激光熔覆大厚度Fe57Co8Ni8Zr10Si4B13非晶表层及其微结构研究

利用激光熔覆制备出１.２ｍｍ厚的Ｆｅ５７Ｃｏ８Ｎｉ８Ｚｒ１０Ｓｉ４Ｂ１３大厚度非晶表层。用ＸＲＤ，ＥＤＳ，ＴＥＭ，ＤＳＣ及硬度仪对获得的非晶表层进行了多种分析，研究了非晶合金表层的微结构与非晶形成能力，初步探讨了大厚度非晶表层的形成机制。

张力腿平台拉索的疲劳损伤

目前在分析张力腿平台(TLP)疲劳损伤时,通常限定平台只发生小位移,未考虑不利工况下平台发生有限位移的情况.在分析模型中考虑有限大位移后,会引入多种非线性因素,也会使TLP的动力响应明显不同于小位移情况,因此研究TLP有限位移下非线性波浪载荷引起的疲劳损伤十分重要.首先求得随机海浪作用下TLP拉索应力的时间历程曲线,并采用雨流法对其进行计数得到疲劳载荷谱;然后依据Miner累积损伤模型,求得TLP拉索在不利工况下的疲劳损伤;最后对ISSC TLP平台拉索在某海况下进行了疲劳损伤短期计算,并说明TLP拉索疲

Electromechanical influence of crack velocity at bifurcation for poled ferroelectric materials

The piezoelastodynamic field equations are solved to determine the crack velocity at bifurcation for poled ferroelectric materials where the applied electrical field and mechanical stress can be varied. The underlying physical mechanism, however, may not correspond to that assumed in the analytical model. Bifurcation has been related to the occurrence of a pair of maximum circumferential stress oriented symmetrically about the moving crack path. The velocity at which this behavior prevails has been referred to as the limiting crack speed. Unlike the classical approach, bifurcation will be identified with finite distances ahead of a moving crack. Nucleation of microcracks can thus be modelled in a single formulation. This can be accomplished by using the energy density function where fracture initiation is identified with dominance of dilatation in relation to distortion. Poled ferroelectric materials are selected for this study because the microstructure effects for this class of materials can be readily reflected by the elastic, piezoelectic and dielectric permittivity constants at the macroscopic scale. Existing test data could also shed light on the trend of the analytical predictions. Numerical results are thus computed for PZT-4 and compared with those for PZT-6B in an effort to show whether the branching behavior would be affected by the difference in the material microstructures. A range of crack bifurcation speed upsilon(b) is found for different r/a and E/sigma ratios. Here, r and a stand for the radial distance and half crack length, respectively, while E and a for the electric field and mechanical stress. For PZT-6B with upsilon(b) in the range 100-1700 m/s, the bifurcation angles varied from +/-6degrees to +/-39degrees. This corresponds to E/sigma of -0.072 to 0.024 V m/N. At the same distance r/a = 0.1, PZT-4 gives upsilon(b) values of 1100-2100 m/s; bifurcation angles of +/-15degrees to +/-49degrees; and E/sigma of -0.056 to 0.059 V m/N. In general, the bifurcation angles +/-theta(0) are found to decrease with decreasing crack velocity as the distance r/a is increased. Relatively speaking, the speed upsilon(b) and angles +/-theta(0) for PZT-4 are much greater than those for PZT-6B. This may be attributed to the high electromechanical coupling effect of PZT-4. Using upsilon(b)(0) as a base reference, an equality relation upsilon(b)(-) < upsilon(b)(0) < upsilon(b)(+) can be established. The superscripts -, 0 and + refer, respectively, to negative, zero and positive electric field. This is reminiscent of the enhancement and retardation of crack growth behavior due to change in poling direction. Bifurcation characteristics are found to be somewhat erratic when r/a approaches the range 10(-2)-10(-1) where the kinetic energy densities would fluctuate and then rise as the distance from the moving crack is increased. This is an artifact introduced by the far away condition of non-vanishing particle velocity. A finite kinetic energy density prevails at infinity unless it is made to vanish in the boundary value problem. Future works are recommended to further clarify the physical mechanism(s) associated with bifurcation by means of analysis and experiment. Damage at the microscopic level needs to be addressed since it has been known to affect the macrocrack speeds and bifurcation characteristics. (C) 2002 Published by Elsevier Science Ltd.

高频等离子法制取超细Si_3N_4粉末

本文述及高频等离子法制取超细Si_3N_4粉末的原理、装置,工艺参数及粉末性能的一些检测结果。利用SiCl_4+NH_3气-气相反应,所得白色粉末含有NH_4Cl晶体,热重分析表明350℃失重停止,280℃失重速率最快,经400～700℃处理后的粉末仍为非晶,不含NH_4Cl,BET测得比表面积为75.8 m~2/g,X光小角度散射法测粒子半径分布主峰R为100～150,且符合正态对数分布规律,平均直径=527;1400℃处理后,X光衍射测得主相为α-Si_3N_4、次相为Si_2N_2O,粒径明显长大,平均直径达1700。

Rayleigh-Bénard热对流的动理论分析

利用基于分子动理论的直接模拟Monte Carlo(DSMC)方法,研究了 Rayleigh-Bènard问题.计算中,上下平板表面温度之比固定为0.1.Kn=0.01时,随着Ra数的增大,大约在1700附近,流动从热传导状态转变为热对流状态,DSMC计算得到的下平板热流与Ra数的关系与经典实验和理论结果相符.Kn=0.05时,流动保持稳定的热传导状态,Ra数的增大并不能引发热对流现象.