The VLT-FLAMES Tarantula Survey: XXIII. Two massive double-lined binaries in 30 Doradus

Aims: We investigate the characteristics of two newly discovered short-period, double-lined, massive binary systems in the Large Magellanic Cloud, VFTS 450 (O9.7 II-Ib + O7::) and VFTS 652 (B1 Ib + O9: III:). 

Methods: We perform model-atmosphere analyses to characterise the photospheric properties of both members of each binary (denoting the "primary" as the spectroscopically more conspicuous component). Radial velocities and optical photometry are used to estimate the binary-system parameters. 

Results: We estimate T_eff = 27 kK, log g = 2.9 (cgs) for the VFTS 450 primary spectrum (34 kK, 3.6: for the secondary spectrum); and T_eff = 22 kK, log g = 2.8 for the VFTS 652 primary spectrum (35 kK, 3.7: for the secondary spectrum). Both primaries show surface nitrogen enrichments (of more than 1 dex for VFTS 652), and probable moderate oxygen depletions relative to reference LMC abundances. We determine orbital periods of 6.89 d and 8.59 d for VFTS 450 and VFTS 652, respectively, and argue that the primaries must be close to filling their Roche lobes. Supposing this to be the case, we estimate component masses in the range ∼20-50 M_⊙. 

Conclusions: The secondary spectra are associated with the more massive components, suggesting that both systems are high-mass analogues of classical Algol systems, undergoing case-A mass transfer. Difficulties in reconciling the spectroscopic analyses with the light-curves and with evolutionary considerations suggest that the secondary spectra are contaminated by (or arise in) accretion disks.

Efficient and Selectable Production of Reactive Species Using a Nanosecond Pulsed Discharge in Gas Bubbles in Liquid

A plasma gas bubble-in-liquid method for high production of selectable reactive species using a nanosecond pulse generator has been developed. The gas of choice is fed through a hollow needle in a point-to-plate bubble discharge, enabling improved selection of reactive species. The increased interface reactions, between the gas-plasma and water through bubbles, give higher productivity. H₂O₂ was the predominant species produced using Ar plasma, while predominantly  and NO₂ were generated using air plasma, in good agreement with the observed emission spectra. This method has nearly 100% selectivity for H₂O₂, with seven times higher production, and 92% selectivity for , with nearly twice the production, compared with a plasma above the water.