Geochemical Study of the Itabirite Iron Ores of the Alegria Mine - Quadrilátero Ferrífero, Minas Gerais, Brazil

The iron ores of Alegria mine are composed of itabirites enclosing minor bodies of high-grade ores. The itabirites are classified according to mineralogical composition in five types: martite-rich, goethite-rich, specularite-rich, magnetite-rich and anphibolite-rich ores. The hematites are martite-rich, magnetite-rich, specularite-rich and more rarely, amphibolite-rich. Other classification criteria of the ores are based on the physical properties and the degree of compaction. As such, the itabirites and hematites can be classified as hard, friable and soft types. The mineralogical/textural evolution of the ores is linked to the pressure and temperature conditions that accompanied the tectonic processes in anphibolite facies and the different degrees of subsequent surficial weathering processes. Petrographic and microstructural studies indicate that the magnetite and amphibole bearing itabirites represent the parent rocks that created the other itabirites and that the specularite itabirites and the hard martite types are related to silica dissolution and redeposition in zones of high and low strain. Most of itabirites ores correspond to chert oxide facies banded iron formation, except the goethite and amphibole bearing itabirite that resemble a silicate or oxide-silicate facies with minor carbonate impurities. The great mass and pods of soft martite itabirites are probably shaley oxide facies BIFs with little volcanic contribution. Trace element contents of the Alegria's itabirites show strong dissimilarities with BIFs associated with volcanism (Algoma type), but closely ressemble to the Lake Superior type, with high content in Cr, Co and low V, Ni, Cu and Zn. Although the absolute contents of REE present in the Alegria's itabirites are, in general very low, the pattern when normalised by NASC is similar to the great majority of the Archean and Paleoproterozoic BIFs elsewhere in the world, and characterised by positive Eu anomaly.

Gênese dos corpos de sulfeto maciço hidrotermal e platinóides associados no depósito de Fortaleza de Minas (MG)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Caracterização estrutural da porção sul do greenstone belt de Guarinos, GO

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Caracterização geofísica e geológica das formações ferríferas do Grupo Macaúbas - MG

Pós-graduação em Geologia Regional - IGCE

Estruturação da seqüência vulcano-sedimentar Rio Mata Cavalo (Morro do Pilar, MG, Brasil) baseada na análise qualitativa de dados geofísicos

Geofísica terrestre (magnetometria e radiometria) foi utilizada como ferramenta de apoio ao mapeamento geológico em uma área de pesquisa mineral da Companhia Mineradora de Minas Gerais (COMIG), denominada Alvo Bueiro, localizada a sudeste da cidade de Morro do Pilar, na Serra do Espinhaço, Estado de Minas Gerais. A integração de informações de geologia de superfície com os dados geofísicos correspondentes permitiu definir quatro zonas: A, B, C e D. A Zona A, caracterizada por altos valores de susceptibilidade magnética e baixos valores de radiometria, é composta por itabiritos do Grupo Serra da Serpentina. A Zona B, pertencente ao mesmo grupo, é constituída por filitos cinza e metassiltitos e mostra baixa susceptibilidade magnética; interrupções nas linhas de contorno foram interpretadas como decorrentes de falhas de empurrão. A Zona C, relacionada à Seqüência Vulcano-Sedimentar Rio Mata Cavalo, é caracterizada por uma expressiva anomalia do campo magnético total em xistos máficos e ultramáficos com lentes de formações ferríferas e filitos carbonosos negros; esta zona hospeda as mais importantes anomalias geoquímicas de ouro conhecidas na área em estudo. A Zona D, correspondente a ortognaisses cisalhados do Complexo Dona Rita, mostra os mais elevados valores de radiometria do Alvo Bueiro e baixas respostas magnéticas.

As formações ferríferas bandadas de Piumhi: geologia, petrografia e caracterização tecnológica

Pós-graduação em Geologia Regional - IGCE

Geologia do platô N6 - província mineral de Carajás (SP)

The N6 Plateau presents an iron-ore occurence in Carajás Mineral Province, standing near to actually operating deposits. Geological mapping in 1:10,000 scale and integration of geochemical, geophysical, petrography and drilling turns possible interpretation of his geological evolution. The mapped area has lithotypes from Archean Grão Pará Group, comprising very lowgrade metamorphic basic rocks and iron formation and an Proterozoic sedimentary association of conglomeratic sandstones called as Caninana Unity. The structural geology in given by a regional scale homoclinal, where the Grão Pará Group strata dips towards SW, as a part of the Northern Limb of the Carajás Fold. Subsequent deformation associated to the installation of the Carajás Shear Zone presents as E-W fold axis. Geochemical evidence permits to consider de Parauapebas Formation as the rocks which has been hydrothermally-altered to outsourcing fluids responsible to deposition of iron formations in the oceanic system, including different signatures which can be interpreted as possible sub-embayments in the Carajás Basin. The iron ore in the area occurs in subsurface as very fine friable hematite generated by supergenous enrichment of the iron formation. The conceived geologic model differs from the current academic proposal on the fact that hydrothermal alteration has been involved on the jaspelite enrichment. Metamorphism on the Parauapebas Formation presents paragenesis considered as ocean-floor metamorphism which precedes de deformation insofar as the rocks show no tectonic fabric referring to shallow crust evolution. Geophysical methods such as magnetometry and gravimetry presents excellent results for structural interpretation in uneven exposed terrain

Rochas calciossilicáticas e feldspáticas na região de Castro Alves e Rafael Jambeiro (BA)

The towns of Castro Alves and Rafael Jambeiro, central-east of Bahia state, are located in the east of São Francisco Craton, in granulite terrains of Salvador-Curaçá Belt, formed in Paleoproterozoic. The region of study contains ortognaisses of Caraíba Complex, metamafic and metaultramafic rocks of São José do Jacuípe Suite, metasedimentary rocks of Tanque Novo-Ipirá Complex, granitoids, pegmatites and alkaline rocks. The study carried out regional and detailed geological mapping in addition to petrographical and geochemical characterization of six areas in the search for targets of feldspar and white diopside, minerals used in ceramic industry. The areas consist of granitic ortognaisses interspersed with lenses of mafic granulite rocks, calc-silicate rock, banded iron formations, paragnaisses, quartzites, and bodies of quartz-feldspar or feldspar pegmatites and alkaline rocks that fill discontinuities. The region of study contains four deformations phases, with a predominance of ductile structures. The foliation Sn has N30E to N70W direction, high angle of dip and is characterized by compositional banding of granoblastic and felsic bands interspersed with nematoblastic or lepidoblastic mafic bands. A mineral or stretching lineation Ln is associated with Sn and has trend of S55E to S72E. The rocks have been suffered a regional metamorphism with granulite facies peak and partial retrogression to greenschist facies. Geochemical studies indicate that the green coloring calc-silicate rocks have lower SiO2, MgO and higher Fe2O3 content compared with white calcssilicate rocks. The alkaline rocks of the studied area have higher Na2O, SiO2 and lower K2O, Fe2O3 content compared with others Paleoproterozoic alkaline rocks of Bahia state. The targets of diopside are associated with white calc-silicate rocks, while the targets of feldspar are associated with paragnaisses, pegmatites and alkaline rocks

Formation of colloidal particles of hydrous iron oxide by forced hydrolysis

The mechanism of formation and growth of hydrous iron oxide (FeOOH) during the initial stages of forced hydrolyses of ferric chloride aqueous solution was studied by small angle X-ray scattering (SAXS). The effect of the hydrolysis temperature (60°C, 70°C and 80°C) and of the addition of urea on the formation of colloidal particles under isothermal conditions were investigated. Based on the experimental scattering functions in the Guinier range, we suggest the presence of elongated colloidal particles. The particle diameter and length, and their variation with time, were determined by fitting the form factor of prolate ellipsoids to the experimental scattering functions. We have assumed that our solutions are in a dilute state and that all colloidal particles are approximately of the same size. The colloidal particles have geometrical shapes similar to those of the subcrystals that build up the superstructure of β-FeOOH crystals, indicating that the formation of this hydrous iron oxide is governed by an aggregation process. Otherwise, the addition of urea hinders the growth and yields smaller particles, with a reduction in size greater than 50%. © 2000 Elsevier Science B.V. All rights reserved.

Dinitrosyl iron complexes with cysteine. kinetics studies of the formation and reactions of dnics in aqueous solution

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Iron phthalocyanine in non-aqueous medium forming layer-by-layer films: growth mechanism, molecular architecture and applications

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Evidence for conformational changes in the yeast deoxyhypusine hydroxylase Lia1 upon iron displacement from its active site

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Iron Oxide Versus Fe55Pt45/Fe3O4: Improved Magnetic Properties of Core/Shell Nanoparticles for Biomedical Applications

In this paper, synthesis of the Fe55Pt45/Fe3O4 core/shell structured nanoparticles using the modified polyol process combined with the seed-mediated growth method is reported. Iron oxide shell thickness was tuned controlling the Fe(acac)(3)/FePt seeds in the reaction medium. Annealing of the core/shell structure leads to iron-rich layer formation around the hard FePt phase in the nanoparticle core. However, the 2 nm Fe3O4 shell thickness seems to be the limit to obtain the enhanced magnetization close to the alpha-Fe and preserving an iron oxide shell after annealing at 500 degrees C for 30 min in a reducing atmosphere. The presence of both the oxide layer on nanoparticle surface and an intermediate iron-rich FePt layer after annealing promote strong decreases in the coercive field of the 2-nm-oxide shell thickness. These annealed nanoparticles were functionalized with dextran, presenting the enhanced characteristics for biomedical applications such as higher magnetization, very low coercivity, and a slightly iron oxide passivated layer, which leads an easy functionalization and decreases the nanoparticle toxicity.

Formation Mechanism via a Heterocoagulation Approach of FePt Nanoparticles Using the Modified Polyol Process

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Zero valent iron mediated degradation of the pharmaceutical diazepam

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)