Custo histórico versus justo valor

Oriêntador: Mestre Carlos Pedro

Cu2ZnSnS4 absorber layers obtained through sulphurization of metallic precursors: Graphite box versus sulphur flux

In this work we employed a hybrid method, combining RF-magnetron sputtering with evaporation, for the deposition of tailor made metallic precursors, with varying number of Zn/Sn/Cu (ZTC) periods and compared two approaches to sulphurization. Two series of samples with 1×, 2× and 4× ZTC periods have been prepared. One series of precursors was sulphurized in a tubular furnace directly exposed to a sulphur vapour and N2+5% H2 flux at a pressure of 5.0×10+4 Pa. A second series of identical precursors was sulphurized in the same furnace but inside a graphite box where sulphur pellets have been evaporated again in the presence of N2+5% H2 and at the same pressure as for the sulphur flux experiments. The morphological and chemical analyses revealed a small grain structure but good average composition for all three films sulphurized in the graphite box. As for the three films sulphurized in sulphur flux grain growth was seen with the increase of the number of ZTC periods whilst, in terms of composition, they were slightly Zn poor. The films' crystal structure showed that Cu2ZnSnS4 is the dominant phase. However, in the case of the sulphur flux films SnS2 was also detected. Photoluminescence spectroscopy studies showed an asymmetric broad band emission whichoccurs in the range of 1–1.5 eV. Clearly the radiative recombination efficiency is higher in the series of samples sulphurized in sulphur flux. We have found that sulphurization in sulphur flux leads to better film morphology than when the process is carried out in a graphite box in similar thermodynamic conditions. Solar cells have been prepared and characterized showing a correlation between improved film morphology and cell performance. The best cells achieved an efficiency of 2.4%.

Organic versus conventional tomatoes: Influence on physicochemical parameters, bioactive compounds and sensorial attributes

The effect of organic and conventional agricultural systems on the physicochemical parameters, bioactive compounds content, and sensorial attributes of tomatoes (‘‘Redondo’’ cultivar) was studied. The influence on phytochemicals distribution among peel, pulp and seeds was also accessed. Organic tomatoes were richer in lycopene (+20%), vitamin C (+30%), total phenolics (+24%) and flavonoids (+21%) and had higher (+6%) in vitro antioxidant activity. In the conventional fruits, lycopene was mainly concentrated in the pulp, whereas in the organic ones, the peel and seeds contained high levels of bioactive compounds. Only the phenolic compounds had a similar distribution among the different fractions of both types of tomatoes. Furthermore, a sensorial analysis indicated that organic farming improved the gustative properties of this tomato cultivar.

Riesz potential versus fractional Laplacian

This paper starts by introducing the Grünwald–Letnikov derivative, the Riesz potential and the problem of generalizing the Laplacian. Based on these ideas, the generalizations of the Laplacian for 1D and 2D cases are studied. It is presented as a fractional version of the Cauchy–Riemann conditions and, finally, it is discussed with the n-dimensional Laplacian.

Determinant factors of turnover versus permanence of portuguese repatriates: an exploratory study

The study seeks to identify the determinant factors of the repatriate’s decision to remain or leave the company after repatriation, in a convenience sample of 40 Portuguese returnees working in companies based in Portugal. The main results were as follows: (1) there are seven factor categories: (a) salaries and benefits; (b) possibility of promotion, development, professional development; (c) organizational support (during and after the international mission) recognition of work; (d) economic and social atmosphere of the company, (e) good relationship with leadership; (f) convenience and/or personal / family well-being and; (g) external alternatives; (2) the main factors leading to permanence are (a) possibility of promotion, development and professional development and; (b) the existence of personal and family well-being / convenience; (3) the main factors leading to abandonment are (a) lack of organizational support and recognition of work performed; (b) lack of possibility of promotion, development and professional development and; (c) lack of personal / family well-being / convenience. Globally, the study suggests that the factors leading to permanence are very similar to those that lead to abandonment, although in reverse.

Riesz potential versus fractional Laplacian

This paper starts by introducing the Grünwald–Letnikov derivative, the Riesz potential and the problem of generalizing the Laplacian. Based on these ideas, the generalizations of the Laplacian for 1D and 2D cases are studied. It is presented as a fractional version of the Cauchy–Riemann conditions and, finally, it is discussed with the n-dimensional Laplacian.

Os jovens versus protocolo social

Os jovens são as gerações adultas do futuro e por isso as que estão mais sujeitas a transformações sociais com consequências diretas e indiretas no seu comportamento. Partindo dessa premissa, consideramos constituir matéria importante de estudo, analisar se os jovens hoje em dia utilizam normas de protocolo social. Foi realizada uma investigação junto de alunos do ensino profissional privado com idades compreendidas entre os 15 e os 24 anos, na cidade do Porto e na cidade de Barcelos, pretendendo-se averiguar se os jovens atualmente sabem ser e sabem estar consoante as situações, usando regras de boa educação e boas maneiras. Por outro lado, tivemos a oportunidade de verificar se devido a variáveis sociais e económicas, assim como devido a variáveis geográficas existiram semelhanças ou diferenças nos resultados da investigação. Para efetuar este estudo optou-se pela pesquisa exploratória usando a estratégia do estudo de caso porque se investigou uma situação do dia-a-dia cujas respostas não estavam bem definidas. É considerado um estudo de caso múltiplo dado que envolve duas realidades (Porto e Barcelos). Foram utilizadas técnicas qualitativas e quantitativas através da aplicação de questionários aos jovens das duas escolas e posteriormente foram realizadas entrevistas para aferir os resultados dos questionários. Após a análise dos resultados, verifica-se que estes jovens utilizam as normas de protocolo social pois adotam comportamentos que o demonstram e respondem adequadamente às perguntas que lhes são feitas. Mais revela o estudo não existir diferenças significativas entre os alunos das duas cidades uma vez que a linha de pensamento entre eles é muito idêntica. A atitude de julgamento em relação aos alunos do ensino profissional desvanece dado que estes fazem uso das regras da boa educação.