Desulfovibrio gigas ferredoxin II: redox structural modulation of the [3Fe–4S] cluster

J Biol Inorg Chem (2006) 11: 307–315 DOI 10.1007/s00775-005-0077-2

Lime-metakaolin mortars for historical buildings repair: study of the hardening reaction

International Conference Durable Structures: from construction to rehabilitation. Lisbon, LNEC, 31 May-1 June 2012

Ground truth determination for segmentation of tomographic volumes using interpolation

Dissertação para obtenção do Grau de Mestre em Engenharia Biomédica

Valorisation of vegetable oil deodorizer distillate by enzymatic reaction and membrane processing

Dissertação para obtenção do Grau de Doutora em Engenharia Química e Bioquímica

Functional characterization and directed engineering of redox proteins for a rational improvement of Bioelectrochemical systems

In recent years, new methods of clean and environmentally friendly energy production have been the focus of intense research efforts. Microbial fuel cells (MFCs) are devices that utilize naturally occurring microorganisms that feed on organic matter, like waste water, while producing electrical energy. The natural habitats of bacteria thriving in microbial fuel cells are usually marine and freshwater sediments. These microorganisms are called dissimilatory metal reducing bacteria (DMRB), but in addition to metals like iron and manganese, they can use organic compounds like DMSO or TMAO, radionuclides and electrodes as terminal electron acceptors in their metabolic pathways.(...)

The thermal effects on the methanol-to-olefins reaction: A modelling and experimental approach

With the projection of an increasing world population, hand-in-hand with a journey towards a bigger number of developed countries, further demand on basic chemical building blocks, as ethylene and propylene, has to be properly addressed in the next decades. The methanol-to-olefins (MTO) is an interesting reaction to produce those alkenes using coal, gas or alternative sources, like biomass, through syngas as a source for the production of methanol. This technology has been widely applied since 1985 and most of the processes are making use of zeolites as catalysts, particularly ZSM-5. Although its selectivity is not especially biased over light olefins, it resists to a quick deactivation by coke deposition, making it quite attractive when it comes to industrial environments; nevertheless, this is a highly exothermic reaction, which is hard to control and to anticipate problems, such as temperature runaways or hot-spots, inside the catalytic bed. The main focus of this project is to study those temperature effects, by addressing both experimental, where the catalytic performance and the temperature profiles are studied, and modelling fronts, which consists in a five step strategy to predict the weight fractions and activity. The mind-set of catalytic testing is present in all the developed assays. It was verified that the selectivity towards light olefins increases with temperature, although this also leads to a much faster catalyst deactivation. To oppose this effect, experiments were carried using a diluted bed, having been able to increase the catalyst lifetime between 32% and 47%. Additionally, experiments with three thermocouples placed inside the catalytic bed were performed, analysing the deactivation wave and the peaks of temperature throughout the bed. Regeneration was done between consecutive runs and it was concluded that this action can be a powerful means to increase the catalyst lifetime, maintaining a constant selectivity towards light olefins, by losing acid strength in a steam stabilised zeolitic structure. On the other hand, developments on the other approach lead to the construction of a raw basic model, able to predict weight fractions, that should be tuned to be a tool for deactivation and temperature profiles prediction.

Alinhamento e continuação de volumes de imagem de tensor de difusão da perna

A imagem por tensor difusão (DTI) é uma extensão da imagem por ressonância magnética que permite a caraterização microestrutural dos tecidos, sendo um destes, os músculos esqueléticos. No entanto, dadas as grandes dimensões dos mesmos, a aquisição de volumes DTI deste tipo de tecidos é comumente realizada em mais que uma sessão. A não linearidade dos gradientes de codificação espacial e a presença de magnetizações parasitas levam a que ocorram distorções que impossibilitam, quando unidos, a continuação de volumes na sua transição. No mercado já existem sotwares que permitem estas correções, no entanto, o seu objetivo tem como fim estudos populacionais aplicados na neurologia, não estando preparados para o alinhamento e união de volumes contíguos. Ao recorrer a algoritmos aplicados nestes softwares, com a devida preparação, é possível garantir a continuidade de volumes. Um desses algoritmos, demons, foi aplicado em pontos de sobreposição de imagens de volumes contíguos. A transformada resultante deste algoritmo foi aplicado ao volume considerado a transformar e unido ao volume de referência. Mostra-se ser possível a aplicação destes algoritmos para a continuação de volumes, sendo observada a preservação da coerência anatómica das fibras quando comparadas aos grupos de controlo. Numa versão futura, recomenda-se a utilização de algoritmos mais robustos, que tomam partido da informação direcional que a imagem por tensor de difusão fornece.