Espectroscopia de infravermelho e suas aplicações

Infrared spectroscopy (IR spectroscopy) explores the infrared region of the electromagnetic spectrum. Like any other spectroscopic technique, it can be used to identify a compound or the composition of investigate a sample. Spectroscopy (IR) is a very important technique in qualitative chemical analysis, widely used in the chemistry of natural products, organic synthesis and transformations. In this work we study of the theoretical foundations of infrared spectroscopy, the different vibration modes, experimental techniques, and the identification and characterization of solids. Were studied as applications: their use in thermograph and remote sensing satellites

Banco Central independente: evolução teórica e possibilidades de implantação deste sistema

Este trabalho busca mostrar a evolução teórica da tese de banco central independente e as diversas possibilidades de implantação deste sistema em alguns países. Além de uma breve introdução, está dividido em três capítulos e uma conclusão geral. O primeiro capítulo descreve a utilização do sistema banco central independente ao longo do século XX por diversos países. É feita uma divisão do século em vários períodos, mostrando como se deu a atuação dos bancos centrais dos países analisados em cada um desses espaços de tempo. O segundo capítulo analisa os pressupostos teóricos que sustentam a tese de banco central independente, mostrando a evolução das teorias monetárias ortodoxas ao longo do tempo e a importância disso para o tema estudado. O terceiro capítulo trata do caso brasileiro, apresentando, um breve histórico de seu banco central desde sua criação, passando pelas últimas décadas do século XX, até chegar aos dias atuais. O capítulo encerra com o debate entre os especialistas brasileiros sobre a possibilidade de implantação de um banco central independente no país

Influência da fonte alimentar na infecção de triatomíneos por Trypanosoma cruzi

Embora a doença de Chagas seja amplamente estudada, ainda não se conhece todos os interferentes que modulam a relação parasitária Trypanosoma cruzi- vetor- hospedeiro vertebrado. Sabe-se que as aves são refratárias ao T. cruzi, ou seja, o parasito não consegue estabelecer parasitismo nas mesmas, enquanto que nos camundongos a infecção ocorre. Essa refratariedade representa um exemplo de resistência natural do hospedeiro a uma infecção parasitária. Originalmente, acreditava-se que isso ocorria devido à presença de um anticorpo natural contra o T. cruzi no sangue das aves, porém estudos atuais atribuem tal atividade ao sistema complemento presente no sangue das mesmas. Pretendeu-se avaliar neste projeto se a referida característica peculiar do sangue das aves interfere no processo e no nível de infecção dos triatomíneos, em especial de Rhodnius neglectus, espécie de comprovada importância epidemiológica. Para tanto, utilizou-se a cepa Y de T. cruzi e ninfas de 4º estádio de R. neglectus. Avaliou-se também a capacidade lítica do soro de galinha em formas epimastigotas e tripomastigotas em meio de cultura LIT, utilizando a cepa Y. Referente à influência de diferentes fontes alimentares na infecção de R. neglectus por T. cruzi, observou-se um decréscimo no número de exemplares infectados após alimentação em patos , apresentando Índice de Infecção médio de 19,74%. Por outro lado, exemplares infectados após alimentação em camundongos não apresentaram diferença significante na parasitemia total. Os testes in vitro demonstraram que a adição de soro de galinha em meio de cultura LIT, com formas epimastigotas e tripomastigotas, foi capaz de diminuir notoriamente a contagem de parasitos móveis até a contagem zero, uma hora após a adição. O conjunto desses resultados sugere que a refratariedade das aves ao T. cruzi influencia a infecção de R. neglectus pelo flagelado e foi demonstrada, in vitro, pela ...

Alterações na dinâmica de colônias de Atta sexdens rubropillosa Forel, 1906 (Hymenoptera: Formicidae) submetidas ao tratamento com iscas tóxicas

As formigas cortadeiras são consideradas pragas por causarem diversos prejuízos em áreas agrícolas e, por este motivo, há um crescente interesse em métodos variados de controle destes insetos. Atualmente, existem diversos métodos de controle conhecidos, mas o mais utilizado é o controle químico, que apresenta diferentes estratégias de formulação e modos de aplicação. O principal método químico utilizado são as iscas tóxicas, que tem a melhor eficiência e já são utilizadas em escala comercial. O presente trabalho teve como objetivo avaliar as alterações que ocorrem na dinâmica de colônias de Atta sexdens rubropilosa Forel, 1906 (Hymenoptera: Formicidae) submetidas ao tratamento com iscas tóxicas contendo os ingredientes ativos sulfluramida e hidrametilnona, as quais serão comparadas com uma colônia controle, que receberá isca sem ingrediente ativo. Para isso, foram utilizadas três colônias de A. s. rubropilosa, mantidas em laboratório, com aproximadamente 1000 mL de jardim de fungo cada. Elas foram dispostas em vitrais, interligados a dois potes plásticos, um para a câmara de forrageamento e outro para o lixo. Um dia antes de iniciar o experimento, todo o lixo foi retirado e as colônias foram deixadas sem o fornecimento de alimento. Após 24 horas sem alimentação, as iscas foram oferecidas na câmara de forrageamento de cada colônia. A colônia 1 recebeu 3g de isca sem ingrediente ativo; a colônia 2 recebeu 3g de isca contendo sulfluramida; e a colônia 3 recebeu 3g de isca contendo hidrametilnona. Durante 10 dias, foram avaliados aspectos como carregamento, incorporação e devolução das iscas, alterações comportamentais das operárias classificadas como sintomas de intoxicação, mudanças no aspecto físico dos jardins de fungo, como umidade e aparecimento de fungos contaminantes, e a extinção da colônia. A partir dos dados obtidos, foram feitas análises comparativas das atividades comportamentais...

Compostos fenólicos de 10 variedades de uva

Phenolic compounds represent one of the main groups of secondary metabolites. Due to their chemical diversity, they have a variety of functions in plants, such as protection against ultraviolet radiation, herbivores and pathogens, and attraction of pollinators or dispersers of fruits and seeds. For human, the phenolic compounds are used like food colorings and flavors and, due to their pharmacological properties, mainly to antioxidant activity, they are associated with several health benefits, such as delay senility, prevention and therapy of cardiovascular diseases and of some cancers. The grapes are considered one of the main source of phenolic compounds and the fruit and its products are consumed in Brazil and worldwide. Considering the phenolic compounds diversity and their different distribution in the grape parts, this work had like aims the extraction, identification and quantification of the main classes of phenolic compounds of 10 grape varieties. The content of total phenols, flavanols and anthocyanins were determined, respectively, according to the Folin-Ciocalteu, DMACA and comparison of pH spectrophotometric methods. The content of total phenols varied from 142.75 + 1.86 to 483.39 + 5.90 mg.L-1 in the peel and from 86.50 + 0.54 to 146.32 + 9.97 mg.L-1 in the pulp. The amount of total flavanols varied from 3.68 + 0.03 to 6.92 + 0.26 mg.L-1 in the peel and from 0.90 + 0.00 to 1.36 + 0.00 mg.L-1 in the pulp. The content of total anthocyanins varied from 7.00 + 0.99 to 406.56 + 39.50 mg.L-1 in the peel and from 2.88 + 0.28 to 46.36 + 1.89 mg.L-1 in the pulp. The phenolic compounds concentration was higher in the peel than in the pulp. The total phenols and anthocyanins varied a lot while the total flavanols were more constant. The flavanols represent the smaller portion of phenolic compounds

Análises moleculares de populações de Wasmannia auropunctata Roger, 1863 (Hymenoptera: Formicidae) e da presença de endossimbiontes

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Resistência à flexão de uma resina acrílica após a incorporação de um polímero antimicrobiano

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Reabilitação oral de paciente com síndrome da combinação: relato de caso

The Combination Syndrome represents an important pathologic condition of the masticatory system that requires a complex rehabilitation treatment. The presence of flaccid mucosa is one of the most common features due to bone resorption of the pre-maxilla caused by anterior hyperfunction of the mandibular teeth on the maxillary complete denture, where the impact of oclusal loading in this region results in movement of the maxillary prosthesis into the ridge, resulting in increased resorption of the residual ridge, internal misfit and loss of the retention of the maxillary complete denture. The presence of flaccid mucosa, in such cases, leads to problems of support and stability of the maxillary complete denture, which can be treated by surgical reduction of the thickness of the tissue or using specific techniques of fabrication of prostheses. This article describes the oral rehabilitation of a patient with the Combination Syndrome where the surgical reduction of flaccid mucosa was not performed, using a modified technique of functional impression in two steps, with the objective of generating forces and less distortion in flaccid mucosa during functional impression.

Hipertonicidade muscular e confecção de próteses totais pela técnica da zona neutra: relato de caso clínico

Introduction: the oral rehabilitation in edentulous patients using removable complete dentures is a classic treatment, easily accessible, and presenting satisfactory results. However, to succeed in this type of treatment, stability is an extremely important factor. The neutral zone technique for the production of complete dentures determines the oral cavity space for the positioning of teeth and denture base that provide a neutralization of the forces delivered by lips, cheeks, and tongue, providing better stability and retention of prostheses, which is indicated in cases with history of difficulties in adapting the conventional mandibular denture. Objective and case report: this paper aimed to describe a clinical case report of the oral rehabilitation of a patient with paraprosthetic muscles hypertonicity through removable complete dentures produced by the neutral zone technique, using condensation silicone. Final considerations: the use of condensation silicone for the development of the neutral zone technique showed to be a good alternative for the development of this clinical case, providing satisfactory stability and retention of the complete mandibular denture.

Estudo prospectivo sobre a utilização de próteses totais implantossuportadas em pacientes edêntulos

The objective of this study was to evaluate the impact of replacing conventional mandibular complete dentures by complete fixed dentures on the oral health-related quality of life and kinesiographic parameters of maxillary edentulous patients. Material and Methods: edentulous patients (n = 16) received one set of new complete dentures and after the intraoral adjustments and adaptation period (30 days), the Brazilian version of Oral Health Impact Profile for assessing edentulous subjects (Ohip-Edent) was used to evaluate the oral health-related quality of life (OHQOL) of the participants. Additionally, the kinesiograph instrument K6-I (Myotronics Research Inc., Seattle, WA) was used to record opening and closure range of movement, mandibular movement, and the pattern of maxillary complete denture movement on chewing. Afterwards, the patients had their mandibular complete dentures replaced by a complete fixed denture and the same evaluation protocol was performed after 3 and 6 months. Ohip-Edent responses were analyzed using Wilcoxon's test for repeated measures (α = .05) and Kinesiographic data using the Student´s t test (α = .05). Results: The Ohip-Edent showed an improvement of general oral health-related quality of life after 3 and 6 months of the treatment with complete fixed dentures. Kinesiographic recordings revealed a significant increase on maximum mandibular movements of vertical opening and no differences for the movement of the maxillary complete denture on chewing after treatment with complete fixed dentures was observed. Conclusion: the installation of complete fixed dentures improved the OHQOL and changed mandibular movements, with increases in vertical amplitude of maximal opening.

Prótese metalocerâmica associada à prótese metaloplástica implantossuportada em paciente desdentado total

The use of different methods and materials should be considered during the planning of implant-supported prostheses. Complications such as fractures of the acrylic resin base, wear and fracture of teeth can occur frequently, creating the need for careful planning for each patient, which can make the selection of the type of treatment more complex. Thus, this article describes the oral rehabilitation of a completely edentulous patient with bimaxillary fixed implant-supported prosthesis, with complaints on aesthetics, loss of vertical dimension and fracture of acrylic resin teeth of the upper arch. After the restoration of vertical dimension, his dentures were replaced with new bimaxillary implant-supported fixed prostheses, ceramic and acrylic resin were used as veneering material for maxilla and mandible, respectively. At the end of the treatment, the patient received bimaxillary flat occlusal splints to protect the teeth and implants of possible parafunctional habits. The approach for the treatment allowed a quick and effective resolution, with aesthetic and functional outcomes very favorable for the patient.

Masticatory performance of complete denture wearers after using two adhesives: a crossover randomized clinical trial

Statement of problem Masticatory performance analysis of conventional complete denture wearers who use denture adhesives is scarce in the dental literature. Purpose The purpose of this study was to assess the effect of the use of 2 denture adhesives on the masticatory performance of conventional complete denture wearers by means of a crossover study. Material and methods Forty individuals who were edentulous received new maxillary and mandibular complete dentures, and, after an adaptation period, were submitted to masticatory performance analysis without denture adhesive (control). The participants were randomly divided and assigned to 2 protocols: protocol 1, denture adhesive 1 (Ultra Corega cream tasteless) use during the first 15 days, followed by no use of denture adhesive over the next 15 days (washout), and then use of denture adhesive 2 (Ultra Corega powder tasteless) for 15 days; protocol 2, denture adhesive 2 (Ultra Corega powder tasteless) use during the first 15 days, followed by no use of denture adhesive during the next 15 days (washout), and then use of denture adhesive 1 (Ultra Corega cream tasteless) for 15 days. The masticatory performance was assessed immediately after the use of denture adhesive by means of the sieve method, in which participants were instructed to deliberately chew 5 almonds for 20 chewing strokes. Masticatory performance was calculated by the weight of comminuted material that passed through the sieves. Data were analyzed by a 1-way ANOVA for paired samples and the multiple comparison of means by using the Bonferroni test (α=.05). Results A significant increase in masticatory performance was noted after using the Ultra Corega cream (mean, 32.6%) and Ultra Corega powder (mean, 31.2%) when compared with the control group (mean, 19.8%) (P<.001). No significant difference was found between the 2 denture adhesives evaluated. Conclusion The use of denture adhesive improved the masticatory performance of conventional complete denture wearers. No difference was found in masticatory performance with the use of cream or powder denture adhesive.

Surface properties and color stability of an acrylic resin combined with an antimicrobial polymer

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Effect of a Denture Adhesive on the Satisfaction and Kinesiographic Parameters of Complete Denture Wearers: A Cross-Over Randomized Clinical Trial

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Fate of non O157 Shigatoxigenic Escherichia coli in ovine manurecomposting

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)