7 resultados para Rheological behaviors

em Cochin University of Science


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ABSTRACT: The rheological and extrudate behaviour of natural rubber/latex reclaim blends were evaluated using a capillary viscometer . The study shows that the viscosity of natural rubber decreases marginally on the addition of latex reclaim while the variation of viscosity with shear rate is not affected. The temperature sensitivity of the blends is not affected significantly with the addition of latex reclaim . The extrudates of natural rubber/latex reclaim blends are smooth up to the addition of about 50 wt. percent latex reclaim in filled natural rubber compounds.

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The rheological characteristics of short Nylon-6 fiber-reinforced Styrene Butadiene rubber (SBR) in the presence of epoxy resin-based bonding agent were studied with respect to the effect of shear rate, fiber concentration , and temperature on shear viscosity and die swell using a capillary rheonzeter. All the composites containing bonding agent showed a pseudoplastic nature, which decreased with increasing temperature. Shear viscosity was increased in the presence of fibers. The temperature sensitivity of the SBR matrices was reduced on introduction of fibers. The temperature sensitivity of the melts was found to be lower at higher shear rates. Die swell was reduced in the presence of fibers. Relative viscosity of the composites increased with shear rate. In the presence of epoxy resin bonding agent the temperature sensitivity of the mixes increased. Die swell was larger in the presence of bonding agent.

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The rheological behavior of a short-polyester-fiber-filled polyurethane elastomer composite containing different bonding agents has been studied in the temperature range 120-160°C and in the shear rate range 63-608 s-'. The composite with and without bonding agents showed a pseudoplastic behavior which decreased with the increase of temperature. Composites containing bonding agents based on polypropyleneglycol and 4,4'-diphenylmethanediisocyanate showed the lowest viscosity values at a particular shear rate, whereas composites containing a glycerol- (GL) based bonding agent showed the highest viscosity. The viscosity of the composite decreased sharply after a particular temperature (140°C) and the fall was less drastic in the composite containing a GL-based bonding agent.

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School of Industrial Fisheries, Cochin University of Science and Technology

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The gel strength, compressibility and folding characteristic of suwari (set) and kamaboko (set and cooked) gels prepared from rohu (Labeo rohita), catla (Catla catla) and mrigal (Cirrhinus mrigala) surimi were examined to understand the occurrence of suwari and modori phenomena in surimi from major freshwater carps. Suwari setting of gels did not take place at lower temperatures. Suwari gels showed good gel strength at 50 °C for rohu and at 60 °C for catla and mrigal after 30 min setting time. Incubation for 60 min decreased the gel strength at 60 °C for rohu and catla. Setting at 25 °C followed by cooking at 90 °C increased the gel strength. Increased setting temperature, however, decreased the gel strength of cooked gels. Gel strength and compressibility data were supported by folding characteristics.

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The gel strength, compressibility and folding characteristic of suwari (set) and kamaboko (set and cooked) gels prepared from rohu (Labeo rohita), catla (Catla catla) and mrigal (Cirrhinus mrigala) surimi were examined to understand the occurrence of suwari and modori phenomena in surimi from major freshwater carps. Suwari setting of gels did not take place at lower temperatures. Suwari gels showed good gel strength at 50 C for rohu and at 60 C for catla and mrigal after 30 min setting time

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Rubber–nickel nanocomposites were synthesized by incorporating freshly prepared nanometric nickel particles in two different matrices namely natural rubber and neoprene rubber according to specific recipes for various loadings of nano nickel and the cure characteristics of these composites were evaluated. The maximum torque values register an increase with the increase in loading of nickel in both composites and this is attributed to the non-interacting nature of nickel nanoparticles with rubber matrices. The cure time of natural rubber composites decreases with increase in the content of nickel, and in neoprene rubber cure, time increases with increase in filler content. In natural rubber, the curing reaction seems to be activated by the presence of nickel particles. The magnetization studies of the composites reveal that the magnetic properties of nickel are retained in the composite samples. The elastic modulus of natural rubber and neoprene rubber are largely improved by the incorporation of nickel particles