Latest progress of the RFQ cooler and buncher RFQ1L

The RFQ cooler and buncher RFQ1L is a key device of the SHANS (Spectrometer for Heavy Atoms and Nucleax Structure). The status of the machining and assembly of the central part is introduced, and the structure of the whole RFQ1L system and the preliminary plan for the testing are discussed also.

Dissociative recombination of the acetaldehyde cation, CH3CHO+

The dissociative recombination of the acetaldehyde cation, CH3CHO+, has been investigated at the heavy ion storage ring CRYRING at the Manne Siegbahn Laboratory in Stockholm, Sweden. The dependence of the absolute cross section of the reaction on the relative kinetic energy has been determined and a thermal rate coefficient of k(T) = (1.5 +/- 0.2) x 10(-6) (T/300)(-0.70 +/- 0.02) cm(3) s(-1) has been deduced, which is valid for electron temperatures between similar to 10 and 1000 K. The branching fractions of the reaction were studied at similar to 0 eV relative kinetic energy and we found that breaking one of the bonds between two of the heavy atoms occurs in 72 +/- 2% of the reactions. In the remaining events the three heavy atoms stay in the same product fragment. While the branching fractions are fairly similar to the results from an earlier investigation into the dissociative recombination of the fully deuterated acetaldehyde cation, CD3CDO+, the thermal rate coefficient is somewhat larger for CH3CHO+. Astrochemical implications of the results are discussed.

DISSOCIATIVE RECOMBINATION OF PROTONATED PROPIONITRILE, CH3CH2CNH+: IMPLICATIONS FOR TITAN'S UPPER ATMOSPHERE

The dissociative recombination of protonated propionitrile, CH3CH2CNH+, has been investigated at the heavy ion storage ring, CRYRING, at the Manne Siegbahn Laboratory, Stockholm University, Sweden. The thermal rate coefficient has been deduced to follow k(T) = (1.5 +/- 0.2) x 10(-6) (T/300)(-0.76) (+/-) (0.02) cm(3) s(-1) for electron temperatures ranging from similar to 10 to similar to 1000 K. Measurements of the branching fractions were performed at similar to 0 eV relative kinetic energy. It has been found that in 43% +/- 2% of the reactions the four heavy atoms remain in the same product fragment. An equal portion of the reactions leads to products where one of the heavy atoms is split off from the other three and 14% +/- 1% result in a breakup into two heavy fragments containing two heavy atoms each. We discuss the significance of the data to Titan's upper atmosphere.

RFQ冷却聚束器RFQ1L的研制

SHANS (Spectrometer of Heavy Atoms and Nuclear Structure，重原子和核结构研究谱议)正在建设中，它不但可以直接鉴别离子的电荷数Z和质量数A，而且还将在核结构和核衰变的精细研究方面发挥重要作用。RFQ冷却聚束器RFQ1L和彭宁离子阱LPT是其中的两个重要组成部分。 RFQ冷却聚束器RFQ1L的主要目的是收集经过充气反冲谱议分离后的反应产物，然后经过冷却、聚束，使原来品质很差的束流转化为能量单一、发射度小、束斑很小的高品质束流。现在已经顺利完成了模拟、设计、机械加工和机械安装等工作，其中机械安装部分是本论文的主要工作之一。经过近半年的时间，我们克服了种种困难，高质量地完成了RFQ1L的机械安装工作。各种测量综合显示：各部件间的位置精度达到了±0.5 mm；真空系统的真空度达到了1.7×10-4 Pa，系统压升率为(0.04±0.02) Pa/h；各电极间的绝缘效果和导电效果良好。彭宁离子阱LPT的主要目的是直接高精度测量原子核的质量。质量是原子核的一个最基本属性，对检验和拓广现有核理论、研究核天体物理中的核反应过程和基本常数具有非常重要的作用。控制系统在LPT中起着至关重要的作用。控制系统的设计和实现也是本论文的另一个主要工作。本论文详细论述了LPT的控制系统LPTCtrlSys的基本要求、硬件和软件布局情况

Three dimensional solution structure of neurotoxin CM-11 from the Ophiophagus hannah

The Ophiophagus hannah (King Cobra) neurotoxin CM-11 is a small protein with 72 amino acid residues, Based on complete assignments of H-1-NMR resonances and determination of secondary structures of CM-11, 349 distance and 27 dihedral angle constraints including 19 phi's and 8 chi's were collected from NOESY and DQF-COSY , and the chemical stereospecific assignment of beta(1)H was partially achieved, Twelve structures with lower energy was obtained via metric matrix distance geometry and refinement with simulated annealing, These structures have a low RMSD of 0.14 nm for backbone atoms and 0.20 nm for heavy atoms, with no distance constraint violation more than 0.05 nm, and no dihedral angle violation more than 3 degrees.

Effects of chloride substitution on the chemical and physical properties and the crystallization behavior in heavy metal fluoride glasses

Effect of the substitutions of chloride for fluoride on the chemical and physical properties and the crystallization behavior in heavy metal fluoride glasses has been investigated. The characteristic temperature of the glass does not changed obviously when the fluoride was taken place by chloride. Compared with samples of being free of ErF3, the doping samples are more inclined to be surface crystallization. Optical basicity in the glass system increases with increasing the negative charge provided by the chloride atoms and the absorption peak red shifted is observed in absorption spectra. XRD measurements show that not a single crystalline phase appears in the heated glass samples, which indicate the substitutions of chloride for fluoride with a variety of crystalline precipitation trends. (c) 2007 Elsevier B.V All rights reserved.