Synthesis of cubic tantalum nitride nanocrystallites

Cubic tantalum nitride (TaN) nanocrystallites were synthesized by the direct-current (dc) arc discharge method in N 2 gas. The influence of N 2 pressure on the as-synthesized cubic TaN samples was studied. The growth mechanism of cubic TaN was discussed. XRD, TEM and XPS were used to characterize the product. The results show that the influence of N 2 pressure plays a key role in the preparation of pure cubic TaN nanocrystallites. The size of cubic TaN nanocrystallites obtained is 5-10 nm.

Comparative study of ni effect on the corrosion behavior of low alloy steels in FGD and acid rain environments

The alloying effect of a small amount of nickel on low alloy steel for application to flue gas desulfurization(FGD) systems was studied. The structural characteristics of the rust layer were investigated by scanning electron microscopy(SEM). The electrochemical properties were examined by means of potentiostatic polarization test, potentiodynamic polarization test, and electrochemical impedance spectroscopy(EIS) in a modified green death solution of 16.9 vol.% H2SO4+0.35 vol.% HC1 at 60°C and an acid rain solution of 6.25 X 10-5 M H2S04+5.5 X 10-3 M NaCl at room temperature. It was found that as the amount of nickel increased, the corrosion rate increased in the modified green death solution, which seemed to result from micro-galvanic corrosion between NiS and alloy matrix. In acid rain solution, the corrosion rate decreased as the amount of nickel increased due to the repulsive force of NiFe204 rust against Cl-ions by electronegativity.

High-pressure study of low-compressibility Ta2N

Room temperature synchrotron x-ray diffraction experiments were performed on nanocrystal Ta₂N in a diamond anvil cell to a pressure of 55.48 GPa. This nitride is a well-known kind of high-hardness material, and it is found to be highly incompressible. The structure is stable with no phase transitions observed in this pressure range. The zero-pressure bulk modulus and its pressure derivative at ambient pressure are B₀ = 360 ± 3 GPa, B₀' = 4, and in room conditions, the a and c parameters are 3.054 Å, 4.996 Å, respectively. The bulk modulus of Ta₂N is greater than those of TaC, ε-TaN, Cr₂N and MoN. The differences in bulk moduli might be due to the differences in structure and the cohesive energy among these phases.

Triple G girls get going in tennis : resource manual

Physical activity is ranked second in importance only to tobacco control in health promotion and disease prevention in Australia. Individuals can be active in many ways every day, including –walking to and/or from school, work and other places of interest; participating in sports clubs; going to the YMCA or community leisure centre where you can be active through gyms, group fitness classes or in the swimming pool; visiting local parks and walking trails, and even at home and in the backyard. You can always find ways to be active in the community.

Promoting physical activity to young people is important for developing healthy lifestyles now and maintaining them for the future. A physically active lifestyle can be of benefit to physical, mental and social health. Despite these benefits, adolescent girls and young women are considerably less active than their male counterparts, and sport participation decreases dramatically among girls during their secondary school years. Many physical education teachers have also expressed concern about girls minimising their participation in school physical education. Consequently, it is timely that a project such as Triple G ‘Girls Get Going in Tennis, in Football, and at the YMCA’ should be developed and implemented in an effort to arrest the decline in girls’ participation in sport, physical activity and physical education.

The Triple G program aims to develop, implement and evaluate a program to promote participation in physical activity by girls in rural and regional schools and communities. The impact of the Triple G program on the mental and physical wellbeing of the girls will also be evaluated. The program specifically aims to create school and community linkages through the introduction of tennis coaches, football coaches, and YMCA instructors into the physical education class to team teach with physical education staff during the 2011 school year. As part of the school-based program, Year 7 – 9 girls will participate in a YMCA unit and one of tennis or football during their physical education classes (6 sessions x 100mins each). Each unit is then followed by an eight week afterschool program at the local tennis or football club, or YMCA centre.

Cellulose nanofibre textured SERS substrate

Poor reproducibility limits the wide uptake of low-cost surface enhanced Raman spectroscopy (SERS) substrates. This study reports a relatively low-cost and reproducible cellulose nanofibre (CNF) textured SERS substrate. Utilizing a layer of CNFs deposited onto glass slides, nanoscale roughness was achieved, which facilitated effective aggregation of gold nanoparticles (AuNPs) to form a novel CNF textured SERS substrate. This substrate meets the critical roughness requirements to control the distribution of AuNPs to provide 'hot spots' for SERS detection, offering significant signal enhancement. The reproducibility and accuracy of low-cost cellulosic SERS substrates were significantly improved on a model SERS molecule of 4-aminothiophenol.

Effect of sintering temperature on electrochemical performance of LiFe0·4Mn0·6PO4/C cathode materials

Carbon coated LiFe0·4Mn0·6PO4 (LiFe0·4Mn0·6PO4/C) was synthesised using high energy ball milling and annealing processes. The starting materials of Li2C2O4, FeC2O4.2H2O, MnC2O4.2H2O, NH4H2PO4 were firstly milled for 40 h, and followed by further milling for 5 h after adding glucose solution. The milled sample was heated at different temperatures (550, 600, 650 and 700°C) for 10 h to produce LiFe0·4Mn0·6PO4/C composites. The structure and morphology of the samples were investigated using X-ray diffraction, field emission scanning electron microscopy, and high resolution electron microscopy. The phase of samples annealed at 550 and 600°C mainly consists of olivine type LiFePO4, but a small amount of Fe2P impurity phase is formed in the samples annealed at 650 and 700°C. Electrochemical analysis results show that LiFe0·4Mn0·6PO4/C synthesised at 600°C exhibits the best performance with the initial discharge capacity of 128 mAh g-1 at 0·1 C, and 109 mAh g-1 at 1 C after 500 cycles. The LiFe0·4Mn0·6PO4/C exhibits excellent electrochemical properties for high energy density lithium ion batteries.

Placing sensors for area coverage in a complex environment by a team of robots

Existing solutions to carrier-based sensor placement by a single robot in a bounded unknown Region of Interest (ROI) do not guarantee full area coverage or termination. We propose a novel localized algorithm, named Back-Tracking Deployment (BTD). To construct a full coverage solution over the ROI, mobile robots (carriers) carry static sensors as payloads and drop them at the visited empty vertices of a virtual square, triangular, or hexagonal grid. A single robot will move in a predefined order of directional preference until a dead end is reached. Then it back-tracks to the nearest sensor adjacent to an empty vertex (an "entrance" to an unexplored/uncovered area) and resumes regular forward movement and sensor dropping from there. To save movement steps, the back-tracking is carried out along a locally identified shortcut. We extend the algorithm to support multiple robots that move independently and asynchronously. Once a robot reaches a dead end, it will back-track, giving preference to its own path. Otherwise, it will take over the back-track path of another robot by consulting with neighboring sensors. We prove that BTD terminates within finite time and produces full coverage when no (sensor or robot) failures occur. We also describe an approach to tolerate failures and an approach to balance workload among robots. We then evaluate BTD in comparison with the only competing algorithms SLD [Chang et al. 2009a] and LRV [Batalin and Sukhatme 2004] through simulation. In a specific failure-free scenario, SLD covers only 40-50% of the ROI, whereas BTD covers it in full. BTD involves significantly (80%) less robot moves and messages than LRV.

The high renaissance properties of porous three dimensional graphene using one step reduction and its application in flexible conductor

 A super conductive graphene with continuous three dimensional (3D) porous structures that can potentially be used as flexible conductors has been produced by one step reduction of graphene oxide (GO) film. The high renaissance properties have been demonstrated by mechanical and electrical results where a noticeable increase in the electrical conductivity to 3850 S/cm has been demonstrated after embedding the 3D graphene foam into nearly insulated polydimethylsiloxane (PDMS). The graphene integrated PDMS film has a higher strain up to 100% elongation compared with the strain of only 60% for PDMS. Fourier transform infrared (FTIR) and x-ray photoemission spectroscopy (XPS) results reveal that most oxidized groups have been removed, which contributes to the renaissance of most outstanding properties of graphene because of the recovery of sp2 carbon structures.

A facile synthesis of mesoporous silica nanoparticle and its morphology manipulation by varying pH value

 Mesoporous silica nanoparticles (MSNs) with particle size of20 nm have been synthesised through the template directed method at low temperature. The pH value of the reaction solution was found to have a great impact on the morphology of the final products. The morphology of resultant MSNs were investigated through transmission electron microscope. The mesoporous structure was examined by Brunauer-Emmett-Teller and Barrett-Joyner-Halenda methods. The results suggested that the high pH value had a great effect on the morphology of the final MSNs. Higher pH value intensified the interaction between particles. The pH value less than 10 is good for the formation of nanoparticles, while at pH 12, a silica framework with heterogeneous mesopore structure can be obtained.