Composition dependency of the glass forming ability (GFA) in Mg—Ni—Si system by mechanical alloying

The pure elemental powder mixtures with the compositions of Mg₆₅Ni_xSi₃₅−_x (x = 10, 20, 25, 33 at.%) were subject to high-energy ball mill, and the structures of the mixtures at different intervals of milling were characterised by X-ray diffraction (XRD). The compositional dependency of the glass forming ability (GFA) in Mg–Ni–Si system was evaluated based on the experimental results and the theoretical calculation. The compositional dependency of GFA in Mg–Ni–Si system can be understood well by comparing the enthalpies of the crystalline and amorphous phases based on the Miedema's theory for the formation enthalpy of alloys. Increasing the Ni/Mg ratio and/or decreasing Si content can improve the amorphous formability. The calculation results might be of great help in optimising the composition with high GFA in Mg–Ni–Si system.

Dependency of recrystallization mechanism to the initial grain size

The effect of initial grain size on the recrystallization behavior of a type 304 austenitic stainless steel during and following hot deformation was investigated using hot torsion. The refinement of the initial grain size to 8 μm, compared with an initial grain size of 35 μm, had considerable effects on the dynamic recrystallization (DRX) and post-DRX phenomena. For both DRX and post-DRX, microstructural investigations using electron backscattered diffraction confirmed an interesting transition from conventional (discontinuous) to continuous DRX with a decrease in the initial grain size. Also, there were unexpected effects of initial grain size on DRX and post-DRX grain sizes.

Context dependency of comfort and energy performance in mixed mode offices

This article investigates the context dependency of comfort and energy performance in mixed-mode offices in the climate of Athens, Greece. It is based on a parametric study using the simulation software EnergyPlus. Context refers to different building design priorities on the real estate market (prestige, low cost and green), occupant behaviour scenarios (ideal and worst case) and cooling strategies (fixed and adaptive set points). Results are evaluated according to energy consumption and related greenhouse gas emissions, daylight autonomy, view and percentage of working time when heating and cooling are operating. The results indicate that a holistic approach to comfort and energy performance evaluation focused on the specific context of a building and its occupants is necessary to develop appropriate optimization strategies. In early design stages, such specific information is not yet available and ideal/worst-case scenarios can indicate the magnitude of influence of occupants compared to building design.

Oxygen dependency of hydrogen sulfide-mediated vasoconstriction in cyclostome aortas

Hydrogen sulfide (H₂S) has been proposed to mediate hypoxic vasoconstriction (HVC), however, other studies suggest the vasoconstrictory effect indirectly results from an oxidation product of H₂S. Here we examined the relationship between H₂S and O₂ in isolated hagfish and lamprey vessels that exhibit profound hypoxic vasoconstriction. In myographic studies, H₂S (Na₂S) dose-dependently constricted dorsal aortas (DA) and efferent branchial arteries (EBA) but did not affect ventral aortas or afferent branchial arteries; effects similar to those produced by hypoxia. Sensitivity of H₂S-mediated contraction in hagfish and lamprey DA was enhanced by hypoxia. HVC in hagfish DA was enhanced by the H₂S precursor cysteine and inhibited by amino-oxyacetate, an inhibitor of the H₂S-synthesizing enzyme, cystathionine β-synthase. HVC was unaffected by propargyl glycine, an inhibitor of cystathionine λ-lyase. Oxygen consumption (ṀO₂) of hagfish DA was constant between 15 and 115 mmHg P_O2 (1 mmHg=0.133 kPa), decreased when P_O2 <15 mmHg, and increased after P_O2 exceeded 115 mmHg. 10 μmol l^–1 H₂S increased and ⩾100μ mol l^–1 H₂S decreased ṀO₂. Consistent with the effects on HVC, cysteine increased and amino-oxyacetate decreased Ṁ_O2. These results show that H₂S is a monophasic vasoconstrictor of specific cyclostome vessels and because hagfish lack vascular NO, and vascular sensitivity to H₂S was enhanced at low P_O2, it is unlikely that H₂S contractions are mediated by either H₂S–NO interaction or an oxidation product of H₂S. These experiments also provide additional support for the hypothesis that the metabolism of H₂S is involved in oxygen sensing/signal transduction in vertebrate vascular smooth muscle.

On anomalous depth-dependency of the hardness of NiTi shape memory alloys in spherical nanoindentation

An experimental study on the indentation hardness of NiTi shape memory alloys (SMAs) by using a spherical indenter tip and a finite element investigation to understand the experimental results are presented in this paper. It is shown that the spherical indentation hardness of NiTi SMAs increases with the indentation depth. The finding is contrary to the recent study on the hardness of NiTi SMAs using a sharp Berkovich indenter tip, where the interfacial energy plays a dominant role at small indentation depths. Our numerical investigation indicates that the influence of the interfacial energy is not significant on the spherical indentation hardness of SMAs. Furthermore, the depth dependency of SMA hardness under a spherical indenter is explained by the elastic spherical contact theory incorporating the deformation effect of phase transformation of SMAs. Hertz theory for purely elastic contact shows that the spherical hardness increases with the square root of the indentation depth. The phase transformation beneath the spherical tip weakens the depth effect of a purely elastic spherical hardness. This study enriches our knowledge on the basic concept of hardness for SMAs under spherical indentation at micro- and nanoscales.

Time - Dependency of chloride diffusion in concrete: a brief review and preliminary results

Abstract
Chloride ingress into concrete has long been known to decrease the service life of built infrastructure. Inadequate knowledge of the physical reasons associated with chloride diffusion into concrete could generate chloride penetration profiles that become meaningless for prediction of service life. In this study, the effects of pore closure (physical effect) and changes in chloride binding (chemical effect) on chloride diffusion through Australian General Purpose (GP) cement pastes were investigated. Through - diffusion tests and “in - and - out” diffusion tests were conducted to monitor the time - dependent chloride diffusion through cement pastes cured from 1 to 28 days. The through - diffusion test quantified the overall chloride diffusion behaviour at different stages of cement hydration, which was a combined result of physical and chemical processes controlling diffusion. The “in - and - out” test differentiated the contributions of the physical and chemical processes on the chloride diffusion at different stages of cement hydration. As expected, the reduction of chloride diffusivity was significant during the first two weeks of curing, most likely attributed to the significant reduction of porosity as well as establishment of capillary discontinuities within the pore structure. It was also observed that the amount of bound chloride was not constant but increased significantly from 1 to 28 days of curing age.

A rough set approach for selecting clustering attribute

A few of clustering techniques for categorical data exist to group objects having similar characteristics. Some are able to handle uncertainty in the clustering process while others have stability issues. However, the performance of these techniques is an issue due to low accuracy and high computational complexity. This paper proposes a new technique called maximum dependency attributes (MDA) for selecting clustering attribute. The proposed approach is based on rough set theory by taking into account the dependency of attributes of the database. We analyze and compare the performance of MDA technique with the bi-clustering, total roughness (TR) and min–min roughness (MMR) techniques based on four test cases. The results establish the better performance of the proposed approach.

Location dependency and sport sponsors : a factor analytic study

Theories explaining the mechanics of sport sponsorship relationships arc underdeveloped (Gilbert, 1 988; Hock, Gendall, & West, 1990; Pope, 1 998), bolstered by studies lacking systematic methods (Kuzma, Shanklin, & McCall, 1993) and tending toward broad, descriptive, macro-level analysis (Sandler & Shani, 1993). This paper attempts to redress this empirical chasm in a small way by examining an element of the sponsorship relationship. Specifically this paper explores the importance of one particular mode of sponsorship delivery: the location of a venue containing sponsor affiliations or what has been named location dependency. Location dependency of sport sponsors has been shown to be a pivotal determinant when devising sponsorship proposals or when assessing the attractiveness of a sponsorship opportunity (Wester- beek, 2000). Factor analysis was used to determine if sponsors' response patterns would deliver a number of constructs that could be related to the concept of location dependency. Factor analysis revealed five factors that principally reinforced the notion of location dependency of sponsorship. T-tests delivered significant differences between location dependent and location independent sponsors on some of the factors. The results of this study suggest that appreciating the concept of location dependency may assist companies in the effective discharge of their sponsorship decisions.

The static and metadynamic recrystallization behaviour of an X60 Nb Microalloyed Steel

A rapid method has been developed to determine recrystallization kinetics of Nb microalloyed steels by interrupted hot torsion test. The softening behaviour was achieved as a function of different processing parameters. The method clearly identified three regions, where the strain dependency of the recrystallization rate varied. Firstly, at large strains the rate of recrystallization was not a function of strain; this is generally ascribed to metadynamic recrystallization. At lower strains the time to 50% recrystallization showed a power low relationship with strain, characteristic of static recrystallization. A further break point exists on the time for 50% softening curve when strain induced precipitation occurs in the material. The onset of strain induced precipitation was at strains below the strain to the peak stress at temperatures below 900°C. The experimental results were used to estimate the time for 50% softening and to anticipate the onset of the strain induced precipitation for the alloy of this study. Grain refinement of the recrystallized austenite continued to strains significantly beyond the peak stress and beyond the static to metadynamic recrystallization rate transition.

Case study research into Australian mechanical engineer attributes

The 1996 Johnson report on Australian engineering education recommended the development of a limited number of broadly defined attributes in engineering graduates as well as a broader based engineering
education. Within a year the Institution of Engineers, Australia responded by switching the focus of its engineering course accreditation to graduate attribute outcomes. It was to be the role of engineering school advisory panels to give greater definition to those attributes, but the scope of engineering is broad and the views of advisory panel members are largely influenced by their own often unique professional formation.
This paper presents a single discipline case study approach to identify the relative significance of a wide range of attributes required for the most common mechanical engineering roles in those industries that employ the greatest number of Australian mechanical engineers. Six industries were
identified that between them employ more than half of all Australian mechanical engineers, and most frequent or generic mechanical
engineering roles within those industries were studied.
Key findings of this research are then reviewed in the context of changing global engineering environment and educational practices.

Australian mechanical engineers : industries and attributes

The US and UK have had significant influence on the delivery and content of engineering programs both globally and particularly on Australia and yet the industrial profile of Australia has historically been significantly different from that of the US and UK. This paper first presents a study into the differences in industrial profile in the employment of mechanical engineers in the US, UK and Australia. This paper then presents key findings from a role-based study that identified the relative significance of a broad range of attributes for the most common mechanical engineering roles in the six industries that employ the greatest number of Australian mechanical engineers.

Hot deformation and recrystallization of austenitic stainless steel: Part 11. post-deformation recrystallization

The postdeformation recrystallization behavior of a hot-deformed austenitic stainless steel was investigated based on the first part of this study, in which the microstructure development during hot deformation and, in particular, the evolution of dynamic recrystallization (DRX), was studied. The effect of different parameters such as strain, strain rate, and temperature were examined. The dependency of the time for 50 pct softening, t 50, changed from “strain dependent” to “strain independent” at a transition strain (ε*) that was in the steady-state area of the hot deformation flow curve. The fully recrystallized microstructure showed a similar transition in strain sensitivity. However, this occurred at stains greater than ε*. A mathematical model was developed to predict the transition strain under different deformation conditions. Microstructural measurements show that the transition strain corresponds to approximately 50 pct DRX in the deformed structure at the point of unloading.

Multifractality and long-range dependence of asset returns: the scaling behavior of the Markov-switching multifractal model with lognormal volatility components

In this paper, we consider daily financial data from various sources (stock market indices, foreign exchange rates and bonds) and analyze their multiscaling properties by estimating the parameters of a Markov-switching multifractal (MSM) model with Lognormal volatility components. In order to see how well estimated models capture the temporal dependency of the empirical data, we estimate and compare (generalized) Hurst exponents for both empirical data and simulated MSM models. In general, the Lognormal MSM models generate "apparent" long memory in good agreement with empirical scaling provided that one uses sufficiently many volatility components. In comparison with a Binomial MSM specification [11], results are almost identical. This suggests that a parsimonious discrete specification is flexible enough and the gain from adopting the continuous Lognormal distribution is very limited.