Synthesis of Ruthenium Dioxide Nanoparticles by a Two-Phase Route and Their Electrochemical Properties

Dissolvable, size- and shape-controlled ruthenium dioxide nanoparticles are successfully achieved through a two-phase route. The influence of reaction time, temperature, and monomer concentration and the nature of capping agents on the morphologies of nanoparticles are studied through transmission electron microscopy (TEM). A possible mechanism for the formation and growth of nanoparticles is also involved. X-ray powder diffraction (XRD) confirms the amorphous structure for as-prepared ruthenium dioxide nanoparticles. Samples are immobilized by simple dip-coating on a current collector, and the cyclic voltammetry measurement is utilized to investigate their electrochemical properties. The specific capacitance of one sample can teach as high as 840 F g(-1), which reveals the promising application potential to electrochemical capacitors.

Electric characteristics of pseudo-spark during breakdown phase

An analysis of the time-dependent resistive voltage and power deposition during the breakdown phase of pseudo-spark is presented. The voltage and current were measured by specially designed low-inductance capacitive voltage divider and current measuring resistor. The measured waveforms of voltage and current are digitized and processed by a computer program to remove the inductive component, so as to obtain resistive voltage and power deposition. The influence of pressure, cathode geometry and charging voltage of storage capacitors on the electrical properties in the breakdown phase are investigated. The results suggest that the breakdown phase of pseudo-spark consists of three stages. The first stage is mainly hollow cathode discharge. In the second stage, field-enhanced thermionic emission takes place, resulting in a fast voltage drop and sharp rise of discharge current. The third stage of discharge depends simply on the parameters of the discharge circuit.

Quantum measurement characteristics of a double-dot single electron transistor

Owing to a few unique advantages, the double-dot single electron transistor has been proposed as an alternative detector for charge states. In this work, we present a further study for its signal-to-noise property, based on a full analysis of the setup configuration symmetry. It is found that the effectiveness of the double-dot detector can approach that of an ideal detector, if the symmetric capacitive coupling is taken into account. The quantum measurement efficiency is also analyzed by comparing the measurement time with the measurement-induced dephasing time.

圆柱受限空间内喷雾燃烧振荡特性研究=Investigation of the Characteristics of Thermal Instability in A Confined Combustor

本文研究了圆柱受限空间内的喷雾火焰嫩烧压力振荡的特性。为了更清楚地了解火焰的构造, 首先测量了火焰的温度场，在较大的一次风和二次风变化范围内, 测量了压力的振荡特性。结果表明，火焰的稳定是由回流区完成的, 在较小的一次风燃料当量比和中等的二次风量时, 振荡最强, 达到100Pa左右的量级,其频率为200-230Hz左右,分析表明燃烧室中的振荡是轴向驻波振荡。

Characteristics of Argon Laminar DC Plasma Jet at Atmospheric Pressure

利用特殊设计的等离子体发生器,选择等离子体产生的工艺参数,实现工艺过程的精确控制,在大气压环境下获得了性能稳定的氖气直流层流等离子体射流。与湍流等离子体射流长度较短、径向尺寸较大、工作噪音高等特点相比,层流等离于体射流长度可达到550mm,而且沿整个射流长度其径向尺寸维持不变,工作噪音很小。当气流量为120cm~3/s、弧电流在70-200A的范围时,射流长度随弧电流的增加而增加,热效率起初略有降低然后维持平稳。随气流量的增加,层流等离子体射流的热效率也增加,在弧电流为200A时,可以达到40%。实验中测

Dynamic Characteristics of Spherically Converging Detonation Waves

The spherically converging detonation wave was numerically investigated by solving the one-dimensional multi-component Euler equations in spherical coordinates with a dispersion-controlled dissipative scheme. Finite rate and detailed chemical reaction models were used and numerical solutions were obtained for both a spherical by converging detonation in a stoichiometric hydrogen-oxygen mixture and a spherically focusing shock in air. The results showed that the post-shock pressure approximately arises to the same amplitude in vicinity of the focal point for the two cases, but the post-shock temperature level mainly depends on chemical reactions and molecular dissociations of a gas mixture. While the chemical reaction heat plays an important role in the early stage of detonation wave propagation, gas dissociations dramatically affect the post-shock flow states near the focal point. The maximum pressure and temperature, non-dimensionalized by their initial value, are approximately scaled to the propagation radius over the initial detonation diameter. The post-shock pressure is proportional to the initial pressure of the detonable mixture, and the post-shock temperature is also increased with the initial pressure, but in a much lower rate than that of the post-shock pressure.

Characteristics of Micronozzle Gas Flows

The fluid characteristics of gas flows in the micronozzle whose throat height is 20 μm were investigated by the direct simulation Monte Carlo (DSMC) method. In a series of cases, the dependence of mass flux on the pressure difference was gained, and the DSMC's results show good agreement with the experimental data. The comparison of mass flux and the Mach number contours between the DSMC and Navier-Stokes equations adding slip boundary also reveals quantitatively that the continuum model will be invalid gradually even when the average Knudsen number is smaller than 0.01. As one focus of the present paper, the phenomenon of the multiple expansion-compression waves that comes from the nozzle's divergent part was analyzed in detailed.

Investigation of kerosene combustion characteristics with pilot hydrogen in model supersonic combustors

Experimental investigations on the ignition and combustion stabilization of kerosene with pilot hydrogen in Mach 2.5 airflows were conducted using two test combustors, with cross sections of 30.5 x 30 and 51 x 70 mm, respectively. Various integrated modules, including the combinations of different pilot injection schemes and recessed cavity flameholders with different geometries, were designed and tested. The stagnation pressure of vitiated air varied within the range of 1.1-1.8 NiPa, while the stagnation temperature varied from 1500 to 1900 K. Specifically, effects of the pilot hydrogen injection scheme, cavity geometry, and combustor scaling on the minimally required pilot hydrogen equivalence ratio were systematically examined. Results indicated that the cavity depth and length had significant effects on the ignition and flameholding, whereas the slanted angle of the aft wall was relatively less important. Two cavities in tandem were shown to be a more effective flameholding mechanism than that with a single cavity. The minimally required pilot hydrogen equivalence ratio for kerosene ignition and stable combustion was found to be as low as 0.02. Furthermore, combustion efficiency of 80% was demonstrated to be achievable for kerosene with the simultaneous use of pilot hydrogen and a recessed cavity to promote the ignition and global burning.

Modeling Study on the Characteristics of Laminar and Turbulent Argon Plasma Jets Impinging Normally upon a Flat Plate in Ambient Air

Modeling study is performed to compare the flow and heat transfer characteristics of laminar and turbulent argon thermal-plasma jets impinging normally upon a flat plate in ambient air. The combined-diffusion-coefficient method and the turbulence-enhanced combined-diffusion-coefficient method are employed to treat the diffusion of argon in the argon-air mixture for the laminar and the turbulent cases, respectively. Modeling results presented include the flow, temperature and argon concentration fields, the air mass flow-rates entrained into the impinging plasma jets, and the distributions of the heat flux density on the plate surface. It is found that the formation of a radial wall jet on the plate surface appreciably enhances the mass flow rate of the ambient air entrained into the laminar or turbulent plasma impinging-jet. When the plate standoff distance is comparatively small, there exists a significant difference between the laminar and turbulent plasma impinging-jets in their flow fields due to the occurrence of a large closed recirculation vortex in the turbulent plasma impinging-jet, and no appreciable difference is found between the two types of jets in their maximum values and distributions of the heat flux density at the plate surface. At larger plate standoff distances, the effect of the plate on the jet flow fields only appears in the region near the plate, and the axial decaying-rates of the plasma temperature, axial velocity and argon mass fraction along the axis of the laminar plasma impinging-jet become appreciably less than their turbulent counterparts.

Some characteristics of low-speed streaks under sheared air-water interfaces

The characteristics of low-speed fluid streaks occurring under sheared air-water interfaces were examined by means of hydrogen bubble visualization technique. A critical shear condition under which the streaky structure first appears was determined to be u(tau) approximate to 0.19 cm/s. The mean spanwise streak spacing increases with distance from the water surface owing to merging and bursting processes, and a linear relationship describing variation of non-dimensional spacing <(+)over bar> versus y(+) was found essentially independent of shear stress on the interface. Values of <(+)over bar>, however, are remarkably smaller than their counterparts in the near-wall region of turbulent boundary layers. Though low-speed streaks occur randomly in time and space, the streak spacing exhibits a lognormal probability distribution behavior. A tentative explanation concerning the formation of streaky structure is suggested, and the fact that <(+)over bar> takes rather smaller values than that in wall turbulence is briefly discussed.

Characteristics and Sub-Characteristics of Two-Dimensional Parabolized Stability Equations

特征分析表明：对原始扰动量的抛物化稳定性方程组(PSE),它在亚超音速区分别具有椭圆和抛物特性,给出PSE特征对马赫数的依赖关系,阐明PSE仅把信息对流-扩散传播特性抛物化,而保留了信息对流-扰动传播特性,因此PSE应称为扩散抛物化稳定性方程(DPSE)。

Characteristics of Gliding Arc Discharge Plasma

A gliding arc discharge plasma and its characteristics are described. Analysis on the production principle of the plasma is presented. Some experimental results about two novel types of the gliding arc plasma generator were obtained. These types of gliding arc plasma are potentially used in chemical industry and environment engineering.

Experimental Study on the Generation and Characteristics of Plasma Jets

报道热等离子体射流产生及射流特性的实验研究结果。。采用同一个直流等离子体发生器，工作气体流量小时产生出层流等离子体长射流，射流长度随气体流量或弧电流的增加而明显增加；工作气体流量大时则产生出湍流等离子体短射流，此时射流长度几乎与工作气体流量或弧电流无关；在层流与湍流等离子体射流工况之间，存在一个流动状况不稳定的过渡区，此时等离子体射流的平均长度随气流量的加大而减小，但随弧电流的加大而明显加大。层流等离子体长射流有相当好的刚性。