Chromate replacement in coatings for corrosion protection of aerospace aluminium alloys

Mixed rare earth organophosphates have been investigated as potential corrosion inhibitors for AA2024-T3 with the aim of replacing chromate-based technologies. Cerium diphenyl phosphate (Ce(dpp) 3) and mischmetal diphenyl phosphate (Mm(dpp) 3) were added to epoxy coatings applied to AA2024-T3 panels and they were effective in reducing the amount and rate of filiform corrosion in high humidity conditions. Ce(dpp) 3 was the most effective and characterisation of the coating formulations showed approximately a factor of 5 reduction in both the number of corrosion filaments initiated as well as the length of these. Mm(dpp) 3 appeared to reduce the corrosion growth rate by a factor of 2 although it was the more effective inhibitor in solution studies. Spectroscopic characterisation of the coatings indicated that the cerium based inhibitor may disrupt network formation in the epoxy thus resulting in a coating that absorbed more water and allowed greater solubilisation of the corrosion inhibiting compound.

Web application protection against SQL injection attack

SQL injection vulnerabilities poses a severe threat to web applications as an SQL Injection Attack (SQLIA) could adopt new obfuscation techniques to evade and thwart countermeasures such as Intrusion Detection Systems (IDS). SQLIA gains access to the back-end database of vulnerable websites, allowing hackers to execute SQL commands in a web application resulting in financial fraud and website defacement. The lack of existing models in providing protections against SQL injection has motivated this paper to present a new and enhanced model against web database intrusions that use SQLIA techniques. In this paper, we propose a novel concept of negative tainting along with SQL keyword analysis for preventing SQLIA and described our that we implemented. We have tested our proposed model on all types of SQLIA techniques by generating SQL queries containing legitimate SQL commands and SQL Injection Attack. Evaluations have been performed using three different applications. The results show that our model protects against 100% of tested attacks before even reaching the database layer.

Novel watermarking methods for copyright protection of audio signals

This research presented improved watermarking methods for mono and stereo audio signals. To enhance the performance, novel methods are developed using echo hiding techniques and patchwork-based algorithms. The superior performances of the proposed methods are demonstrated by theoretical analysis and simulation examples, in comparison with the existing methods.

Development of a retention model for child protection workers

This thesis addressed the critical issue of retention in the child protection workforce. Key predictors of a workers 'intention to stay' or the 'likelihood of staying' were lifestyle factors and whether a worker had contemplated leaving the organisation. The degree of satisfaction was not in itself predictive of either intentions to stay or the actual 'likelihood of staying'.

Plant variety protection and traditional agricultural knowledge in Southeast Asia

This article provides an overview of the emerging plant variety protection (PVP) systems in Southeast Asia. The case studies are from countries that form part of the regional Association of Southeast Asian Nations (ASEAN), mainly Indonesia, Malaysia, Philippines and Thailand. The focus will be on the intersection between intellectual property rights (IPRs) and popular demands for the protection of the traditional knowledge (TK) of local communities. Factors that fuelled the emergence and shaped the content of the PVP laws were the obligation to comply with art 27(3)(b) of the Agreement on Trade Related Aspects of Intellectual Property Rights (TRIPS Agreement), aspirations for the development of the biotechnology industry, avoidance of possible sanction under the US ‘Special 301’ procedure, Free Trade Agreements (FTAs), the role played by the International Union for the Protection of New Plant Varieties (UPOV), technical assistance from UPOV member countries, membership of international biodiversity treaties and demands from civil society organisations for protection of TK. The PVP laws that resulted present an uneasy amalgam of conventional property rights with some aspects of protection of TK. It is very likely that the local communities claiming TK rights will face legal hurdles, in as much as government agencies implementing the law will face administrative and technical complications.

Active data-centric framework for data protection in cloud environment

Cloud computing is an emerging evolutionary computing model that provides highly scalable services over highspeed Internet on a pay-as-usage model. However, cloud-based solutions still have not been widely deployed in some sensitive areas, such as banking and healthcare. The lack of widespread development is related to users’ concern that their confidential data or privacy would leak out in the cloud’s outsourced environment. To address this problem, we propose a novel active data-centric framework to ultimately improve the transparency and accountability of actual usage of the users’ data in cloud. Our data-centric framework emphasizes “active” feature which packages the raw data with active properties that enforce data usage with active defending and protection capability. To achieve the active scheme, we devise the Triggerable Data File Structure (TDFS). Moreover, we employ the zero-knowledge proof scheme to verify the request’s identification without revealing any vital information. Our experimental outcomes demonstrate the efficiency, dependability, and scalability of our framework.

Reduction of the photocatalytic activity of ZnO nanoparticles for UV protection applications

The detrimental effects of UV radiation are having a significant impact on our life and environment. The development of effective UV shielding agents is therefore of great importance to our society. ZnO nanoparticles are considered to be one of the most effective UV blocking agents. However, the development of ZnO-based UV shielding products is currently hindered due to the adverse effects of the inherent photocatalytic activity exhibited by ZnO. This paper reports our recent study on the possibility of reducing the photoactivity of ZnO nanoparticles via surface modification and impurity doping. It was found that the photoactivity was drastically reduced by SiO2-coatings that were applied to ZnO quantum dots using the Stöber method and a microemulsion technique. The effect of transition metal doping on the photoactivity was also studied using mechanochemical processing and a co-precipitation method. Cobalt doping reduced the photoactivity, while manganese doping led to mixed results, possibly due to the difference in the location of dopant ions derived from the difference in the synthesis methods.