Otimização de método para analise de tebutiurom, diurom e seus produtos de degradação em água superficial

In 2001, it was estimated that pesticide used worldwide exceeded 2.27 billion kilograms, over 35%, of which, were herbicides. Brazil is considered one of the leaders in the production of sugarcane and mainly ethanol as fuel. The monoculture of sugarcane requires the usage of a range of pesticides, among these, the herbicides diuron and tebuthiuron. The degradation products most studied (DCA and DCPU) are diuron's, especially for toxicological characteristics of this herbicide that is identified as carcinogen and suspected to be endocrine disruptor in mammals. After optimization of the chromatographic separation using HPLC-UV, the analytical curve was constructed in solvent and subsequently in the matrix (surface water). The extraction method contains the usage of SPE (solid phase extraction) (Strata-X, 200 mg/6 mL), applicating 1L of sample and elution with 5 mL of acetonitrile / methanol (50:50, v/v). Analysis by HPLC/UV was performed in gradient mode, acetonitrile/water (70/30-74/26 by 1 min, 74/26 - 78/22 till 3.2 min, returning to initial conditions and remaining this way until 10 min), 018 column (Phenomenex, 4.6 mm diameter, 250 mm long and 5pm particle size) and detection at 254 nm. Tests F and t were performed to verify the presence of the matrix effect. There was matrix effect to all analytes, ranging from -33% (DCA) and 38% (tebuthiuron). Thereby the method was optimized and validated for analysis of diuron, tebuthiuron, and DCPU DCA in surface water using HPLC/UV. The data obtained show that in order to assure the analytical reliability desired the use of the analytical curves in the matrix for the quantification of these analytes in water is required.

Fisiologia térmica e balanço hídrico em anfíbios anuros

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Da margem ao centro dos holofotes: o arcabouço legal dos/as catadores/as de material reiclável e reutilizável

Pós-graduação em Serviço Social - FCHS

O movimento ambientalista e as propostas de implantação de usinas de álcool no pantanal de Mato Grosso do Sul (1979-2009): um espaço sócio-ocupacional para o Serviço Social de MS

Pós-graduação em Serviço Social - FCHS

Importância da avaliação do ciclo de vida na análise de produtos: possíveis aplicações na construção civil

Much has been discussed lately about reusing waste in new construction materials and countless studies have been carried out based on this objective. However, before these products can be called “sustainable” and a recycling system can be effectively implemented, it is fundamental for all the aspects involved in this action to be understood, and more important, what are the true gains for the productive sector and what are the benefits for the environment if this was to occur. In order to obtain a general framework for all environmental aspects and potential impacts associated with these products, over their entire life cycle, the most appropriate methodology is the Life Cycle Assessment (LCA). In view of the above, the objective of this work is to provide an overview of current studies of LCA, its history, its importance, its standards and the methodology employed and its applications related to civil construction. It is expected, to obtain a more complete scenario of the influences from a study of LCA, as well as establishing a contribution for the assessment of specific products and processes for civil construction, disseminating the importance of the use of this tool within the sector.

Caracterização de impactos socioambientais no setor sucroalcooleiro: o caso da fuligem em Piracicaba - SP

A busca por novas fontes de energia é consequência do aumento da demanda de energia consumida no mundo. Com a instabilidade política dos países detentores das maiores reservas de combustíveis fósseis e a eminência do esgotamento dos recursos naturais surge a preocupação de produzir uma energia mais limpa, desta forma, surgem os estudos com a biomassa, no caso, a cana de açúcar. Esta pesquisa tem como objetivo entender as relações do cultivo cana e da produção de etanol, caracterizando seus impactos socioambientais. Além disso, procura demonstrar a manifestação de um dos efeitos negativos gerados na fase agrícola. A prática da queima da cana é muito antiga, porém ainda muito utilizada. Esta gera efeitos diretos na saúde do trabalhador e da população, neste sentido, procuramos saber se a população está ciente desta prática e das suas implicações. Portanto, esta pesquisa justifica-se para colaborar com os estudos ligados a produção de energias mais limpas, para alcançar o desenvolvimento sustentável

Análise de uso da terra e sua interferência em enchentes na região do Córrego Lavapés, Rio Claro (SP)

The development of cities is initially nearby rivers and with the intensification of the urbanization process occurs the soil sealing, leading to an increased level of water runoff, and, consequently, in a greater number of floods. The main goal of this study is to verify the interference of land occupation in the floods of the Lavapés Stream basin, Rio Claro (SP), in five temporal series, 1962, 1972, 1988, 1995 and 2014. The characterizations of land use were made from photo-interpretation and, thus, were produced thematic maps on scale 1: 20.000. The description of the Soil Conservation Service, 2007 was the basis for the classification of land use, thus achieving the CN parameter (Curve Number) used in hydrologic modeling done in IPHS1 program. The results indicate that soil sealing associated with the growth of the city of Rio Claro are responsible for increasing of the discharge in the Lavapés Stream basin and floods in this watershed

Proposta de trilha interpretativa para a Floresta Estadual Edmundo Navarro de Andrade (FEENA) - Rio Claro

Within the current context of environmental degradation, primarily caused by unsustainable pat terns of production and consumption (AGENDA 21, 1992), the Protected Areas (PAs) are considered internationally as one of the most successful measures for the conservat ion of biodiversity, according to the Union for the Conservation of Nature (IUCN). The city of Rio Claro (Sao Paulo, Brazi l ) has a significant conservation area in both environmental aspects as historical and cultural, the State Forest 'Edmundo Navarro de Andrade' (FEENA). Beyond the conservation measures, there is a need to develop environmental education that encourages community participation and appreciation in the unit 's maintenance and protection, as well as provide moments of reflection that could conduct perceptual changes, behavioral, attitudinal and evaluative on relations between human beings and their environment . This work brings the proposal to create an interpretive trail in the area of public use of FEENA to contribute to the Unit Management Plan in order to make it an Environmental Education tool. To prepare the planning of the interpretive trail, a deep bibliographic and cartographic review was performed on the subject. It was applied questionnaires in order to know the visitors better and map the features of public visitation, as well as map the visitor preferences about how they would like to receive information on the area and expose field studies in the track site. The trail was traced taking into account the environmental and social aspects, we propose a track suspended above the ground, in order to affect as little as possible and to include the area in the context of PAs people with reduced mobility and visually impaired

Perfil da renda e do volume dos resíduos sólidos urbanos da associação de catadores de São Manuel - SP

The implementation of residue selective collection has brought to the city of Sao Manuel an incalculable benefit. It brought a better life for a group of adults and children that lives in a humanitarian condition of extreme poverty. These people live in an open-air dump, disputing the remains found in fifteen tons of garbage that are deposited at the site almost every day.The objective of this paper is to present thecollectors annual income profile and the volume of solid waste collected.To present these factors, the total and fractionated amount according to their material items, collected since the creation of the Association in February 2003 until December 2008, were considered., In addition,the social gains were enumerated. These factors were developed from a theoretical base for municipal solid waste involving environmental, social, and financial concepts. Based on these results it was found that the ACAPEL income value was above the average of other income indicators of the population analyzed, besides the social value enhance that the creation of the Association brought to the people who work there.

Degradação urbana decorrente da atividade de mineração para a construção civil em Teresina - PI

Pós-graduação em Geografia - IGCE

Propostas para a elaboração de plano de gestão para a praia de Macapá - Luis Correia - PI

Pós-graduação em Geografia - IGCE

Recurso natural, organização espacial e ordenamento territorial: mineração e degradação de terras na depressão interplanáltica semiárida do Alto Coreaú (CE)

Pós-graduação em Geografia - IGCE

Cenários da expansão urbana e da legislação e os reflexos na cobertura vegetal arbórea e arbustiva na cidade de Americana-SP

Pós-graduação em Geografia - IGCE

As vozes e as visões dos catadores de materiais recicláveis sobre o meio ambiente

Pós-graduação em Serviço Social - FCHS

Benefícios na execução de uma obra sustentável em contrapartida aos métodos tradicionais da construção civil

The civil construction sector in Brazil is, simultaneously, a necessity that drives the economy and an evil that degrades the environment. Simple choices adopted in an enterprise can make big difference in harm caused by constructive practices, minimizing its harmful to the environment and making it sustainable. These choices, however, involve the use of materials and techniques often unknown by the builders, since the construction industry is very traditional. Even worse, the eco-friendly materials and sustainable techniques also face another obstacle to its use: the prejudice. Builders and customers prefer traditional methods to sustain belief that they present lower quality and higher price. This work raises awareness of the urgency with traditional methods must be overridden, showing practical and simple ways for this replacement, as well as confirm the quality equal to or even higher in the use of alternative materials and techniques, without addition in cost. Thus, the benefits are generated for all parties involved, from builders to residents