Abatement of waste gases and water during the processes of semiconductor fabrication

The purpose of this article is to examine the methods and equipment for abating waste gases and water produced during the manufacture of semiconductor materials and devices. Three separating methods and equipment are used to control three different groups of electronic wastes. The first group includes arsine and phosphine emitted during the processes of semiconductor materials manufacture. The abatement procedure for this group of pollutants consists of adding iodates, cupric and manganese salts to a multiple shower tower (MST) structure. The second group includes pollutants containing arsenic, phosphorus, HF, HCl, NO2, and SO3 emitted during the manufacture of semiconductor materials and devices. The abatement procedure involves mixing oxidants and bases in an oval column with a separator in the middle. The third group consists of the ions of As, P and heavy metals contained in the waste water. The abatement procedure includes adding CaCO3 and ferric salts in a flocculation-sedimentation compact device equipment. Test results showed that all waste gases and water after the abatement procedures presented in this article passed the discharge standards set by the State Environmental Protection Administration of China.

Environmental Kuznets Curve for SO_2 Emissions in China

This study examines the link between the economic growth and the environmental quality. Based on a panel data set, a N-shaped Environmental Kuzents Curve has been found for the sample period: a cubic relationship between per capita GDP and emissions of sulphur dioxide (SO2). We also find that energy consumption is an important determinant of environmental degradation. The empirical results suggest that we should promote environmental protection as soon as possible.

Coagulation removal of melanoidins from biologically treated molasses wastewater using ferric chloride

The pigments (melanoidins) in molasses wastewater are refractory to conventional biological treatment. Ferric chloride was used as coagulant to remove color and chemical oxygen demand (COD) from molasses effluent. Using jar test procedure, main operating conditions such as pH and coagulant dosage were investigated. Under the optimum conditions, up to 86% and 96% of COD and color removal efficiencies were achieved. Residual turbidity in supernatant was less than 5 NTU and Fe3+ concentration was negligible because of effective destabilization and subsequent sedimentation. The results of high performance size exclusion chromatography (HPSEC) show that low molecular weight (MW) fraction of melanoidins is more reactive than high MW fraction and increase in the concentration of the lowest MW organic group is related to the capacity of charge neutralization. Aggregate size measurement reveals the size effect on the settleability of flocs formed, with larger flocs settling more rapidly. Charge neutralization and co-precipitation are proposed as predominant coagulation mechanism under the optimum conditions. (C) 2009 Elsevier B.V. All rights reserved.

ANTHROPOGENIC ORGANIC CONTAMINANTS IN WATER AND SURFACE SEDIMENTS OF LARGE SHALLOW EUTROPHIC CHAOHU LAKE, CHINA

To characterize the contamination of anthropogenic organic contaminants in the aquatic environment of Chaohu Lake, China, 7 samples for both water and surface sediment were collected in the lake. Organic contaminants were extracted by solid phase extraction (SPE) and Soxhlet extraction from the water and surface sediment samples, respectively, and then analyzed by GC-MS. One hundred and twenty kinds of organic chemicals were detected in these samples including phenol, benzene series, benzaldehydes, ethanol, polycyclic aromatic hydrocarbons (PAHs), sulfur compounds, alcoholic halides, amines, ketones, esters, alkenes and alkanes. Among them, 13 kinds of chemicals were identified as priority pollutants listed by the U.S. Environmental Protection Agency (EPA), such as phthalate esters (PAEs) and PAHs. Besides, the concentrations of 19 of PAEs and PAHs including, priority pollutants identified were also determined. Bis(2-ethylhexyl)phthalate, the predominant component of the analyzed pollutants, was in the range from 72.34 ng g(-1) DW to 613.71 ng g(-1) DW, 14.80 ng L-1 to 47.05 ng L-1 in sediment and water, respectively. The results indicated that the northwest part of the lake was heavily polluted by domestic and industrial wastewater.

Polishing Treatment of Molasses Wastewater with Iron Salts: the Role of Counter-ions

The effect of counter-ions on the coagulation of biologically treated molasses wastewater using iron-based coagulants was investigated. Parameters such as removals of chemical oxygen demand (COD) and color, and residual turbidity, were measured to evaluate coagulation performance. Experimental results showed that ferric chloride and ferric nitrate were more effective than ferric sulfate at optimal dosages, achieving 89 to 90% and 98 to 99% of COD and color removals, respectively, with residual turbidity of less than 5 NTU. High-performance size exclusion chromatography (HPSEC) results revealed differences in the removal of the molecular weight fraction of organic compounds using iron salts. Scanning electron microscopy (SEM) showed randomly formed coagulated flocs characterized with irregular, sheet-like shapes. Nitrate and chloride counter-ions had similar effects on coagulation performance compared to sulfate. Both FeCl3 and Fe(NO3)(3) yielded better results than Fe(SO4)(2) under underdosed and optimum dosage conditions. Coagulation efficiency was less adversely affected in the overdosed regions, however, if sulfate rather than chloride or nitrate was present. Water Environ. Res., 81, 2293 (2009).

Variables affecting melanoidins removal from molasses wastewater by coagulation/flocculation

Coagulation/flocculation process was applied in the polishing treatment of molasses wastewater on a bench-scale. Important operating variables, including coagulant type and dosage, solution pH, rapid mixing conditions as well as the type and dosage of polyeletrolytes were investigated based on the maximum removal efficiencies of chemical oxygen demand (COD) and color, residual turbidity and settling characteristics of flocs. HPSEC was utilized to evaluate the removal of molecular weight fractions of melanoidins-dominated organic compounds. Experimental results indicate that ferric chloride was the most effective among the conventional coagulants, achieving 89% COD and 98% color eliminations; while aluminum sulfate was the least effective, giving COD and color reductions of 66% and 86%, respectively. In addition to metal cations, counter-ions exert significant influence on the coagulation performance since Cl--based metal salts attained better removal efficiency than SO42--based ones at the optimal coagulant dosages. Coagulation of molasses effluent is a highly pH-dependent process, with better removal efficiency achieved at lower pH levels. Rapid mixing intensity, rather than rapid mixing time, has relatively strong influence on the settling characteristics of flocs formed. Lowering mixing intensity resulted in increasing settling rate but the accumulation of floating flocs. When used as coagulant aids, synthetic polyelectrolytes showed little effects on the improvement in organic removal. On the other hand, cationic polyacrylamide was observed to substantially enhance the settleability of flocs as compared to anionic polyacrylamide. The effects of rapid mixing conditions and polymer flocculants on the coagulation performance were discussed. (C) 2009 Elsevier B.V. All rights reserved.

Hydrolysis and coagulation behavior of polyferric sulfate and ferric sulfate

The hydrolysis behaviors of polyferric sulfate (PFS) and ferric sulfate (FS) under conditions similar to raw wastewater were investigated and the coagulation of biologically pretreated molasses wastewater using PFS and FS was evaluated by studying coagulation efficiency, zeta potential and microscopic surface morphology of flocs. Experimental results show that the hydrolysis behavior of PFS is different from that of FS on the basis of ferron assay. In the case of FS, fast-reacting Fe(III) polymers were the dominant polynuclear species while large fraction of slow-reacting iron polymers is present in PFS. Despite slightly fewer dosages of PFS required as compared to FS, there is no marked difference in the coagulation of molasses effluent between PFS and FS, especially at the optimum dosages. Both coagulants destabilize organic compounds predominantly through charge neutralization-precipitation mechanism. Hydrolysis rate of PFS in synthetic solution is appreciably different from that in raw wastewater. This may due to the effect of sulfate anion introduced as counter-ion as well as depolymerization of larger polymeric Fe(III) species by the organic ligands present in molasses effluent.

森林流域单元水文模型的构建与应用

目前全球缺水、水污染、洪涝灾害以及水土流失仍然非常严重，尤其在我国北方地区。流域水文模型可用来进行不同需水管理的情景分析，为解决我国水问题提供科学依据。分布式水文模型是流域水文模型的发展方向，具有显著特点：1）应用前景广泛，不仅可以模拟流域水文过程，还可以协助模拟泥沙或污染物的运移过程，为水利工程设计、水土保持、环境保护等领域提供技术支持；2）能够预测流域土地利用或气候变化下的流域水文响应过程变化，为管理部门提供决策支持；3）模型所需要的参数全部具有物理意义，可通过实际测量确定，适合模拟实测系列较短或是无观测流域的水文过程；4）对于目前国际水文界的前沿问题—水文尺度转换提供了一种有效的解决途径。 然而分布式水文模型还不完善，如1)真实性问题。对一些水文过程和边界条件还不确定。2)尺度转换问题。目前很少考虑尺度对参数有效性的影响。3)检验问题。还无法判断对有些难以测量的水文状态变量的模拟正确与否。4)计算时间和数据存储的问题。有些分布式水文模型虽然具有很强的水文物理基础和完善的模型结构，但是计算时间过长和(或)数据存储过大，难以应用。上述问题的核心就是对分布式水文模型的核心—单元水文模型的研究不够，需要为进一步完善单元水文模型进行研究。 本文采用饱和入渗理论、Saint-Venant方程、Richards方程、Penman-Monteith方程等等构建了以有限差分法求解的适用于森林流域的单元水文模型，并通过实验室模拟试验和坡地径流场资料进行了验证，主要结论为： 通过不同坡度和不同雨强下的室内坡面产汇流实验模拟，表明：该模型模拟的坡面流和壤中流过程与实测过程基本一致，峰现时间、径流历时、峰值流量、出流总量模拟值与实测值的相对误差均较小，基本小于10%。模型的模拟精度较高，实用性较强，为深入研究壤中流机制和改进流域降雨-径流模型提供了理论依据。 通过坡地径流观测场实测资料的验证，表明：该模型模拟的坡面流过程精度较高，累计流量的精度更高于小时过程的精度，离差系数、效率系数、确定系数均较理想，具有应用价值，有助于改善分布式水文模型在森林流域的模拟效果。

土地利用总体规划环境影响评价指标体系研究——以邛崃市土地利用总体规划为例

土地利用是人类根据土地质量特性来开发利用土地，创造财富，满足人类生产和生活的需要，同时改善环境，满足人类生存需要的过程。土地利用总体规划是对未来各类用地在空间上、时间上作出总体的协调的预先安排，不仅受到一定历史背景的制约，同时也受影响于当前的社会经济发展情况。但是，国内传统的土地利用总体规划往往从狭窄的技术经济观点出发，对远期的生态环境问题、社会问题缺少考虑，将新的用地尽量安排在最便捷、最经济的地方。 由于土地利用总体规划对环境影响具有长期性、复杂性、综合性、有时还有不可逆转性等特点，迫切需要在编制土地利用总体规划时对规划区与土地利用有关的环境影响进行科学研究，把环境保护纳入土地利用活动的计划、决策和规划实施中，促进土地资源持续、协调的利用。为更好地进行土地利用总体规划环境影响评价必须首先建立相应的评价指标体系，而目前国内关于该项研究的理论和实践的相关报道都较少。 本论文在综述国内外土地利用总体规划环境影响评价的理论与实践的基础上，在国内第一批开展了相关领域的案例研究，采用理论研究和案例分析相结合的研究方法对土地利用总体规划环境影响评价方法和指标体系进行了研究，对邛崃市土地利用总体规划进行了环境影响评价，其研究的主要内容和论点如下: (1)第一次根据FAO 确定的五大原则，引入了生态用地的概念并按照价值模型构建了以土地资源可持续利用为目标的县级土地利用总体规划环境影响评价的指标体系。以生产性、稳定性、保护性、经济活力、社会可接受性五个方面作为指标层来度量土地利用总体规划的环境影响，并选取了土地利用率、土地整理率、水面指数、生态用地面积比例、耕地转化率、建设用地产值指数、公众满意度等21 个元指标作为具体的评价指标。该指标体系强调了规划方案的公众参与，便于充分吸收公众的意见和建议；并且评价指标获取容易，实用性较强。 (2)在土地利用总体规划环境影响评价方法上进行了有益的探索和尝试，由于土地利用总体规划环境影响评价的主要对象是几个拟定的规划方案，所以采用综合评分法（包括特尔斐法和层次分析法）和公众参与相结合的评价方法。应用上述指标体系和评价方法对邛崃市土地利用总体规划的三个方案进行了评价筛选，高方案最终得分为92.049；中方案最终得分为91.028；而低方案最终得分为95.541，为最优方案。 （3）开展了对土地利用总体规划替代方案和公众参与机制的研究，对公众参与的方式、程序及主要内容从理论和实践两方面进行了有益的尝试，收到了良好的效果。 （4）对邛崃市土地利用总体规划进行了环境影响评价，根据邛崃市的具体情况，对规划实施后可能造成的环境正、负面影响进行了分析和预测，提出了预防或者减轻不良环境影响的对策和措施。 Land use is a process, which is to develop land according to its mass property. Bycreating the wealth and improving the environment, it can meet the need of production,life and human survival. Land use planning, as a planning form to guide land use, issubject to the historical background, and influenced by development of economic andsociety. The land use planning in the past, from narrow economic technology view,lacking of concerning ecologic environmentand social problem, arranged new land in the most convenient and economic place. Because of complexity, comprehensive and sometimes irreversible characteristicsof environmental impact caused by land use planning which has been implemented, it isneed to carry on scientific research on environmental impact related to land use as theland use planning is forming, to bring environmental protection within the plan, policymaking and implementing of land use activity, promoting the sustainment, harmonious use of land resource. This paper, taking the readjustment of land use planning in Qionglai as an example,assessed its environmental impact of land use planning. The main contents and results arepresented as follows: (1) On the basis of the five criterions of AFO, for the first time propose county classoverall planning of land uses SEA index by inducting ecological land use andestablishing the Value factor system, according to Productivity criterion，Stabilitycriterion，Sheltered criterion，Economic livingness criterion，Social acceptabilitycriterion，the environmental impact of land use system was assessed by using Valuemodel. Through identifying the factors of environmental impact of land use planning, thepaper established the factor system of SEA of land use planning. From the land usefactors, 21 factors was chosen to assess the environmental impact degree of land useplanning, such as, index of land use degree, the rate of land collating, index of watersurface, the rate of ecological use land, cultivated land conversion ratio, forest landconversion ratio, public satisfaction degree and so on. These indexes make a point thatpublic participation of plan project fully absorb public idea and propose and the index easily get, better utility. (2) Attempt useful assessment method system of SEA of land use planning. In viewof there are no or almost no inevitable contact among the factors of SEA of land useplanning，we use AHP （Analytic Hierarchy Process） as the main assess method . Thereare three plans are compared in this paper apply the foregoing index and assessmentmethod. The high plan finally score is 92.049，while the middle plan is 91.028. The lowplan score is 95.541，is the best one，as the selected plan. (3) Carry on the research of the alternative scheme of overall planing of land useand public participation，to the fashion ，procedure and object matter carry out helpfulattempt from theory to practice，the results is good. （4）Took place SEA of Qionglai County overall planing of land use，according to thecircumstance of Qionglai，we analyze and forecast the positive and negative affect afterthe plan implement，and put forward the countermeasure and means to prevent or abatebad environmental impact.

关于黄土高原农业、生态环境建设与土地资源问题的研究

对农业、环境建设、自然资源和农业生态经济“专家”系统建设等限制黄土高原生态农业建设和发展的有关的重大问题进行了理论分析 ,探讨了其存在的问题和运作设想 ,以求得在上述几个领域内为黄土高原生态农业、环境保护和经济的发展提供参考

中国环境问题与持续发展

人口、资源、环境和灾害问题已刻不容缓地提到人类发展的日程上来,它不仅是自然科学的问题,同时也是社会问题.在国际环境保护的浪潮日益高涨、国内生态环境保护工作日益发展、社会主义市场经济逐渐发育完善的新形势下,我国正在采取一系列措施,保护生态环境,提高全社会的环保意识,大力开展生态建设,控制环境污染,实现经济建设与环境保护的相互配合和协调发展.笔者在上述背景下,分析了国内外人口增长过快、资源逐减少、环境日趋恶化、灾害发生频繁等严重危害社会发展之恶果,讨论了中国政府自1992年巴西“环发”大会之后所采取的一系列行动.

Industrial development and land use/cover change and their effects on local environment: a case study of Changshu in eastern coastal China

The interactions among industrial development, land use/cover change (LUCC), and environmental effects in Changshu in the eastern coastal China were analyzed using high-resolution Landsat TM data in 1990, 1995, 2000, and 2006, socio-economic data and water environmental quality monitoring data from research institutes and governmental departments. Three phases of industrial development in Changshu were examined (i.e., the three periods of 1990 to 1995, 1995 to 2000, and 2000 to 2006). Besides industrial development and rapid urbanization, land use/cover in Changshu had changed drastically from 1990 to 2006. This change was characterized by major replacements of farmland by urban and rural settlements, artificial ponds, forested and constructed land. Industrialization, urbanization, agricultural structure adjustment, and rural housing construction were the major socio-economic driving forces of LUCC in Changshu. In addition, the annual value of ecosystem services in Changshu decreased slightly during 1990-2000, but increased significantly during 2000-2006. Nevertheless, the local environmental quality in Changshu, especially in rural areas, has not yet been improved significantly. Thus, this paper suggests an increased attention to fully realize the role of land supply in adjustment of environment-friendly industrial structure and urban-rural spatial restructuring, and translating the land management and environmental protection policies into an optimized industrial distribution and land-use pattern.

Land use and water quality response in the northern region of Changxing County

In this paper, taking the northern region of Changxing County for example, with ammonia nitrogen as a pollution assessment index, we used an improved export coefficient method for estimate polluting load of non-point source pollution (NSP) and the social pollution survey data in the study area to estimate point source pollution. By comparing the total pollution output and the national surface water environmental quality standards find that the whole study area achieves the second water quality standard. However, Jiapu Township exceeds the water quality standards seriously because of the superfluous point source pollution. The water quality of other Townships is good. Further analysis showed that different types of land use and proportions in the northern region of Changxing County have a significant impact on the non-point source pollution, the general law is farmland contributes the largest share of the non-point source pollution output, followed by residential area and bare land, besides, with the increase in the proportion of forest and the decrease of farmland and residential area, the non-point source pollution reduces gradually. © 2010 IEEE.