Aplicação de carbono vítreo monolítico para produção de eletrodos a partir da resina furfurílica com diferentes variações de pH

Nowadays, we live in a time of rapid research for technological advances, in a way that this pursuit of new technologies is deeply connected to the diversity of new materials that have been developed by mankind. It deals with issues such as materials with enhanced properties which offer better quality, less cost and high performance, while they are accessible both in their production and moment of operation. In this context, it was required to develop electrodes that were easy to prepare as well as which present high electric conductivity and good mechanic proprieties by using carbonaceous material as basis. For this reason, the best parameters of the furfuryl resin cures were established with different pH variations through viscosimetric measurements and differential scanning calorimetry. By scanning electron microscopy (SEM) was possible to identify an increased porosity in the samples with pH 7 and pH 8, as compared to samples with lower pH content. After carbonization of the material, the characterization of monolithic glassy carbon was held by means of FT-IR techniques, Raman spectroscopy, X-ray diffraction and cyclic voltammetry. The spectra showed that the change in pH does not have significant influence on the crystallographic ordering of the material and its structural characteristics. As for the electrochemical character, the CVM electrodes showed excellent response, with good reversibility and wide potential window. Some voltammetric curve deviations were only observed for the sample with pH 4, which may be related to processing parameters adopted

Estudo da viabilidade da implantação de frotas de veículos elétricos e híbridos elétricos no atual cenário econômico, político, energético e ambiental brasileiro

Currently there are two car models that use electricity in their propulsion systems, the electric vehicle and the hybrid electric vehicle. The electric vehicles are classified as vehicles that use electric motors in their propulsion system and batteries as a power source, on the other hand, the hybrid vehicles are classified as vehicles that use both electric motors and internal combustion engines in their propulsion system, using both batteries and líquid fuels as a power source. The main goal of this work is to analyze the characteristics of electric and hybrid electric vehicles and demonstrate the unfeasibility of the electric vehicle in the current economic, political, energetic and environmental brazilian scenario, for this purpose it was realized a study about the current brazilian situation regarding to electricity generation, current conservation status of road network, lack of electrical infrastructure for charging batteries, national lithium reserves, environmental characteristics, tax incentives, economic scenario, oil market and political positioning related to the implantation of electric or hybrid electric fleets in nacional territory. The operational characteristics analysis of electric and hybrid electric vehicles in this current scenario leads to the conclusion that currently a growth of electric vehicles fleets on a national scale is totally impractical in the Brazil, Thus, the introduction of green vehicles probably will occur primarily with hybrid electric models, motivated mainly due the bigger autonomy of this models compared to electric models, lower cost of hybrid electric models compared to electric models, factors related to the lack of recharging infrastructure and also factors related to political positioning

Estudo e desenvolvimento de filmes espessos de CeO2 obtidos por tape casting

Tape Casting proved to be an effective method for the production of thick films of CeO2 pure and doped with La. For this study, the nanoparticles used to form the slurry were synthesizes by the H-M method, at 100°C for 8 minutes, using KOH mineralizer. The slurry was made in aqueous solvent, requiring optimal control of surroundings conditions so that the produced tape has conditions to be studied. However, there's no toxicity or flammability in the film made by such solvent, being pleasing to the environment. The structural, optical and electrical properties of the films obtained by the Tape Casting process were studied by the methods of X-ray diffraction, scanning electron microscopy, specific surface area, Ultraviolet-visible spectroscopy and voltage-current measures, varying the electric field and frequency. From the results obtained by laboratory experiments, based on the literature, it was possible to reveal and understand some CeO2 features pure and doped with La

O ensino de física com lousa digital: atividades lúdicas como ferramenta mediadora na aprendizagem

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)