Dielectric properties of conducting polymer

The dielectric properties of conducting polymer composites containing polypyrrole (PPy) crushed films, PPy powder, polyaniline (PAn) base and acid powders as the dispersants and silicone rubber and vinyl ester as matrix materials have been investigated in the frequency range 2-18 GHz. The dielectric parameters such as the real part, epsiprime, and imaginary part, epsiPrime, of the permittivity and loss tangent, tandelta, increase with increasing conductivity and concentration of the dispersant. The geometrical shape of the dispersant governs the ability of conductive network formation which is indicated by a large drop in the resistivity of the composite. Also, dispersant/matrix interactions and physical properties of the matrix influence the agglomeration of the dispersant phase which, in turn, affects the dielectric properties of the composites. Flakes of PPy obtained by crushing highly conductive films and large PAn powder aggregates were unable to form a conducting network. The composites without a network of dispersant exhibit low dielectric parameters. On the other hand, high values of tan delta ranging from 0.7&ndash;1.1 were achieved for the PPy powder (15 parts)/silicone rubber composites where a conducting network was observed. <br />

Comparing different economic linkages among commodity futures

Gasoline (GA) and kerosene (KO) are extracted from crude oil (CO), such that the three fuel commodities share a chemical link. On the other hand, GA also shares an industrial link with natural rubber (NR) and palladium (PA) as complementary commodities that are heavily consumed by the automobile industry. We contrast the information content embedded in the two economic linkages. Focusing on TOCOM futures contracts written on the five commodities and centering on GA, we confirm that incremental information provided by either CO, KO or NR, PA over a buy-and-hold strategy and a naive forecast, are both statistically and economically significant. While the chemical link forecast is more profitable, a double-link forecast generated from a VECM with two cointegrating vectors (KO-GA and GANR prices) outperforms both single-link forecasts based on risk-adjusted profit net of transaction costs. Further comparisons against the profitability of commodity-based momentum strategies documented in Erb and Harvey (2006) and Miffre and Rallis (2007) show that the double-link forecast holds its own against the most profitable of the 75 momentum strategies considered. This strongly suggests that not only are there incremental profits to be gained from harnessing and combining economic links among commodity futures, the resultant incremental profits are economically significant against other proven commodity-based trading strategies in the existing literature.<br />

Involvement of rootstocks and their hydraulic conductance in the drought resistance of grafted rubber trees

Improving drought resistance of rubber trees has become a pressing issue with the extension of rubber plantations and the prevalence of seasonal drought. Root system is vital to water and nutrients uptake of all plants, therefore, rootstocks could play decisive roles in drought resistance of grafted rubber trees on a specific scion clone. To investigate the responses of different clone rootstocks and their grafted trees to water stress and find applicable methods for selecting drought resistant rootstocks, seven related parameters and root hydraulic properties of both seeds originated and grafted saplings of PB86, PR107, RRIM600 and GT1 were measured to assess their drought resistance. It was shown that the rootstock drought resistance and root hydraulic conductance may improve the drought resistance of the grafted rubber trees. Among the four clone rootstocks, GT1, which demonstrated more resistant to drought and higher root hydraulic conductance, was comparatively resistant to drought both for the seed propagation seedlings and grafted saplings. In addition, studies on the grafted saplings with different root hydraulic conductance further validated the possibility of selecting drought resistant rootstocks on the basis of rootstock hydraulic conductance using a high-pressure flow meter.

Structure and properties of self-assembled narural rubber/multi-walled carbon nanotube composites

Natural rubber (NR)/multi-walled carbon nanotube (MWCNTs) composites were prepared bycombining self-assembly and latex compounding techniques. The acid-treated MWCNTs (H2SO4: HNO3=3:1,volume ratio) were self-assembled with poly (diallyldimethylammonium chloride) (PDDA) through electrostaticadhesion. In the second assembling, NR/MWCNTs composites were developed by mixing MWCNTs/PDDAsolution with NR latex. The results show that MWCNTs are homogenously distributed throughout the NRmatrix as single tube and present a great interfacial adhesion with NR phase when MWCNTs contents areless than 3 wt%. Moreover, the addition of the MWCNTs brings about the remarkable enhancement in tensilestrength and crosslink density compared with the NR host, and the data peak at 2 wt% MWCNTs loadings.When more MWCNTs are loaded, aggregations of MWCNTs are gradually generated, and the tensile strengthand crosslink both decrease to a certain extent.

Preparation of constant viscosity natural rubber with mercaptan

Constant viscosity natural rubber has been prepared using mercaptan. The accelerated storage tests indicate that the storage hardening phenomenon of natural rubber can be inhibited by mercaptan. The amount of mercaptan (2-mercaptobenzothiazole) of 0.14 phr is sufficient to prepare constant viscosity natural rubber and the storage hardening numbers of constant viscosity NR in both Mooney viscosity and Wallace plasticity are less than 4. The processing properties and anti-oxidative behavior of CV-NR can be improved, although the mechanical properties of vulcanizates decreased slightly as compared to those of natural rubber. The results further support the hypothesis that the abnormal groups in natural rubber molecules are aldehyde groups and are responsible for the hardening of natural rubber.

Structure and thermal stability of natural rubber reinforced with in situ generated zinc sorbate

In situ prepared zinc disorbate (ZDS) in natural rubber (NR) by the reaction of zinc oxide and sorbic acid was used to reinforce the dicumyl peroxide-cured NR vulcanizate. The changes in mechanical properties of NR vulcanizates after ageing and were determined and the structures and thermal stability of vulcanizates were also analyzed using scanning electron microscope and thermal gravimetric analyzer. The change ratios in tensile strength and elongation at break of NR vulcanizate with theoretic formation of ZDS of 21phr can be increased to -33 from -44 and -27 from -38 after ageing and the initial weight loss temperature of NR vulcanizate can be increased for about 7&Acirc;&deg;C as compared to un-reinforced NR vulcanizate, indicating that the antioxidative behavior and thermal stability of NR can be improved significantly with theoretic formation of ZDS of 21phr.

The effects of testing procedure on critical fall height determination for third-generation synthetic turf

Test procedures and their accuracy in determining critical fall height (CFH) on sporting grounds are paramount to player safety. The procedure currently adopted for synthetic turf in Australian football [1] consists of four consecutive drops at various drop heights at three test locations on the sample. The quantity and packing of the infill in third-generation turf and the pooling effect of the rubber particles with consecutive drops suggests that the current standard protocol may need re-assessment. Therefore, the purpose of this pilot study was to investigate whether current methods of testing for CFH are appropriate for third-generation synthetic turf or whether an alternative or adapted method needs to be developed. CFH was measured, using a HISUN Uniaxe-II Impact Tester, on 12 combinations of synthetic turf samples (four different products with three shock pad options). Three conditions were investigated on each sample; the existing protocol; an alternative 12 single-drop protocol and four single drops from the CFH determined from the existing protocol. A significant difference was found for both absolute and percentage difference between the existing and 12 single-drop protocol, with p = 0.001 and t = 4.33 and p &lt; 0.001 and t = 6.03, respectively. There was also a significant difference between the CFH reached with and without a shock pad for both the existing protocol and the 12 single-drop protocol. The results of this pilot study demonstrate that differences do occur with alterations to the existing protocol and highlight the need for a more detailed characterisation of testing methods on third-generation synthetic turf and the response of surfaces to them. <br />

Reinforcement of natural rubber with core-shell structure silica-poly(Methyl Methacrylate) nanoparticles

A highly performing natural rubber/silica (NR/SiO2) nanocomposite with a SiO2 loading of 2&thinsp;wt% was prepared by combining similar dissolve mutually theory with latex compounding techniques. Before polymerization, double bonds were introduced onto the surface of the SiO2 particles with the silane-coupling agent. The core-shell structure silica-poly(methyl methacrylate), SiO2-PMMA, nanoparticles were formed by grafting polymerization of MMA on the surface of the modified SiO2 particles via in situ emulsion, and then NR/SiO2 nanocomposite was prepared by blending SiO2-PMMA and PMMA-modified NR (NR-PMMA). The Fourier transform infrared spectroscopy results show that PMMA has been successfully introduced onto the surface of SiO2, which can be well dispersed in NR matrix and present good interfacial adhesion with NR phase. Compared with those of pure NR, the thermal resistance and tensile properties of NR/SiO2 nanocomposite are significantly improved.