose of this project is to show the stages of implementation of ISO 14001 in a chemical company and propose changes in chemical procedures creating goals to be achieved. In this paper, the study for the implementation of ISO 14001 is in Viapol ltda., where the lack of environmental management can cause enormous impact to the environment and may generate air, soil and water pollution. The project resulted in a mapping of all the processes and a broad survey of waste and emissions, generating proposals to change some of the processes and and creating programs to achieve the goals and objectives proposed in the Environmental Policy. Adopting an environmental management system (EMS), the company will reduce costs by decreasing the amount of raw material used, shooting down on waste disposal and the amount of it, and increasing productivity. By committing to the implementation of the EMS, companies will be demonstrating a proactive approach to environmental issues and enrich its image to consumers’ point of view

O valor da elaboração de relatórios de sustentabilidade para as empresas de mineração

Sustainability has been moving up on the business agenda in recent decades, and many methods to assess corporate sustainability have already been created. One of the most used and reliable methods is the Sustainability Reporting Guidelines of the Global Reporting Initiative (GRI). Given the importance of sustainability for society and organizations, this study examined sustainability reports published by mining companies – Alcoa, Vale and Samarco – since 2006. The objective was to verify the indicators that contribute most to the minimization of environmental impacts and the improvement of environmental performance. The methodology consisted of collecting and analyzing data from the GRI sustainability reports. It was discovered that the sustainability reports helped the companies to identify improvement opportunities and it is essential companies provide in their reports an economic, environmental and social context of their activities. Furthermore, it was found out that the indicators related to atmospheric emissions, solid waste generation, environmental protection expenditure, and the consumption of raw materials, energy and water are the ones more attached to the production process, which means they are the main contributors for the environmental performance improvement

Análise ambiental em um canteiro de obras

The building sector can cause the environmental degradation, by the natural resources consumption, machinery use and natural landscape modifying. The environmental management system (EMS) improves the environmental quality and makes the companies more competitive. So, this work developed an environmental management system in a building site focused on the solid waste and in the development of mitigation proposals for the most significant environmental impacts. To develop this work it was necessary to follow the building site activities; evaluate the solid waste management; identify the law requirements; identify the environmental aspects and impacts; evaluate the environmental impacts; and propose alternatives for mitigating the adverse environmental critical impacts. The main proposals are the reduction of the waste generation in the place that it’s generated; the reuse and correct final disposal of that wastes; the treatment and reuse of the effluent; and the supervising in the trucks and machineries avoiding the oil spilling and the air pollution

Participação dos receptores purinérgicos no núcleo do trato solitário sobre as respostas cardiorrespiratórias induzidas por hipóxia

A queda da pressão parcial de oxigênio no sangue arterial (PaO2), provocada pela hipóxia aguda, aumenta as descargas dos quimiorreceptores periféricos, carotídeos e aórticos, cujas aferências estimulam núcleos bulbares como o núcleo do trato solitário (NTS, Chitravanshi e cols., 1994, Mifflin, 1992), resultando em uma série de repostas compensatórias incluindo o aumento da VE ( Overgaard e cols., 1996, Sun e Reis, 1994). Estudos demonstraram que a via neural do quimiorreflexo periférico no NTS tem como neurotransmissores o L-glutamato e mais recentemente o ATP. Além disso, o ATP atuando em receptores purinérgicos presente na superfície ventral do bulbo estaria envolvido com as respostas cardiorrespiratórias induzidas por hipóxia. No entanto, a participação dos receptores purinérgicos do NTS sobre as respostas cardiorrespiratórias induzidas por hipóxia ainda é desconhecida. Portanto, o presente estudo investigou o envolvimento dos receptores purinérgicos P2 no NTS sobre as respostas cardiorrespiratórias induzidas por hipóxia em ratos acordados, usando injeção bilateral de suramin (antagonista inespecífico dos receptores P2) e PPADS (antagonista seletivo dos receptores P2X). Foram utilizados ratos Holtzman (290-310g, n=4-9/grupo) com implante de cânulas guia no NTS. Para medida da pressão arterial média (PAM) e freqüência cardíaca (FC) foi inserido na artéria abdominal, através da artéria femoral, um tubo de polietileno (P-10 conectado ao P-50). Freqüência respiratória (FR), volume corrente (VC) e VE foram registrados através do método de pletismografia de corpo inteiro. Os parâmetros FR, VC, VE, PAM e FC foram registrados antes e após a injeção bilateral de salina, suramin (2 nmol/100 nl) ou PPADS (2 nmol/100 nl) no NTS durante hipóxia (7% de O2 por 35 min) ou normóxia (21% de O2)... (Resumo completo, clicar acesso eletrônico abaixo)

Caracterização de plasmas através da espectrometria de massa

Mass spectrometry is a diagnosis that can aid in the understanding of the kinetics of chemical plasma environment. Through this you can get information about some species present in the environment and make inferences about the behavior of the plasma when parameters such as pressure and applied power changes. When analyzed plasmas generated by the discharge of argon and diglyme (both individually and mixtures of them in various proportions) could be found conditions in which the plasma behavior was different from what is often found in the literature. By the end some peculiar characteristics of plasmas generated by mixing argon / diglyme were raised and it was found that the noble gas is a good mediator of physical and chemical reactions that occur in the environment, and help in the understanding of chemical kinetics. Therefore mass spectrometry was shown highly important tool for the study of plasma environment

Aplicação da descarga por barreira dielétrica (DBD) em diferentes frequências no tratamento de polipropileno

In this work, air dielectric barrier discharge (DBD) operating at two different frequencies (60 Hz and 17 kHz) was used to improve surface properties of polypropylene (PP). The changes in surface hydrophilicity were investigated by contact angle measurements. The modifications in chemical composition of PP surface were studied by X-ray photoelectron spectroscopy (XPS) and Fourier-transformed infrared spectroscopy (FTIR). The PP roughness were analyzed before and after the DBD treatment using atomic force microscopy (AFM). In order to compare the results obtained at different frequencies, the analyses are presented as a function of the deposited energy density. The results show that both DBD treatments led to formation of low-molecular weight oxidized material (LMWOM). It tends to agglomerate into small mounts on the surface, as shown by AFM analyses. These structures are weakly bounded to the surface and can be easily removed by rinsing in polar solvents. After washing the DBD-treated samples, the PP partially recovers its original wetting characteristics. This suggests that oxidation also occurred at deeper and more permanent levels on the PP samples. Comparing both DBD treatments, the 17 kHz process was found to be more efficient in introducing oxygen groups to the PP surface

O clima urbano em Alfredo Marcondes/SP: uma análise dos indicadores geoambientais

There are obvious changes that occur within the cities, experienced in synthesis for the degradation of the environment and especially the worsening quality of life. Even small cities, began to exhibit characteristics typical of an atmospheric climate. Thus, it becomes natural to analyze the characteristics of these spaces, unlike the medium and large cities, provide a detailed analysis of the peculiarities of intra-urban space in order to highlight what factors enhance or soften the formations of a typical urban climate distinct patterns of land use. The aim of this research from a geoenvironmental mapping of attributes (uses and land cover, vegetation and tree characteristics of buildings) while representing the dynamic City entertainment. Thus, we seek to inter-relate these indicators to analysis climate urban-rural and intra-urban applied to the city of Alfredo Marcondes / SP, a small town in order to identify a potential compromise climate conditions point to generate a specific climate. From this detailed analysis, we intend to give suggestions with the government to improve the comfort of that environment. For the data collection was organized a specific methodology for its collection, organization and representation and for the record of climatic data (temperature, wind speed and direction and cloud cover) were used mini-shelters weather with temperature sensors in fixed locations, and a temperature sensor attached on the side of a vehicle, 1.5 meters in height from the floor for 42 points perpassando selected in different intra-urban spaces... (Complete abstract click electronic access below)

Ocorrência de evento climático extremo na cidade de Rio Claro-SP: episódio 24 e 25 de fevereiro de 2010

This work focuses on the analysis of extreme precipitation episode in the city of Rio Claro, held on 24 and 25 February 2010, which caused severe impacts to society, and a victim of drowning due to flooding due to flood in urban stream. Although the temporal concentration of summer rainfall is characteristic of tropical climatic regimes, each year there are issues of social and environmental impacts deflagrated by precipitation events in the city. These findings reinforce the importance of analyzing atmospheric conditions correlated to change in space usage

Monitoramento hidrossedimentlógico da bacia hidrográfica do alto rio Sucuriú (MS) contribuinte da PCH Costa Rica

The growing demand for electricity in Brazil has stimulated the implementation of Small Hydro Power (PCH) in various regions of the country. However, the silting of reservoirs is a major problem faced by power plants and power plants. In this context, this study aimed to evaluate the data hydrosedimentological strategic points of the watershed of the Alto Rio Sucuriú (MS) to identify the possible causes siltation of the reservoir PCH Costa Rica and suggest mitigation measures. Hydrosedimentological surveys were conducted during the rainy season (February / March 2012) and drought (August 2012), and obtained data flow, discharge liquid, suspended solids and bottom and organic matter content. Based on these results it was determined that the points 2, 4, 7 and 9 are the largest contributors to sedimentation, and point 4 got most liquid discharge (38,20 m3s-1), point 7 largest discharge of solid suspension (906,3 mg L-1), points 2 and 4 major discharges solid totals (231,59 t dia-1 and 238,185 t dia-1 respectively) and point 9 higher organic matter content (22,18%) . Found greater fraction of fine sand and very fine suspended solids and solid medium sand in the background. As mitigation measures for the process of silting of the reservoir PCH Costa Rica (MS) highlights the orientation of landowners in adopting conservation measures and planting of leguminous species native to the region in symbiosis with nitrogen-fixing bacteria

Poluição atmosférica e paisagem urbana no município de São Paulo

This paper proposes an analysis of two major polluting elements of the atmosphere of São Paulo city, carbon monoxide (CO) and sulfur dioxide (SO2). This study was performed through analysis of data on the quality of air, by means of published reports and records obtained by experiment using measuring rate monitor for CO2. Atmospheric data were collected and sorted. From this work it was possible to identify the concentration of carbon dioxide in the center of São Paulo on September 14, 2012 using the infrared gas analyzer (IRGA). From the ratios of carbon monoxide and sulfur dioxide spatially analyzed could identify major emitters by comparing records of pollutants and their origin. The analysis makes it possible to map the intensity of air pollution in urban areas, identifying the polluting elements, their issuers and thereby contributes to the current understanding of atmospheric features, bringing a geographical spatial analysis of air pollutants in São Paulo, contributing to awareness of vulnerabilities, enabling a useful tool for planning and maintenance of the urban environment related public policies

Dieta de Turdus leucomelas (Aves: Turdidae) em uma área urbanizada, com ênfase no consumo de frutos

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Dispositivo de microdescargas em gases na pressão atmosférica

Neste trabalho foi desenvolvido um dispositivo de microdescargas em gases à pressão atmosférica para geração de plasma a fim de ser utilizado no tratamento de superfícies. O trabalho foi baseado em um estudo de iniciação científica que aconteceu em duas etapas. Na introdução apresentam-se as motivações do estudo, o dispositivo desenvolvido na primeira etapa do trabalho bem como os primeiros resultados e propostas de melhorias. Definem-se os objetivos da segunda etapa, que contemplam modificações no dispositivo de descarga e na fonte de alimentação. Em seguida são explanados os métodos utilizados para confecção do dispositivo, construção da fonte de alimentação e circuito de fotodetecção para observar as descargas. Apresenta-se o modelo e configurações dos experimentos, os resultados obtidos são expostos e debatidos brevemente. Colocam-se as conclusões do trabalho e novas propostas de investigação e melhoramentos para o estudo das microdescargas. Seguem-se os agradecimentos aos envolvidos no projeto e, por fim, a bibliografia utilizada