Transparent uv-shielding films from organic small molecule-intercalated layered double hydroxide nanoplatelets/polymer composite

In this study, layered double hydroxide (LDH) with nitrate as the interlayer anion has been partially exfoliated in dimethyl sulfoxide (DMSO). Atomic force microscopy (AFM) images showed that both the lateral size and the thickness of the LDH nanoplatelets were decreased after DMSO treatment. Formation of transparent LDH suspension in DMSO was observed. Taking this advantage, we have prepared transparent LDH/ethylene-vinyl alcohol copolymer (EVOH) nanocomposite films using DMSO as the processing solvent. Organic small molecules, UV absorbers, were intercalated into the LDH interlayers to incorporate the UV-shielding property into the transparent composite films. The thermal stability of UV absorbers was considerably improved after intercalation, which was attributed to the electrostatic interaction between the guest UV absorbers and the host LDH layers. The prepared composite films were flexible and exhibited excellent UV-shielding capability, but had transmittance as high as 90% in the visible region. The effect of LDH filler on thermal and mechanical properties of the composite films was also examined.

Partial exfoliation of layered double hydroxides in DMSO : a route to transparent polymer nanocomposites

Layered double hydroxides (LDHs), either having nitrate counter anions or intercalated with organic molecules, have been for the first time partially exfoliated in dimethyl sulfoxide (DMSO) to form a transparent suspension. Atomic force microscopy (AFM) images showed that both the lateral size and the thickness of the LDH nanoplatelets were decreased after the exfoliation. The organic-LDHs maintained their intercalation characteristics, i.e. the thermal stability improvement of the incorporated organic anions, after the exfoliation in DMSO. Transparent ethylene-vinyl alcohol copolymer (EVOH) nanocomposite films containing partially exfoliated LDHs intercalated with UV absorbers were prepared using DMSO as the processing solvent. As the first reported example of a highly transparent LDH/polymer composite, the obtained composite film had a visible light transmittance of 90% (comparable to that of the pure matrix), was flexible and exhibited an excellent UV-shielding capability and thermal stability.

High quality electrospun nanofibres

The data collected relates to the operating parameters of electrospinning, the nanofibre and fibrous membrane properties and the performance evaluation in different applications.

Late Middle Permian (Guadalupian) fusuline fauna from the Gyanyima area of Burang County, Tibet, China and its paleobiogeographic implications

Numerous Permian limestone blocks exposed along the Yarlung-Zangbo Suture Zone have been named Tibetan facies exotic limestone blocks or Chitichun-type Permian deposits.The Gyanyima limestone block,one of those limestone blocks,is located in Burang County,southwestern Tibet.Fusulines are abundant in the Gyanyima limestone block especially for Middle Permian Xilanta Formation.The fusuline fauna comprises 10 genera,respectively Neoschwagerina, Yangchienia, Armenina, Verbeekina, Paraverbeekina, Kahlerina, Lantschichites, Codonofusiella,Chusenella, Nankinella.This fauna indicates a Midian age(Late Guadalupian or Lengwuan age of South China) in terms of the coexistence of Kahlerina, Lantschichites, Codonofusiella and Neoschwagerina.

Ordovician nautiloid fossils of Xainza region, Tibet

The Taerma bridge-Zhakang in the Xainza area is the second spot of Ordovician in northern Tibet based on the discovery of some reliable fossils. The strata contain a large amount of fossils of many taxa, which developed well enough to attain reliable support for era and distinctive boundary. It is the best spot for the fossil study of the Ordovician in the northern Tibet up to now and provides important clues to the classification and correlation of the Ordovician and to the paleogeography distribution as well as to the tectonic evolution of the northern Tibet. 29 species of Nautiloid fossils, which belong to 3 orders, 8 families and 15 genera, have been identified. Among them,3 genera and 9 species are new. Here only one new genus Eneoceras gen. nov. and six new species are described in detail as example. Other two new genera Taremaocera's and Variabioceras will be described in other papers.Genus Eneoceras gen.nov.Diagnosis:The new genus Eneoceras gen. nov. is characterized by the features as “Conch orthoconic, medium in size. The surface is decorated with annulus which array in a distance as the septa. Conch enlarging slowly. Compressed laterally. Circular in cross section. Siphuncle small, situated central from ventral in position. Spetal neck subcyrtochoanitic. Slightly expanded in connecting rings. Siphuncle appears as a string of beads with thin parietal deposits in it. Medium in spetal density. Thin epithecal and hypothecal deposits developed in cameras

New materials of Ordovician nautiloids from Xainza,Tibet

Eastern Taerma bridge-Zhakang was found in recent years to be the second spot of Ordovician outcrop based on reliable fossils. The nautiloids described here include one new genus, two new species and one indeterminate species,which represent only a small fraction of the nautiloids collected from this area. They are new materials of Ordovician nautiloids that have been determined up to now, which enrich Ordovician nautiloid faunal assemblages as well as provide new data to both classification and correlation of the Ordovician for this area and geographical distribution of nautiloid fauna.

Integrated fluid-thermal-structural numerical analysis for the quenching of metallic components

The quenching of a metal component with a channel section in a water tank is numerically simulated. Computational fluid dynamics (CFD) is used to model the multiphase flow and the heat transfer in film boiling, nucleate boiling and convective cooling processes to calculate the difference in heat transfer rate around the component and then combining with the thermal simulation and structure analysis of the component to study the effect of heat transfer rate on the distortion of the U-channel component. A model is also established to calculate the residual stress produced by quenching. The coupling fluid-thermal-structural simulation provides an insight into the deformation of the component and can be used to perform parameter analysis to reduce the distortion of the component. © 2011 Shanghai Jiaotong University and Springer-Verlag Berlin Heidelberg.

Elevated levels of triglyceride and triglyceride-rich lipoprotein triglyceride induced by a high-carbohydrate diet is associated with polymorphisms of AP0A5-1131T>C and AP0C3-482C> in chinese healthy young adults

Background/aims: Changes in lipid profiles have been shown to be associated with diet and apolipoprotein (APO) polymorphisms. Therefore, 2 polymorphisms, i.e. APOA5-1131T>C and APOC3-482C>T, and serum lipids were examined in a Chinese healthy young population with high-carbohydrate/low-fat (HC/LF) diet intervention.

Methods: After a wash-out diet for 7 days, 56 young adults (22.89 +/- 1.80 years) received the HC/LF diet for 6 days. Body mass index (BMI) and fasting serum lipid profiles at baseline, after the wash-out diet, and after the HC/LF diet were measured.

Results: APOA5-1131C carriers had higher triglyceride (TG) and TG-rich lipoprotein TG (TRL-TG) levels at baseline and after the HC/LF diet, though this mainly corresponded to the female cohort. APOC3-482T carriers had higher TRL-TG levels following the wash-out and HC/LF diets, but these were not directly attributable to a single gender.

Conclusions: Both polymorphisms may play an important role in the elevated TG and TRL-TG levels induced by the HC/LF diet, especially in females, thus indicating a potential dietary prevention of coronary heart disease in this Chinese cohort.

Associations of the SREBP-1c gene polymorphism with gender-specific changes in serum lipids induced by a high-carbohydrate diet in healthy Chinese youth

We investigated the possible association between the sterol regulatory element-binding protein-1c gene (SREBP-1c) rs2297508 polymorphism and the changes in lipid profiles in a high-carbohydrate and low-fat (high-CHO/LF) diet in a Chinese population well characterized by a lower incidence of coronary heart disease and a diet featuring higher carbohydrate and lower fat. Fifty-six healthy youth (aged 22.89 ± 1.80 years) were given wash-out diets of 31% fat and 54% carbohydrate for 7 days, followed by the high-CHO/LF diet of 15% fat and 70% carbohydrate for 6 days, without total energy restriction. Fasting blood samples were collected. Serum variables of lipid and glucose metabolism after the wash-out and high-CHO/LF diets, as well as the rs2297508 polymorphism, were analyzed. Compared with the male subjects on the wash-out diet, significantly elevated levels of high-density lipoprotein cholesterol (HDL-C) and decreased levels of apolipoprotein B-100 were observed in the male carriers of the C allele after the high-CHO/LF diet. In the female subjects, significantly increased triacylglycerol levels, insulin, and homeostasis model assessment of insulin resistance (HOMA-IR) were found in the GG genotype after the high-CHO/LF diet. These results suggest that the C allele of the rs2297508 polymorphism is associated with a retardation of the increases in serum triacylglycerol, serum insulin, and HOMA-IR in females and with the elevated serum HDL-C in males after the high-CHO/LF diet.

One-step vapour-phase formation of patternable, electrically conductive, superamphiphobic coatings on fibrous materials

Patternable, electrically conductive coatings having a superhydrophobic and superoleophobic surface have been prepared by one-step vapour-phase polymerisation of polypyrrole in the presence of a fluorinated alkyl silane directly on fibrous substrates. The coated fabrics showed a surface resistance of 0.5-0.8 kΩ □^-1 with water and hexadecane contact angles of 165° and 154°, respectively.