Deformation twinning and the hall-petch relation in commercial purity ti

The effect of grain size and deformation temperature on the behavior of wire-drawn a-Ti during compression has been examined. At strains of 0.3, the flow stress exhibited a negative Hall–Petch slope. This is proposed to result from the prevalence of twinning during the compressive deformation. Electron backscattered diffraction revealed that {1012} was the most prolific twin type across all the deformation temperatures and grain sizes examined. Of the twinning modes observed, {1122} twinning was the most sensitive to the grain size and deformation temperature. The range of morphologies exhibited by deformation twins is also described.

Determination of resin acids in pulp mill effluent and receiving waters by high performance liquid chromatography

Resin acids are reported to be of major toxicological importance in pulp mill effluents for Rainbow Trout. Their determination, using a high performance liquid chromatographic method, is described.

Wandering Rocks : truth and purity in the Australian Irish diaspora

This thesis comprises a novel, Wandering Rocks, and a discursive component concerning the Australian Irish diaspora. Diaspora theory, loss of culture, rememory and silence (especially around accounts of Irish women), sentimental and creative forces perpetuating identity, and the importance of written works as artefacts imbued with ;milieu effects' are explored.

Effect of grain size on corrosion of high purity aluminium

A complete understanding of how grain refinement, grain size, and processing affect the corrosion resistance of different alloys has not yet been fully developed. Determining a definitive 'grain size-corrosion resistance' relationship, if one exists, is inherently complex as the processing needed to achieve grain refinement also imparts other changes to the microstructure (such as texture, internal stress, and impurity segregation). This work evaluates how variation in grain size and processing impact the corrosion resistance of high purity aluminium. Aluminium samples with a range of grain sizes, from ∼100 μm to ∼2000 μm, were produced using different processing routes, including cold rolling, cryo rolling, equal channel angular pressing, and surface mechanical attrition treatment. Evaluation of all the samples studied revealed a tendency for corrosion rate to decrease as grain size decreases. This suggests that a Hall-Petch type relationship may exist for corrosion rate and grain size. This phenomenon, discussed in the context of grain refinement and processing, reveals several interesting and fundamental relationships.

Effect of grain size on deformation twinning in a magnesium alloy and commercial purity titanium

This data collection contains several optical microstructure images, EBSD maps and stress-strain curves. The research involves collecting data from samples with different grain sizes at several values of plastic strains to measure some important twinning parameters such as twin volume fraction and number of twins per grain. The aim of this study is to investigate the effect of grain size on deformation twinning behaviour in two hcp metals i.e. commercial purity titanium and AZ31 magnesium alloy.

Purity and enrichment of laser-microdissected midbrain dopamine neurons

The ability to microdissect individual cells from the nervous system has enormous potential, as it can allow for the study of gene expression in phenotypically identified cells. However, if the resultant gene expression profiles are to be accurately ascribed, it is necessary to determine the extent of contamination by nontarget cells in the microdissected sample. Here, we show that midbrain dopamine neurons can be laser-microdissected to a high degree of enrichment and purity. The average enrichment for tyrosine hydroxylase (TH) gene expression in the microdissected sample relative to midbrain sections was approximately 200-fold. For the dopamine transporter (DAT) and the vesicular monoamine transporter type 2 (Vmat2), average enrichments were approximately 100- and 60-fold, respectively. Glutamic acid decarboxylase (Gad65) expression, a marker for GABAergic neurons, was several hundredfold lower than dopamine neuron-specific genes. Glial cell and glutamatergic neuron gene expression were not detected in microdissected samples. Additionally, SN and VTA dopamine neurons had significantly different expression levels of dopamine neuron-specific genes, which likely reflects functional differences between the two cell groups. This study demonstrates that it is possible to laser-microdissect dopamine neurons to a high degree of cell purity. Therefore gene expression profiles can be precisely attributed to the targeted microdissected cells.

Functionalization of bamboo pulp fabrics with noble metal nanoparticles

Noble metal (gold and silver) nanoparticles (NPs) were synthesized in-situ on bamboo pulp fabrics. The gold NPs were reduced by bamboo pulp fabrics and bonded to fibers under heating, and an alkaline condition was needed to synthesize silver NPs in the presence of bamboo pulp fabrics. The synthesized gold and silver NPs endowed bamboo pulp fabrics with different colors because of their localized surface plasmon resonance (LSPR) property. The colors of the fabrics treated with metal NPs were extended through complex synthesis of gold and silver NPs in different proportions. The bamboo pulp fabrics treated with noble metal NPs showed good fastness to light and rubbing. In addition, the gold and silver NPs imparted bamboo pulp fabrics excellent UV protection property and remarkable antibacterial activity.

Preparation of cellulose nanofiber from softwood pulp by ball milling

This paper reports the possibility of producing cellulose nanofiber from softwood pulp using a simple ball milling technique under ambient pressure and at room temperature. The effects of milling conditions including the ball-to-cellulose mass ratio, milling time, ball size and alkaline pretreatment were investigated. It was found that milling-ball size should be carefully selected for producing fibrous morphologies instead of particulates. Milling time and ball-to-cellulose mass ratio were also found important to control the fiber morphology. Alkali pre-treatment helped in weakening hydrogen bonds between cellulose fibrils and removing small particles, but with the risks of damaging the fibrous morphology. In a typical run, cellulose nanofiber with an average diameter of 100 nm was obtained using soft mechanical milling conditions using cerium-doped zirconia balls of 0.4–0.6 mm in diameter within 1.5 h without alkaline pretreatment.

Comparison of laboratory-scale and industrial-scale equal channel angular pressing of commercial purity titanium

This study contrasts the extent to which laboratory and industrial scale variants of equal channel angular pressing (ECAP) impart desirable microstructures and mechanical properties in Grades 2 and 4 titanium. Industrial-scale ECAP-Conform (ECAP-C) with post-ECAP thermo-mechanical processing (TMP) enhanced performance levels beyond those achieved with the same material processed in the laboratory by ECAP only. ECAP-C processed titanium demonstrated exceptional tensile properties and fatigue strength, superior even to conventional Ti-6Al-4V.

Strain rate effect of high purity aluminum single crystals: experiments and simulations

In order to study the strain rate effect on single crystal of aluminum (99.999% purity), aluminum single crystals are fabricated and subjected to uniaxial compression loading at quasi-static and dynamic strain rates, i.e., from 10-4 s-1 to 1000 s-1. The orientation dependence is also investigated with single slip or multi slip. The stress-strain curves of pure Al single crystals along two orientations and at different strain rates are obtained after measuring initial orientation using the Laue Back-Reflection technique. Crystal Plasticity Finite Element Method (CPFEM) with three different single crystal plasticity constitutive models is used to simulate the deformations along two orientations under various strain-rates. The classical and two newly developed single crystal plasticity models are used in the investigation. The simulation results of these models are compared to experimental results in order to study their abilities to predict finite plastic deformation of single crystalline metal over a wide strain rate range.

Bending fatigue testing of commercial purity titanium for dental implants

High fatigue strength is one of the major requirements for dental implant materials. It was previously shown that the fatigue strength under conventional stress-control tension–compression testing can be doubled for commercially pure (CP) titanium processed by equal channel angular pressing. However, the fatigue endurance of an implant exposed to cyclic loading in corrosive media (bodily fluids) may potentially be compromised. In this work, non-conventional bending fatigue testing in air and in simulated body fluid (SBF) has been carried out for coarse-grained and ultrafine-grained CP titanium.