一种以浒苔为原料制取生物乙醇的方法

本发明公开一种以浒苔为原料制取生物乙醇的方法，包括以下步骤：（1）对浒苔进行漂洗；（2）对浒苔粉碎至粒径为0.5～2mm；（3）将步骤（2）所得的浒苔投入到酸解装置中，料液比为1：20-1：5，加入酸，至酸浓度为0.5%-2.5%(w/w)。反应釜中110℃-150℃水解；（4）将步骤（3）所得的浒苔水解液中加入氢氧化钙中和至中性，室温静置；压滤除去固形物，得富含葡萄糖和木糖的水解液；（5）将步骤（4）所得的水解液，接入5%的休哈塔假丝酵母30℃发酵1~5天；（6）发酵液蒸馏得到生物乙醇。本发明利用浒苔作为乙醇发酵的原料，结合浒苔的特点，不需经过酶解，水解液可直接用于生物乙醇发酵。

一种海带渣糖化产葡萄糖工艺

本发明公开一种海带渣糖化产葡萄糖的工艺。包括以下步骤：（1）将海带渣加适量水后投入到酸预处理装置中，料液比为1:30-1：7，加入硫酸，至酸浓度为为0.5%-2.5%(w/w)，反应釜中110℃-150℃水解；（2）对步骤（1）所得的海带渣转移至200目过滤布上，用清水冲洗除去残留的硫酸至海带渣pH为中性；（3）将步骤（2）所得的中性海带渣中加入柠檬酸钠缓冲液，pH为4.0-5.8，料液比为1:40-1：8，加入纤维素酶，酶用量为4-20mg/g底物，恒温摇床中40-55℃酶解，酶解时间为24-48小时，摇床转速为120 rpm。本发明工艺简单有效，将海带加工废弃物变废为宝。

高灵敏度低暗电流GaAs量子阱红外探测器

报道所研制的高灵敏度、低暗电流的 GaAs量子阱长波长红外探测器的制备和性能。探测器具有50个GaAs量子阱和Al_(0.28)Ga_(0.72)As势垒,器件制成直径为320μm的台面型式单管。探测器的主要性能──响应率和探测率与偏置电流和工作温度关系很大。 通过材料结构的精心设计和器件工艺的改进使探测器的性能进一步提高: 探测峰值波长为9.2μm,工作温度为77K时,峰值电压响应率为9.7×10~5V/W,峰值探测率超过1×10~(11)cm。((Hz)~(1/2))/W,暗电流小于0.1μA。

110-W fiber laser with homemade double-clad fiber

A high-power ytterbium-doped fiber laser (YDFL) with homemade double-clad fiber (DCF) is introduced in this letter. The geometric parameter and laser characteristics of the fiber have been studied. With one-end-pumping scheme, pumped by a high-power laser diode with launching power of 280 W, a maximum continuous wave (CW) output of 110 W is obtained with an optical-to-optical efficiency of 40%.

Syntheses and reactions of heterometallic complexes of nickel and copper with tetrathiotungstates. The molecular structures of [Ph(4)P](2)[S2W(mu-S)(2)Ni(S-2)] and W(mu-S)(4)Cu-2(PPh(3))(4)center dot py

Reaction of [Ph(4)P]2WS4 With NiCl2 in methanol solution in the presence of NaOCH3 leads to the formation of [Ph(4)P](2) [S2W(mu-S)(2)Ni(S-2)] (I) A Similar reaction between (NH4)(2)WS4 and NiCl2 under O-2 atmosphere in the presence of Ph(4)PCl or (n)Bu(4)NCl affords [Ph(4)P](2)([(S-2)W(O)(mu-S)(2)]Ni-2] (IIa) and [(n)Bu(4)N](2)([(S-2)W(O)(mu-S)(2)]Ni-2} (IIb) Under argon the same reaction gives [Ph(4)P](2)[Ni(WS4)(2)] (IIIa) and [(n)Bu(4)N](2)[Ni(WS4)(2)] (IIIb). [Ph(4)P](2)[Ni(WOS3)(2)] (IV) and [Ph(4)P](2)[Ni(WO2S2)(2)] (V) can be prepared from the reaction of [Ph(4)P]2WOS3 and [Ph(4)P]2WO2S2 with NiCl2. Treatment of (NH4)(2)WS4 with CuCl in the presence of PPh(3) in boiling pyridine produces W(mu-S)(4)Cu-2(PPh(3))(3) (VI), which can further react with excess PPh(3) to give W(mu-S)(4)Cu-2(PPh(3))(4) . py (VII). Complex I crystallizes in the space group P2(1)/n with the cell parameters: a = 20.049(4), b = 17.010(4), c = 14.311(7) Angstrom; beta = 110.24(3)degrees and Z = 4; R = 0.058 for 4267 independent reflections. The structural study confirms that complex I contains two terminal sulfide ligands, two bridging sulfide ligands, a side-on disulfide ligand, and a planar central W(mu-S)(2)Ni four membered ring. Complex VII crystallizes in the space group C2/c with the cell parameters: a = 26.436(8), b = 20.542(6), c = 19.095(8) Angstrom; beta = 125.00(3)degrees and Z = 4; R = 0.080 for 3802 independent reflections. The structural study reveals a perfect linear arrangement of the three metal atoms Cu-W-Cu.

Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions

The kinetic studies of the acrylic octadecyl ester and styrene polymerization in microemulsion systems, (1) cetyl pyridine bromide (CPDB)/t-butanol/styrene/water; (2) CPDB/t-butanol/toluene + acrylic octadecyl ester (1:1, w/v)/ water; (3) cetyl pyridine bromide/styrene/formamide, were made by using dynamic laser light scattering techniques (DLS). The mechanisms of nucleation of latex particles were discussed. The most possible nucleation location of the styrene and acrylic octadecyl ester microlatex particles in aqueous microemulsion system is in aqueous phase via homogeneous nucleation. Meanwhile, parts of microlatex particles are possibly produced via swollen micelles (microemulsions) and monomer droplets nucleation. On the other hand, the most possible nucleation location of the styrene microlatex particles in nonaqueous microemulsion system is inside monomer droplets. The relationship between the amount of monomer and the size of microlatex was also investigated. It has been found that the size of microlatex particles could be controlled by changing the amount of monomer. (C) 2002 Elsevier Science B.V. All rights reserved.

三组元W/O乳化液的表面张力和雾化特性

研究了W／O型乳化液的表面张力，压力雾化喷嘴的乳化液雾化特性与乳化液的组分、乳化剂的黏度以及喷油压力的关系．实验结果表明：乳化液的表面张力接近柴油，但喷雾滴径均大于柴油，而且喷嘴的启喷压力、乳化液组分和乳化剂黏度对乳化液平均滴径均有显著影响．随着启喷压力升高，喷雾滴径明显减小；若启喷压力相同，随着乳化液中水相含量增加(不高于50％)，乳化液喷雾滴径随之增加；采用高黏度、低HLB值乳化剂配制的乳化液的喷雾滴径相对较大；内相界面特性和界面上的乳化剂会对滴径分布有重要影响．

Nonequilibrium microstructures and their evolution in a Fe-Cr-W-Ni-C laser clad coating

The laser-solidified microstructural and compositional characterization and phase evolution during tempering at 963 K were investigated using an analytical transmission electron microscope with energy dispersive X-ray analysis. The cladded alloy, a powder mixture of Fe, Cr, W, Ni, and C with a weight ratio of 10:5:1:1:1, was processed with a 3 kW continuous wave CO2 laser. The processing parameters were 16 mm/s beam scanning speed, 3 mm beam diameter. 2 kW laser power, and 0.3 g/s feed rate. The coating was metallurgically bonded to the substrate, with a maximum thickness of 730 mu m, a microhardness of about 860 Hv and a volumetric dilution ratio of about 6%. Microanalyses revealed that the cladded coating possessed the hypoeutectic microstructure comprising the primary dendritic gamma-austenite and interdendritic eutectic consisted of gamma-austenite and M7C3 carbide. The gamma-austenite was a non-equilibrium phase with extended solid solution of alloying elements and a great deal of defect structures, i.e. a high density of dislocations, twins, and stacking faults existed in gamma phase. During high temperature aging, in situ carbide transformation occurred of M7C3 to M23C6 and M6C. The precipitation of M23C6, MC and M2C carbides from austenite was also observed.

铁基抗高温磨损激光熔覆涂层强韧设计和研究II:Fe-Cr-C-W-Ni激光熔覆层的微观组织及性能

本文以对热工模具进行失效分析的基础上，利用激光熔覆技术，在５ＣｒＭｎＭｏ基础上设计并制备强韧兼备的抗高温磨损涂层。

The W-11-4A platform comprehensive strength monitoring system

A comprehensive strength monitoring system used on a fixed jacket platform is presented in this paper. The long-term monitoring of W-11-4A platform achieved. Structural responses (strain and acceleration) at selected locations, as well as associated environmental parameters, have been obtained. The emphasis of the paper is placed on the system design, and the instrumentation and operation methodology employed in the monitoring of the structural responses. The performance of the system and the characteristic results obtained during its 13-month operation are also summarized.

Quantum Monte Carlo study of the CO interaction with a dimer model surface for Cr(110)

The chemisorption of CO on a Cr( 110) surface is investigated using the quantum Monte Carlo method in the diffusion Monte Carlo (DMC) variant and a model Cr2CO cluster. The present results are consistent with the earlier ab initio HF study with this model that showed the tilted/ near-parallel orientation as energetically favoured over the perpendicular arrangement. The DMC energy difference between the two orientations is larger (1.9 eV) than that computed in the previous study. The distribution and reorganization of electrons during CO adsorption on the model surface are analysed using the topological electron localization function method that yields electron populations, charge transfer and clear insight on the chemical bonding that occurs with CO adsorption and dissociation on the model surface.

碱金属在[110]单轴应力下的理论强度

<正> 我们知道,晶须的强度远远大于大晶体的强度,很可能接近于理想晶体的理论强度.而晶须的轴线则通常平行于晶体的三个主要方向[100],[110]或[111]。因此当计算理想晶体在单轴应力下的理论强度时,也必须考虑不同的应力方向.七十年代,Milstein等人利用Morse势和Born稳定性判据计算了立方晶体分别在[100],[110]和[111]单轴应力下的理论强度.由于有心力近似受到Cauchy关系的限制,我们在文献

铁基抗高温磨损激光熔覆涂层强韧设计和研究 Ⅱ:Fe-Cr-C-W-Ni激光熔覆层的微观组织及性能

利用ＯＭ、ＳＥＭ、ＴＥＭ研究了Ｆｅ－Ｃｒ－Ｃ－Ｗ－Ｎｉ激光熔覆涂层熔覆态及其高温时效态的微观组织结构。结果表明激光熔覆层组织细小，具有强韧两相组成（奥氏体和Ｍ_７Ｃ_３碳化物）的微观结构特征，高温时效处理组织中有Ｍ_（２３）Ｃ_６、Ｍ_６Ｃ、Ｍ_２Ｃ等新碳化物形成。显微硬度和冲击磨损实验证实了激光熔覆态和峰值时效态熔覆层均具有良好的力学性能。