Synthesis of percarboxylic acids in microreactor

Percarboxylic acids are commonly used as disinfection and bleaching agents in textile, paper, and fine chemical industries. All of these applications are based on the oxidative potential of these compounds. In spite of high interest in these chemicals, they are unstable and explosive chemicals, which increase the risk of synthesis processes and transportation. Therefore, the safety criteria in the production process should be considered. Microreactors represent a technology that efficiently utilizes safety advantages resulting from small scale. Therefore, microreactor technology was used in the synthesis of peracetic acid and performic acid. These percarboxylic acids were produced at different temperatures, residence times and catalyst i.e. sulfuric acid concentrations. Both synthesis reactions seemed to be rather fast because with performic acid equilibrium was reached in 4 min at 313 K and with peracetic acid in 10 min at 343 K. In addition, the experimental results were used to study the kinetics of the formation of performic acid and peracetic acid. The advantages of the microreactors in this study were the efficient temperature control even in very exothermic reaction and good mixing due to the short diffusion distances. Therefore, reaction rates were determined with high accuracy. Three different models were considered in order to estimate the kinetic parameters such as reaction rate constants and activation energies. From these three models, the laminar flow model with radial velocity distribution gave most precise parameters. However, sulfuric acid creates many drawbacks in this synthesis process. Therefore, a ´´greener´´ way to use heterogeneous catalyst in the synthesis of performic acid in microreactor was studied. The cation exchange resin, Dowex 50 Wx8, presented very high activity and a long life time in this reaction. In the presence of this catalyst, the equilibrium was reached in 120 second at 313 K which indicates a rather fast reaction. In addition, the safety advantages of microreactors were investigated in this study. Four different conventional methods were used. Production of peracetic acid was used as a test case, and the safety of one conventional batch process was compared with an on-site continuous microprocess. It was found that the conventional methods for the analysis of process safety might not be reliable and adequate for radically novel technology, such as microreactors. This is understandable because the conventional methods are partly based on experience, which is very limited in connection with totally novel technology. Therefore, one checklist-based method was developed to study the safety of intensified and novel processes at the early stage of process development. The checklist was formulated using the concept of layers of protection for a chemical process. The traditional and three intensified processes of hydrogen peroxide synthesis were selected as test cases. With these real cases, it was shown that several positive and negative effects on safety can be detected in process intensification. The general claim that safety is always improved by process intensification was questioned.

Rakennustarkastuksen mobiilityökalun suunnittelu ja toteuttaminen

Rakennusteollisuuden prosessit ovat vielä usein paperipohjaisia, mikä aiheuttaa työmaiden luonteesta johtuen tiedon hajaantumista, hidastaa tiedon siirtymistä ja vaikeuttaa tiedon käsittelyä. Työmaiden väliaikaisilla konttoreilla tiedon määrä voi nousta hallitsemattoman suureksi, mikä haittaa ja hidastaa työnjohdon päätöksentekoa. Käyttämällä sähköisiä työkaluja tiedon keräämistä, keskittämistä ja siirtoa voidaan tehostaa. Projektin tavoitteeksi otettiin teollisuuden laadunvalvonnan tarkastusprosessin tehostaminen ajallisesti käyttämällä tarkastustyöhön sähköistä tarkastuspöytäkirjaa. Tätä varten suunniteltiin sähköinen tarkastusjärjestelmä, joka koostuu kolmesta erillisestä osasta: Tarkastajan mukana kulkeva mobiililaite, jolle tallennetaan suoraan tarkastuksen laatutietoa, palvelinkone avustamaan tiedonsiirrossa ja –varastoinnissa sekä työpöytäsovellus työnjohdon tarpeisiin. Järjestelmää testattiin sähköalan asennuksia tekevässä yrityksessä osana yrityksen normaalia tarkastustyötä. Verrattuna paperiseen pöytäkirjaan sähköinen tarkastusjärjestelmä nopeutti prosessia moninkertaisesti. Nopeustesteissä havaittiin kuitenkin, että valittu tiedon synkronointikirjasto oli järjestelmän tarpeisiin liian hidas. Järjestelmä saavutti sille asetetut tavoitteet tehostamalla prosessia ajallisesti, mutta järjestelmässä on vielä osa-alueita, jotka tarvitsevat jatkokehittämistä.

IFRS-standardien noudattaminen liikearvon raportoinnissa suomalaisissa listayhtiöissä

Tutkimuksen tavoitteena oli tutkia liikearvoon liittyvien IFRS 3- ja IAS 36 –standardien säännösten noudattamista suomalaisten korkean liikearvon määrän omaavien listayhtiöiden tilinpäätöksissä. Teoria muodostettiin tarkastelemalla aihepiirin tieteellisiä julkaisuja, sekä yritysten kirjanpitoa ohjailevia liikearvoon liittyviä säännöksiä. Tutkimusmenetelmä oli kvalitatiivinen, ja empiirisenä aineistona käytettiin viiden yrityksen tilinpäätöksiä vuodelta 2011. Yritykset valittiin tarkastelemalla liikearvon suhteellista osuutta omasta pääomasta. Analysointimenetelmänä käytettiin sisällönanalyysia, ja tutkimuksen runko muodostettiin tilintarkastukseen tarkoitetun tarkastuslistan avulla. Tutkimuksessa tuotettiin tarkkaa ja kuvailevaa tietoa säännösten noudattamisesta kohdeyrityksissä. IFRS 3- ja IAS 36 –standardeissa on määritelty tarkat esitysvaatimukset tilinpäätöksissä esitettävälle liikearvoon liittyvälle tiedolle. Esitettäviä tietoja ovat esimerkiksi kuvaus yritysostojen yhteydessä syntyneestä liikearvosta, sekä selvitys liikearvon arvonalentumistestauksessa käytetyistä avainoletuksista. Kohdeyritysten havaittiin noudattavan tutkimuksessa tarkasteltuja esitysvaatimuksia noin 94 % tarkkuudella. Virheet eivät keskittyneet tiettyihin esitysvaatimuksiin, vaan eri yritykset tekivät erilaisia virheitä liikearvon raportoinnissa.

A global transport packaging guideline for selected business areas

In this Master’s Thesis a global transport packaging guideline for selected business areas was compiled for the Fiskars the company, which provides branded consumer goods for home, garden and outdoor use. The business areas included were Home and Garden business areas. The aim of the guideline was to be a comprehensive guide for the suppliers, product development, operations and external vendors of the company. The guideline consists of written instructions, tables and illustrations that provide useful information for players working with transport packages from sourcing through to shipments. As the role of corporate responsibility and sustainability has grown, a part of responsible manufacturing strategy includes using materials that are re-usable, recyclable or recoverable as energy or through composting. Hence packaging waste management implementations of different regions were also inspected. The resulting guide covers a range of topics concerning packaging and its transport. The topics include legal requirements, restricted materials and substances, preferred materials, markings, labeling of boxes, logistics and distribution center requirements, physical testing and an inspection checklist.

A repository is NOT a digital archive

Presentation at Open Repositories 2014, Helsinki, Finland, June 9-13, 2014

Communicating trustworthiness in online stores

Even though e-commerce systems are expected to have many advantages compared to the traditional ways of doing business, it is not always the reality. Lack of trust is still said to be one of the most important barriers to online shopping. In traditional stores, trust has usually been established in a direct contact between the customer and the company or its personnel. In online stores, there is no direct interaction. The purpose of this thesis is to identify the key antecedents to online trust and to distinguish between effective and ineffective practices. A model on how consumers establish initial trust towards an unknown online vendor was proposed based on previous theories. The model was tested empirically by targeting an online survey at higher degree students in Finland and in Germany. The data confirmed the proposed view that trusting intentions are affected by individual characteristics, characteristics of the company as well as characteristics of the website. Additionally national differences were found between Finnish and German respondents. The data suggested that online vendors can convey a message of trustworthiness by improving information quality and overall usefulness of the website. Perceived risk of online shopping was found to depend especially on general trust in the Internet, service quality and ease of use. A trustworthy online store should include several payment methods as well as means to access and modify given data. The vendors should also make sure that inquiries are addressed quickly, transactions are confirmed automatically and that customers have a possibility to track their order. A model that includes three different sources of trust should contribute to the theoretical understanding of trust formation in online stores. The resulting list of trust antecedents can also be used as a checklist when e-commerce practitioners wish to optimize the trust building.

Discerning Cultural Depictions and Mistakes in Kafe Piter, a Russian Language Textbook for Finnish Students

This thesis presents the results of an analysis of the content in the series of Russian textbooks Kafe Piter, which is widely used in Finnish educational institutions for adult learners at the time that the research is conducted. The purpose of this study is to determine and describe how a textbook may purvey an image of a foreign country (in this case, Russia). Mixed-methods research with a focus on the qualitative content analysis of Kafe Piter is performed. The guidelines for textbook evaluation of cultural content proposed by Byram (1993) are used in this study as the basis for creating a qualitative analysis checklist, which is adopted according to the needs of the current research. The selection of the categories in the checklist is based on major themes where direct statements about Russia, Russian people and culture appear in the textbook. The cultural content and the way in which it is presented in Kafe Piter are also compared to the intercultural competence objectives of the Common European Framework of Reference for Languages. Because the textbook was not written by a native Russian speaker, it was also important to investigate the types of mistakes found in the books. A simple quantitative analysis in the form of descriptive statistics was done, which consisted of counting the mistakes and inaccuracies in Kafe Piter. The mistakes were categorized into several different groups: factual or cultural, lexicosemantic, grammatical, spelling and punctuation mistakes. Based on the results, the cultural content of Kafe Piter provides a rich variety of cultural information that allows for a good understanding of the Russian language and Russian culture. A sufficient number of cross-cultural elements also appear in the textbook, including cultural images and information describing and comparing Russian and Finnish ways of life. Based on the cultural topics covered in Kafe Piter, we conclude that the textbook is in line with the intercultural competence objectives set out in the Common European Framework of Reference for Languages. The results of the study also make it clear that a thorough proofreading of Kafe Piter is needed in order to correct mistakes - more than 130 cultural and linguistic mistakes and inaccuracies appear in the textbook.