Geografías psicológicas de los recursos educativos

¿Qué recursos dispone un profesor, alumno, padre o escuela para optimizar los procesos de enseñanza y aprendizaje? El objetivo del articulo es presentar un modelo teórico que permita responder esta pregunta. Tradicionalmente los 'recursos educativos' -artefactos implicados en las actividades de enseñanza-aprendizaje- se han reducido a ciertos instrumentos como un manual o libro de texto, una libreta o una pizarra.Sin embargo, la psicología cultural advierte que nuestra geografia fisica (personas, objetos y simbolos de nuestro derredor) tiene también un valor psicológico y educativo. En base al modelo ecológico de Bronfenbrenner propone­ mos la existencia de cuatro tipos de recursos: los 'micro-recursos', los 'meso-recursos', los 'exo-recursos' y los 'macro-recursos'. Después de definir estos conceptos los ilustramos con ejemplos derivados de distintas experiencias y programas de investigación e intervención como el "funds of knowledge" ('fondos de conocimiento') de Arizona

Síntesi, caracterització i avaluació com a catalitzadors de nous complexos quirals de platí

The oxidative addition proved to be a useful method to prepare platinum (II) hydridotiolate by reaction of tetrakis(triphenylphosphine)platinum(0) with aminothiolate and phosphinothiolate ligands like cysteamine, cysteine ethyl and methyl Esther, 2-(diphenylphosphino)ethanetiol and 2-(diphenylphosphino)propanetiol. The complexes are square-planar and the aminothiolate or phosphinothiolate ligands are chelated to platinum (II). The hydrido ligand is trans to the sulfur and the other coordination position is occuped by a triphenylphosphine ligand. The complexes are mononuclear and they show low symmetry. The only symmetry element, the plan is broke if the ligand is branched, obtaining asymmetric complexes C1. If the ligand has electronic or esteric impediments the reaction doesn't run and the starting products are recovered. This was observed with N,N-dimethylcysteamine and penicylamine methyl esther ligands. In the special case of orthoaminotiophenol the hydridotiolate was obtained but the ligand was not chelated. The aminothiolate complexes don't show solution equilibrium. Otherwise, the complexe with 2-(diphenylphosphino)ethanetiol show an isomerisation equilibrium which forms cis isomer as a minor component. The complexe with 2-(diphenylphosphino)-propanetiol shows a conformational equilibrium between chair and twist forms. The complexes have been tested as catalyst precursors in hydroformylation and hydrosilylation reactions. The hydroformylation reaction runs only in presence of SnCl2 as cocatalyst. Catalytic activity depends on the presence of triphenylphosphine and, with less magnitude, CO and H2 pressure. We also studied the enantioselectivity using a chiral complexe. In the hydrosililation reaction, catalysts run with good results (<90%) using triethylsilane as silicon hydride. Dehydrogenative addition product has been also found in this reaction.