Surface-enhanced resonance Raman scattering as an analytical tool for single molecule detection

A perylene derivative, n-(n-butyl)-n'-(4-aminobutyl) perylene-3,4,9,10-tetracarboxylic acid diimide (simplified as nBu-PTCD-(CH2)(4)-NH2) has been chosen as the target molecule for studies involving single molecule detection (SMD) using Raman scattering. The enhancement of the Raman signal is the result of the multiplicative effects of two phenomena, resonance Raman scattering (RRS) and surface-enhanced Raman scattering (SERS), which leads to the resulting surface-enhanced resonance Raman scattering (SERRS) process. The SERRS spectra from a single molecule have been collected using both silver and gold colloids. The SMD detection of the fundamental vibrational frequencies characteristic of nBu-PTCD-(CH2)(4)-NH2 is complemented with the detection of some overtones and combinations from ring stretching modes at the single molecule level. The background characterization of the ensemble vibrational spectroscopy of the target perylene and its SERRS is also presented, which includes the UV-vis absorption, experimental and calculated Raman scattering and infrared absorption, and molecular organization using reflection-absorption infrared spectroscopy (RAIRS).

Effect of ammoniation and moisture-content on the quality of signal grass (Brachiaria-decumbens stapf) hay

The experiment was carried out to evaluate the effects of two moisture levels (18-20% and 13-15%) and three anhydrous ammonia levels (0.0; 1.5; 3.0% of NH3) on the quality of Brachiaria decumbens Stapf hay. The hay was bailed in April and weighed and treated under plastic cover during 30 days. The hay presented a similar chemical composition when bailed with high or low moisture. The percentages of NDF (80.59; 77.61; 76.10%); hemicellulose (32.56; 29.48; 28.76%) and lignin (9.53; 8.21; 7.54% decreased and the percentages of crude protein (4.04; 11.35; 13.22%) and IVDMD (36.78; 49.72; 54.33%) increased as the NH3 level increased. The fractions ADF, cellulose, and ADIN did not change due to the ammoniation. The incidence of fungi decreased with application of NH3 being the better results obtained with the 1.5% treatments.

Residual signal auto-correlation to evaluate speech in Parkinson's disease patients

Objective: To evaluate the maximum residual signal auto-correlation also known as pitch amplitude (PA) values in patients with Parkinson's disease (PD) patients. Method. The signals of 21 Parkinson's patients were compared with 15 healthy individuals, divided according age and gender. Results: Statistical difference was seen between groups for PA, 0.39 for controls and 0.25 for PD. Normal value threshold was set as 0.3; (p <= 0.001). In the Parkinson's group 80.77%, and in the control group only 12.28%, had a PA < 0.3 demonstrating an association between these variables. The dispersion diagram for age and PA for PD individuals showed p=0.01 and r=0.54. There was no significant difference in relation to gender and PA between groups: Conclusion: the significant differences in pitch's amplitude between PD patients and healthy individuals demonstrate the methods specificity.-The results showed the need of prospective controlled studies,to improve the use and indications of residual signal auto-correlation to evaluate speech in PD patients.

Level crossing rate of Nakagami-m fading signal: Field trials and validation

Field trial measurements are used to validate the level crossing rate formula derived in an exact manner recently for the Nakagami-m signal. The formula reveals an excellent fit to measurements in situations other than those for which the Rice model is more appropriate.

Dressing monitoring with a digital signal processor

Grinding is a finishing process in machining operations, and the topology of the grinding tool is responsible for producing the desired result on the surface of the machined material The tool topology is modeled in the dressing process and precision is therefore extremely important This study presents a solution in the monitoring of the dressing process, using a digital signal processor (DSP) operating in real time to detect the optimal dressing moment To confirm the monitoring efficiency by DSP, the results were compared with those of a data acquisition system (DAQ) and offline processing The method employed here consisted of analyzing the acoustic emission and electrical power signal by applying the DPO and DPKS parameters The analysis of the results allowed us to conclude that the application of the DPO and DPKS parameters can be substituted by processing of the mean acoustic emission signal, thus reducing the computational effort

On the construction of perfect codes from HEX signal constellations

Recently, minimum and non-minimum delay perfect codes were proposed for any channel of dimension n. Their construction appears in the literature as a subset of cyclic division algebras over Q(zeta(3)) only for the dimension n = 2(s)n(1), where s is an element of {0,1}, n(1) is odd and the signal constellations are isomorphic to Z[zeta(3)](n) In this work, we propose an innovative methodology to extend the construction of minimum and non-minimum delay perfect codes as a subset of cyclic division algebras over Q(zeta(3)), where the signal constellations are isomorphic to the hexagonal A(2)(n)-rotated lattice, for any channel of any dimension n such that gcd(n,3) = 1. (C) 2012 The Franklin Institute. Published by Elsevier Ltd. All rights reserved.

Influence of the heat treatment on the nucleation of silver nanoparticles in Tm3+ doped PbO-GeO2 glasses

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Protective effect of nickel chloride on superoxide damage: enhancement of CuZn superoxide dismutase affinity to the oxygen free radical.

The effect of nickel from soluble NiCl2 on Cu-Zn superoxide dismutase (SOD) activity, as well as on rate of nitro blue tetrazolium reduction, was studied in vitro since lipid peroxidation has been implicated in cell damage by nickel insoluble compounds, whose toxicity and carcinogenicity are well established. The physical and chemical nature of nickel compounds is one of the key determinations of its toxicity. Soluble nickel freely enter cells, but is just as readily excreted reducing the opportunity for production of lipid damage. Nickel from NiCl2 strongly activated SOD activity. In vitro addition of nickel chloride to a crude lung preparation altered the KM for SOD without changing the Vmax. Nickel chloride produced increased enzyme affinity to the substrate, because decreased (O2-) concentration that yields half-maximal velocity. The combination of nickel and SOD may contribute to stabilization of the particular conformation of SOD responsible for maximal catalytically activity.

Signal and backgrounds for the single production of scalar and vector leptoquarks at the CERN LHC

We perform a detailed analysis of the potentiality of the CERN Large Hadron Collider to study the single production of leptoquarks via pp→e±q→ leptoquark →e± q, with e± generated by the splitting of photons radiated by the protons. Working with the most general SU(2)L⊗U( 1 )Y invariant effective Lagrangian for scalar and vector leptoquarks, we analyze in detail the leptoquark signals and backgrounds that lead to a final state containing an e± and a hard jet with approximately balanced transverse momenta. Our results indicate that the LHC will be able to discover leptoquarks with masses up to 2-3 TeV, depending on their type, for Yukawa couplings of the order of the electromagnetic one.

Single top quark at future hadron colliders: Complete signal and background study

We perform a detailed theoretical study including decays and jet fragmentation of all the important modes of single top quark production and all the basic background processes at the upgraded Fermilab Tevatron and CERN LHC colliders. Special attention is paid to the complete tree level calculation of the QCD fake background which was not considered in previous studies. An analysis of the various kinematical distributions for the signal and backgrounds allow us to work out a set of cuts for an efficient background suppression and extraction of the signal. It is shown that the signal to background ratio after optimized cuts could reach about 0.4 at the Tevatron and 1 at the LHC. The remaining after cuts signal rate at the LHC for the lepton+jets signature is expected to be about 6.1 pb and will be enough to study single top quark physics even during LHC operation at a low luminosity. ©1999 The American Physical Society.

Signal and backgrounds for leptoquarks at the CERN LHC. II. Vector leptoquarks

We perform a detailed analyses of the CERN Large Hadron Collider (LHC) capability to discover first generation vector leptoquarks through their pair production. We study the leptoquark signals and backgrounds that give rise to final states containing a pair e+e- and jets. Our results show that the LHC will be able to discover vector leptoquarks with masses up to 1.8-2.3 TeV depending on their couplings to fermions and gluons. ©1999 The American Physical Society.