口腔修复材料-可见光固化复合树脂的制备与性能的研究

本论文分为两部分：1. 综述部分（第一章），介绍了可见光固化复合树脂的组成、分类、性能以及应用；评述了复合树脂的研究进展。2. 实验部分（第二章至第七章），包括以下几个方面的内容：无机填料的制备与硅烷化处理研究；树脂基质固化过程的研究；可见光固化复合树脂的制备及物理机械性能的评价；研究不同浸泡液对复合树脂吸水性、挠曲强度、弯曲弹性模量以及复合树脂单体洗出量的影响，并探讨了这些物理机械性能与复合树脂组成成分的关系。 无机填料能赋予复合树脂良好的物理机械性能。本论文通过烧结法和醇盐水解法分别制备了1 µm和0.75 μm的无机填料，利用醇盐水解法成功制备了纳米级二氧化硅，最终制得强度符合临床要求的复合树脂，为工业化生产提供了依据。 无机填料硅烷化处理效果的好坏对复合树脂的各种性能会产生很大影响，本论文对无机填料进行硅烷化处理，引入了比商品化产品更多的硅烷偶联剂，而且实验中硅烷化处理的8235玻璃粉表面既有化学包覆又有物理包覆的硅烷偶联剂。渗透实验表明3-甲基丙烯酰氧丙基三氯硅烷处理的无机填料表面疏水性比3-甲基丙烯酰氧丙基三甲氧基硅烷强。 膨胀单体可以用来减小甚至消除复合树脂聚合过程的体积收缩，论文第四章尝试用螺双内酯作为复合树脂的单体，提出了一种新型的先阳离子聚合后阴离子聚合的联合引发聚合过程。论文第五、六章用环氧化芳香族超支化聚合物制备了新型可见光固化复合树脂，研究结果表明：①环氧化芳香族超支化聚合物的加入，环氧树脂基复合树脂的挠曲强度和弯曲弹性模量增大；②收缩变小；③吸水量变大；④环氧树脂的转化率降低；⑤玻璃化转变温度降低。环氧化芳香族超支化聚合物能够增强增韧脂肪族环氧树脂，如果对其进行必要的改性，所得复合树脂有可能被应用到牙科修复中。 不同浸泡液对复合树脂的物理机械性能和生物相容性会产生不同的影响，论文第七章系统研究了不同浸泡液对复合树脂各种物理机械性能的影响。结果表明：① 三种浸泡液对复合树脂各种性能的影响随浸泡液种类的不同而不同，其中乙醇/水对复合树脂的影响最严重；②即使在同一浸泡液中，不同组成的复合树脂也有不同的物理机械性能。

Fabrication of low-cost and high-reflectivity bottom mirrors for Si-based micro-cavity devices

A novel and simple way to prepare high-reflectivity bottom mirrors for Si-based micro-cavity devices is reported. The bottom mirror was deposited in the hole, which was etched from the backside of the sample by ethylenediamine-pyrocatechol-water solution with the buried Sio, layer in the silicon-on-insulator substrate as the etching-stop layer. The high-reflectivity of the bottom mirror deposited in the hole and the narrow hill width at half maximum of the cavity formed by this method both indicate the successful preparation of the bottom mirror for Si-based micro-cavity devices.

Preparation and characterization of a novel beta-cyclodextrin modified poly(N-acetylaniline) film

Hydroquinone was chosen as an electroactive probe to study the beta-cyclodextrin (beta-CD) modified poly(N-acetylaniline) (PNAANI) electrode. The beta-CD modified PNAANI electrode was prepared by electrooxidation of the PNAANI electrode in a beta-CD/DMSO solution. The electrochemical properties of the beta-CD inclusion complex of hydroquinone on the PNAANI electrode and hydroquinone on the beta-CD modified PNAANI electrode were studied. In the cyclic voltammogram of hydroquinone at the beta-CD/PNAANI electrode, DeltaE(p) of the peaks is sharpening and the area of the peaks is increasing, which can be due to the inclusion of hydroquinone into the cavity of beta-CD immobilized at the electrode surface. The beta-CD/PNAANI film was characterized by X-ray photoelectron spectroscopy and H-1 NMR. The mechanism for beta-CD incorporation into the polymer film was also proposed.

The Displacement and Strain Field of Three-Dimensional Rheologic Model of Earthquake Preparation

Based on the three-dimensional elastic inclusion model proposed by Dobrovolskii, we developed a rheological inclusion model to study earthquake preparation processes. By using the Corresponding Principle in the theory of rheologic mechanics, we derived the analytic expressions of viscoelastic displacement U(r, t) , V(r, t) and W(r, t), normal strains epsilon(xx) (r, t), epsilon(yy) (r, t) and epsilon(zz) (r, t) and the bulk strain theta (r, t) at an arbitrary point (x, y, z) in three directions of X axis, Y axis and Z axis produced by a three-dimensional inclusion in the semi-infinite rheologic medium defined by the standard linear rheologic model. Subsequent to the spatial-temporal variation of bulk strain being computed on the ground produced by such a spherical rheologic inclusion, interesting results are obtained, suggesting that the bulk strain produced by a hard inclusion change with time according to three stages (alpha, beta, gamma) with different characteristics, similar to that of geodetic deformation observations, but different with the results of a soft inclusion. These theoretical results can be used to explain the characteristics of spatial-temporal evolution, patterns, quadrant-distribution of earthquake precursors, the changeability, spontaneity and complexity of short-term and imminent-term precursors. It offers a theoretical base to build physical models for earthquake precursors and to predict the earthquakes.

Experimental Study on Flow and Sediment Movement in Cavity Circulations

This paper reports a flume experiment of flow and sediment movement in a cavity. The flow velocity, sediment concentration and the mechanism of hydraulic sorting in the circulation flow are discussed. The quantity and patterns of sediment deposition in the circulation area are studied as well.

Preparation And Tribology Studies of Alkyl Carboxylic Acid Monolayer Films on Pei-Coated Glass Substrate

首次在涂敷PEI的玻璃表面上制备了癸酸及全氟癸酸的单分子层膜。研究了成膜机理及摩擦特性。结果表明。脱水剂DCCD促进了癸酸或全氟癸酸与PEI酞胺化的反应。导致两种羧酸在PEI表面产生了靠化学键（酞胺键）连接的稳定的单分子层膜,摩擦、磨损实验表明。单分子层有机膜的摩擦特性受膜的组成、表面能及有序性和堆积密度的重要影响。表面能越低,有序性和堆积密度越高。摩擦系数越低。与碳氢化合物相比。碳氟化合物形成的有序膜具有更高的强度和抗磨性能。

Preparation and Tribological Studies of Stearic Acid Self-Assembled Monolayers on Polymer-Coated Silicon Surface

We present a good alternative method to improve the tribological properties of polymer films by chemisorbing a long-chain monolayer on the functional polymer surface. Thus, a novel self-assembled monolayer is successfully prepared on a silicon substrate coated with amino-group-containing polyethyleneimine (PEI) by the chemical adsorption of stearic acid (STA) molecules. The formation and structure of the STA-PEI film are characterized by means of contact-angle measurement and ellipsometric thickness measurement, and of Fourier transformation infrared spectrometric and atomic force microscopic analyses. The micro- and macro-tribological properties of the STA-PEI film are investigated on an atomic force microscope (AFM) and a unidirectional tribometer, respectively. It has been found that the STA monolayer about 2.1-nm thick is produced on the PEI coating by the chemical reaction between the amino groups in the PEI and the carboxyl group in the STA molecules to form a covalent amide bond in the presence of N,N'-dicyclohexylcarbodiimide (DCCD) as a dehydrating regent. By introducing the STA monolayer, the hydrophilic PEI polymer surface becomes hydrophobic with a water contact angle to be about 105degrees. Study of the time dependence of the film formation shows that the adsorption of PEI is fast, whereas at least 24 h is needed to generate the saturated STA monolayer. Whereas the PEI coating has relatively high adhesion, friction, and poor anti-wear ability, the STA-PEI film possesses good adhesive resistance and high load-carrying capacity and anti-wear ability, which could be attributed to the chemical structure of the STA-PEI thin film. It is assumed that the hydrogen bonds between the molecules of the STA-PEI film act to stabilize the film and can be restored after breaking during sliding. Thus, the self-assembled STA-PEI thin film might find promising application in the lubrication of micro-electromechanical systems (MEMS).

Shock wave diffraction by a square cavity filled with dusty gas

A simple two-dimensional square cavity model is used to study shock attenuating effects of dust suspension in air. The GRP scheme for compressible flows was extended to simulate the fluid dynamics of dilute dust suspensions, employing the conventional two-phase approximation. A planar shock of constant intensity propagated in pure air over Aat ground and diffracted into a square cavity filled with a dusty quiescent suspension. Shock intensities were M-s = 1.30 and M-s = 2.032, dust loading ratios were alpha = 1 and alpha = 5, and particle diameters were d = 1, 10 and 50 mum. It was found that the diffraction patterns in the cavity were decisively attenuated by the dust suspension, particularly for the higher loading ratio. The particle size has a pronounced effect on the flow and wave pattern developed inside the cavity. Wall pressure historics were recorded for each of the three cavity walls, showing a clear attenuating effect of the dust suspension.

Frequency characteristics and dynamical behaviors of self-modulation in vertical-cavity surface-emitting lasers

The frequency characteristics of a VCSEL with a quarter-wave plate (QWP) and an external reflector are investigated with the translation matrix of the vectorial field. Two series of eigenmode with a shift of half the free spectrum range are linearly polarized, respectively, along the neutral axes of QWP. We also numerically explore the polarization self-modulation phenomenon by using a vectorial laser equation and considering the inhomogeneous broadening of the gain medium. If the external cavity is so short that the shift is bigger than the homogeneous broadening, two stable longitudinal modes oscillate, respectively, on the neutral axes of QWP because they consume different carriers. With a long external cavity, the competition of the modes for the common carriers causes the intensity fluctuation of the modes with a period of one round-trip time of the external cavity.

Shock wave diffraction and reflection around a dusty square cavity

The diffraction and reflection of planar shock wave around a dusty square cavity is investigated numerically, which is embedded in the net bottom surface of a two-dimensional channel, and the induced gas-particle two-phase now. The wave patterns at different times are obtained for three different values of the particle diameter. The computational results show that the existence of particles affects appreciably the shock wave diffraction and cavity flow.

A New Modified Expanding Cavity Model for Characterizing the Spherical Indentation Behaviour of Bulk Metallic Glass with Pile-up

Spherical nanoindentation tests were performed on Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass and pile-ups were observed around the indenter. A new modified expanding cavity model was developed to characterize the indentation deformation behavior of strain-hardening and pressure-dependent materials. By using this model, the representative stress-strain response of this bulk metallic glass to hardness and indentation in the elastic-plastic regime were obtained taking into consideration the effect of pile-up.

The Hydrothermal Wave Of Large-Prandtl-Number Fluid In A Shallow Cavity

The hydrothermal wave was investigated numerically for large-Prandtl-number fluid (Pr = 105.6) in a shallow cavity with different heated sidewalls. The traveling wave appears and propagates in the direction opposite to the surface flow (upstream) in the case of zero gravity when the applied temperature difference grows and over the critical value. The phase relationships of the disturbed velocity, temperature and pressure demonstrate that the traveling wave is driven by the disturbed temperature, which is named hydrothermal wave. The hydrothermal wave is so weak that the oscillatory flow field and temperature distribution can hardly be observed in the liquid layer. The exciting mechanism of hydrothermal wave is analyzed and discussed in the present paper.

Preparation And Optical Properties Of Cdte/Cdo Center Dot Nh(2)O Core/Shell Nano-Composites In Aqueous Solution

The deposition of CdO center dot nH(2)O On CdTe nanoparticles was studied in an aqueous phase. The CdTe nanocrystals (NCs) were prepared in aqueous solution through the reaction between Cd2+ and NaHTe in the presence of thioglycolic acid as a stabilizer. The molar ratio of the Cd2+ to Te2- in the precursory solution played an important role in the photoluminescence of the ultimate CdTe NCs. The strongest photoluminescence was obtained under 4.0 of [Cd2+]/[Te2-] at pH similar to 8.2. With the optimum dosage of Cd(II) hydrous oxide deposited on the CdTe NCs, the photoluminescence was enhanced greatly. The photoluminescence of these nanocomposites was kept constant in the pH range of 8.0-10.0, but dramatically decreased with an obvious blue-shifted peak while the pH was below 8.0. In addition, the photochemical oxidation of CdTe NCs with cadmium hydrous oxide deposition was markedly inhibited.

Experimental investigation on the cavity-based scramjet model

The present work focused on improving the engine performance with different fuel equivalence ratios and fuel injections. A scramjet model with strut/cavity integrated configurations was tested under Mach 5.8 flows. The results showed that the strut may sreve as an effective tool in a kerosene-fueled scramjet. The integration of strut/cavities also had great effect on stablizing the combustion in a wide range of fuel equivalence ratio. The one-sdimensional analysis method was used to analyze the main characteristics of the model. The two-stage fuel injection should have better performance in increasing the chemical reaction rate in the first cavity region.

A constitutive model for cavitation and cavity growth in rubber-like materials under arbitrary tri-axial loading

In this paper, we attempted to construct a constitutive model to deal with the phenomenon of cavitation and cavity growth in a rubber-like material subjected to an arbitrary tri-axial loading. To this end, we considered a spherical elementary representative volume in a general Rivlin's incompressible material containing a central spherical cavity. The kinematics proposed by [Hou, H.S., Abeyaratne, R., 1992. Cavitation in elastic and elastic-plastic solids. J. Mech. Phys. Solids 40, 571-722] was adopted in order to construct an approximate but optimal field. In order to establish a suitable constitutive law for this class of materials, we utilized the homogenisation technique that permits us to calculate the average strain energy density of the volume. The cavity growth was considered through a physically realistic failure criterion. Combination of the constitutive law and the failure criterion enables us to describe correctly the global behaviour and the damage evolution of the material under tri-axial loading. It was shown that the present models can efficiently reproduce different stress states, varying from uniaxial to tri-axial tensions, observed in experimentations. Comparison between predicted results and experimental data proves that the proposed model is accurate and physically reasonable. Another advantage is that the proposed model does not need special identification work, the initial Rivlin's law for the corresponding incompressible material is sufficient to form the new law for the compressible material resulted from cavitation procedure. (C) 2007 Elsevier Ltd. All rights reserved.