The formation mechanism of low leaching glassy slag during plasma arc vitrification treatment of fly ash

In this paper, the glass formation theory is applied to study the formation mechanism of the low leaching glassy slag during the process of plasma waste treatment. The research shows that SiO2 acts as network former to form a 3-dimensional Si-O tetrahedral network in which heavy metals are bonded or encapsulated, so the Si-O tetrahedron protect heavy metals against leaching from the vitrified slag or acid corrosion. For given chemical compositions of waste, the formation ability of the vitrified slag can be represented by the ratio of the whole oxygen ions to the whole network former ions in glass (O/Si) which is appropriate in the range of 2~3. A plasma arc reactor is used to conduct the vitrification experiments of two kinds of fly ashes with additives in which effects of various parameters including arc power, cooling speed, treatment temperature are studied. The chemical compositions of fly ashes are analyzed by X-ray fluorescence (XRF) spectrometry. The experimental results show that both cooling speed and O/Si have important influence on the formation of the vitrified slag, which is qualitatively in accordance with the predictions of the glass formation theory.

THE FORMATION MECHANISM OF THE VITRIFIED SLAG IN A PLASMA ARC REACTOR FOR HAZARDOUS WASTE TREATMENT

Various hazardous wastes with additives have been vitrified to investigate the formation mechanism of the glassy slag by a 30 kW DC plasma-arc reactor developed by the Institute of Mechanics, Chinese Academy of Sciences. The average temperature in the reaction area is controlled at 1500°C. The chemical compositions of three sorts of fly ashes are analyzed by XRF (X-Ray Fluorescence). Fly ashes with vitrifying additives can be vitrified to form glassy slag, which show that the ratio of the whole oxygen ions to the whole network former ions in glass (R) is appropriate in the range of 2~3 to form durable vitrified slag. In this experiment, the arc power is controlled below 5 kW to inhibit waste evaporation. To enhance the effects of heat transfer to wastes, ferrous powder has been added into the graphite crucible, which aggregates as ingot below the molten silicate after vitrification. The slag fails to form glass if the quenching rate is less than 1 K/min. Therefore, the slag will break into small chips due to the sharp quenching rate, which is more than 100 K/sec.

Modeling of a coal-fired slagging combustor: Development of a slag submodel

In a slagging combustor or furnace, the high combustion temperature makes the molten slag layer cover the wall and capture the particles. If these particles contain combustible matter, they will continue to burn on the running slag. As a result, the total amount of ash deposition will be much greater than that in dry-wall combustors and the total heat flux through the deposition surface will change greatly. Considering the limitations of existing simulation methods for slagging combustion, this paper introduces a new wall burning model and slag flow model from the analysis; of particle deposition phenomena. Combined with a conventional combustion simulation program, the total computational frame is introduced. From comparisons of simulation results from several kinds of methods with experimental data, the conclusion is drawn that the conventional simulation methods are not very suitable for slagging combustion and the wall burning mechanism should be considered more thoroughly.

Pulverized-coal combustion in Wall-Protecting-Jets combustor (WPJC)

A new type of pulverized-coal combustor, called "Wall-Protecting-Jets Combustor" (hereafter, WPJC has been proposed, designed and studied with both CFD (Computational Fluid Dynamics) and experimental methods. The WPJC is based on a novel concept in which all inlet jets are along the combustor wall. Pilot combustion experiments were conducted to investigate the combustion performance of WPJC. Two-phase flows and pulverized-coal combustion were simulated to study the mechanism of),WPJC using the commercial software FLUENT. The results show that the WPJC has many remarkable advantages: wall-protection by the cold jets without the use of refractory materials; low-temperature and three-stage combustion with low NOx emission; negligible ash/slag-deposition; multiple functions with convenient switching between them; effective adjustment of the combustion intensity and the ignition position.

Numerical modeling of 3-D turbulent two-phase flow and coal combustion in a pulverized-coal combustor

In the present paper, a multifluid model of two-phase flows with pulverized-coal combustion, based on a continuum-trajectory model with reacting particle phase, is developed and employed to simulate the 3-D turbulent two-phase hows and combustion in a new type of pulverized-coal combustor with one primary-air jet placed along the wall of the combustor. The results show that: (1) this continuum-trajectory model with reacting particle phase can be used in practical engineering to qualitatively predict the flame stability, concentrations of gas species, possibilities of slag formation and soot deposition, etc.; (2) large recirculation zones can be created in the combustor, which is favorable to the ignition and flame stabilization.

Destruction of Chemical Agents in a Plasma Reactor with Working Gas of Hydrogen

Plasma-Arc Technology For The Thermal Treatment Of Chemical Wastes

Plasma-arc technology was developed to dispose of chemical wastes from a chemical plant by the Institute of Mechanics, Chinese Academy of Sciences (CAS-IMECH). A pilot plant system with this technology was constructed to destroy two types of chemical wastes. The system included shredding, mixing, and feeding subsystems, a plasma-arc reactor of 150 kW, an off-gas burning subsystem, and a scrubbing subsystem. The additives (CaO, SiO2, and Fe) were added into the reactor to form vitrified slag and capture the hazardous elements. The molten slag was quickly quenched to form an amorphous glassy structure. A direct current (DC) experimental facility of 30kW with plasma-arc technology was also set up to study the pyrolysis process in the laboratory, and the experimental results showed the cooling speed is the most important factor for good vitrified structure of the slag. According to previous tests, the destruction and removal efficiency (DRE) for these chemical wastes was more than 99.999%, and the polychlorinated biphenyls (PCBs) concentration in the solid residues was in the range of 1.28 to 12.9mg/kg, which is far below the Chinese national emission limit for the hazardous wastes. A simplified electromagneto model for numerical simulation was developed to predict the temperature and velocity fields. This model can make satisfactory maximum temperature and velocity distributions in the arc region, as well as the results by the magneto hydrodynamic approach.

Differentiate performance of eight filter media in vertical flow constructed wetland: Removal of organic matter, nitrogen and phosphorus

A comparative study was conducted to reveal the differentiate effects of eight different filter media including gravel, zeolites, anthracite, shale, vermiculite, ceramic filter media, blast furnace steel slag and round ceramsite. The study mainly related to the eight different filter media's removal performances of organic matter, nitrogen and phosphorus in the vertical flow constructed wetland simulated system, which treating wastewater at hydraulic loading rate of 1000-2500 mm/d. The results indicated that the removal effects were closely related to the physical and chemical properties of medium materials. Anthracite-filled system had the highest removal rate for the total organic carbon (TOC), up to 70%, and the removal rates of other systems ranged from 20% to 30%. As for the five-day biochemical oxygen demand (BOD5), anthracite-filled and steel slag-filled systems had the highest removal rates, also up to 70%, as well as other systems all exceeded 50%. At the same time, for the total nitrogen (TN) and NH4(+)-N, the zeolites-filled and ceramic-filled systems had the best performances with the removal rates of more than 70%, the other way round, the removal rates of other systems were only about 20%. The distinguishable effects were also observed in removal performances of total phosphorus (TP) and total dissoluble phosphorus (TDP). The removal rates of TP and TDP in steel slag-filled systems were more than 90%, a much higher value, followed by that of the anthracite-filled system, more than 60%, but those of other systems being the less. Our study provided a potential mechanism to optimize the filter media design for the vertical flow constructed wetlands.

INFLUENCE OF LINEAR ALKYLBENZENE SULFONATE (LAS) AS ORGANIC COSOLVENT ON LEACHING BEHAVIOR OF PCDD/FS FROM FLY-ASH AND SOIL

The leaching of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) was measured in soil and standard fly ash column eluted with pure water and linear alkylbenzene sulfonate (LAS)- water. The data obtained were used to evaluate the leachability of PCDD/Fs from waste dump like incineration residual slag and fly ash deposition. The leaching rate was shown to be increased significantly by using LAS water. The leachate contents of PCDD/Fs were above their known water solubility. Concentration of PCDD/Fs in the leachates as well as the relative leaching (calculated on the fly ash content) increased with increasing chlorinating degree and decreasing water solubility. LAS above the critical micelle concentration (CMC) probably enhances PCDD/Fs solubility.

The Deposition and Burning Characteristics During Slagging Co-Firing Coal and Wood: Modeling and Numerical Simulation

Numerical analysis was used to study the deposition and burning characteristics of combining co-combustion with slagging combustion technologies in this paper. The pyrolysis and burning kinetic models of different fuels were implanted into the WBSF-PCC2 (wall burning and slag flow in pulverized co-combustion) computation code, and then the slagging and co-combustion characteristicsespecially the wall burning mechanism of different solid fuels and their effects on the whole burning behavior in the cylindrical combustor at different mixing ratios under the condition of keeping the heat input samewere simulated numerically. The results showed that adding wood powder at 25% mass fraction can increase the temperature at the initial stage of combustion, which is helpful to utilize the front space of the combustor. Adding wood powder at a 25% mass fraction can increase the reaction rate at the initial combustion stage; also, the coal ignitability is improved, and the burnout efficiency is enhanced by about 5% of suspension and deposition particles, which is helpful for coal particles to burn entirely and for combustion devices to minimize their dimensions or sizes. The results also showed that adding wood powder at a proper ratio is helpful to keep the combustion stability, not only because of the enhancement for the burning characteristics, but also because the running slag layer structure can be changed more continuously, which is very important for avoiding the abnormal slag accumulation in the slagging combustor. The theoretic analysis in this paper proves that unification of co-combustion and slagging combustion technologies is feasible, though more comprehensive and rigorous research is needed.

利用城乡废弃资源提高土壤保水保肥功能

以生活炉渣、建筑废料、生物秸秆等城乡废弃资源为原料,制备一种面向节水农业的环保新产品———土壤扩蓄增容肥.实验结果表明:在棉花苗期,6种土壤扩蓄增容肥配方的节水效果较土对照高300倍,干物质积累增加4.77%~50.00%.6种配方的皮棉产量均比对照高,增产幅度为4.70%~14.25%,纤维物理性状有所改善.产量高低顺序依次是,玉米秸秆>小麦秸秆>生活炉渣>秸秆木炭>建筑废料>煤矸石>CK.利用城乡废弃资源生产的扩蓄增容剂,不仅能改良土壤物理和化学性状,更是棉花增产、优质、节水、降低生产成本的关键技术措施之一,具有显著的生态效益、社会效益和经济效益.

Rare earth complexes with Ge-132 and their catalytic hydrolysis to phosphatide bond of mononucleotide

The complexes of a series of rare earths with Ge-132 have been prepared. The carboxyl anions of Ge-132 molecule were coordinated to rare earth ion with chelate style. In the complexes molecule, the GeO3/2 group of Ge-132 were hydrolyzed to become -Ge(OH)(3) group, and later does:not coordinate with rare earth ions. All of the complexes possess similar properties. In aqueous solution of pH 6 and 50 degrees C, these complexes can obviously selectively catalytically hydrolize the phosphatide bond of 5'-AMP and 5'-dAMP into phosphatic acid and riboside.

ELECTROCHEMICAL MECHANISM FOR FULLERENE FORMATION IN PLASMA ARCS

During the synthesis of fullerenes by dc plasma arcs, it has been found that the anodic graphite rod consistently burns up, while the cathodic graphite rod grows slag at its end. Further investigations revealed that the anodic and cathodic graphite rods p

转炉钢渣对海洋生态环境影响及碳的生物利用探索研究

利用“铁肥”方法增加海洋初级生产力、吸收大气中的CO2、降低温室效应是目前国际上的一个研究热点。为此，本文利用炼钢企业产生的废料转炉钢渣，系统研究了其对海洋微藻生长的影响， 同时研究了转炉钢渣对海水水质及海洋生物的影响，探讨了其作为“铁肥”材料的可行性。 本文首先研究了转炉钢渣对海水水质的影响，包括金属、营养盐、pH、COD及浊度等理化参数。研究发现，在天然海水中加入转炉钢渣后营养盐均有不同程度的溶出；实验条件下，在天然海水和人工海水中加入钢渣，金属大部份被吸附，个别金属溶出，但基本都达到了一、二类海水标准，而pH明显增高，大多超过了海水水质三、四级（6.88.8）的范围，COD低于一类海水水质标准。实验结果显示，钢渣粒度越小、浓度越大，水质浊度越大，但钢渣的比重一般较大，在水体中可以较快的沉降，所以在实际应用过程中不会对水体的透明度造成不良影响。 研究了转炉钢渣对典型海洋底栖生物（紫贻贝）、海洋游泳生物（日本对虾和中国对虾幼虾）的影响。在实验浓度范围内，钢渣对紫贻贝的急性毒性作用基本可以忽略，但紫贻贝的生长率和摄食率随钢渣浓度的增加有所下降，血细胞个数有所下降，但形态没有显著变化，对紫贻贝的免疫功能没有太大影响。钢渣对日本对虾幼虾的半致死浓度为1.62g/L，对中国对虾幼虾的半致死浓度要高于日本对虾，说明在实验条件下中国对虾幼虾的适应能力高于日本对虾幼虾。 另外，重点考察了转炉钢渣对海洋浮游植物－赤潮异弯藻和中肋骨条藻生长的影响，发现加入钢渣以后，相对于对照组微藻生物量显著增加。当钢渣浓度为124248mg/L时赤潮异弯藻的生物量达到最大，当钢渣浓度达到61124mg/L时，中肋骨条藻的生物量最大；钢渣对两种微藻生长的影响规律是相同的，但是影响程度因不同藻种而有所不同，其中对中肋骨条藻的促进作用更加显著，可能与钢渣中能溶出较大量的硅酸盐有关。在室内实验的基础上，初步估算了通过钢渣对微藻生长的促进作用，近海每平方公里海域对二氧化碳吸收的增加量。