100 resultados para Al-c-o
em Chinese Academy of Sciences Institutional Repositories Grid Portal
Resumo:
Novel cemented carbides (W0.4Al0.6)C-0.5-Co With different cobalt contents were prepared by mechanical alloying and hot-pressing technique. Hot-pressing technique as a common technique was performed to fabricate the bulk bodies of the hard alloys. The novel cemented carbides have good mechanical properties compared with WC-Co. The density and operation cost of the novel material were much lower than the WC-Co system. It was easy to process submicroscale sintering with the novel materials and obtain the rounded particles in the bulk materials. There is almost no eta-phase in the (W0.4Al0.6)C-0.5-CO cemented carbides system although the carbon deficient obtains the astonishing value of 50%.
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The hydrolysis/precipitation behaviors of Al3+, Al-13 and Al-30 under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl3, PAC(A113) and PAC(A130) were 6.5-7.5, 8.5-9.5, and 7.5-9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl3 >> PAC(A130) > PACA113. The precipitates' size increased when the dosage increased from 50 mu M to 200 mu M, but it decreased when the dosage increased to 800 AM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The isoelectric points of the freshly formed precipitates for AlCl3, PAC(A113) and PAC(A130) were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl3 hydrolysis precipitates were lower than those of PAC(A113) and PAC(A130) when pH > 5.0. The Zeta potential of PAC(A130) hydrolysis precipitates was higher than that of PACA113 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al-Ferron research indicated that the hydrolysis precipitates of AlCl3 were composed of amorphous AI(OH)3 precipitates, but those of PACA113 and PACA130 were composed of aggregates of Al-13 and Al-30, respectively. Al3+ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al-13 and Al-30 species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al-Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al--Ferron method. The chemical composition of Al-a, Al-b and Al-c depended on coagulant and solution pH. The Al-b measured in the current case was different from Keggin Al-13, and the high Alb content in the AlCl3 hydrolysis precipitates could not used as testimony that most of the Al3+ Was converted to highly charged Al-13 species during AlCl3 coagulation.
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W1-xAlx (x=0-0.86) alloys were synthesized by mechanically alloying the pure metal powder mixtures at designated compositions by conventional high-energy ball milling. The W-Al alloys were stable under high pressure and high temperature. The alloys were lighter than W. The hardness and oxidation resistance of the alloys was greatly improved compared to both W and Al. (C) 2002 Elsevier Science B.V. All rights reserved.
Fracture Mechanisms And Size Effects Of Brittle Metallic Foams: In Situ Compression Tests Inside Sem
Resumo:
In situ compressive tests on specially designed small samples made from brittle metallic foams were accomplished in a loading device equipped in the scanning electron microscopy (SEM). Each of the small samples comprises only several cells in the effective test zone (ETZ), with one major cell in the middle. In such a system one can not only obtain sequential collapse-process images of a single cell and its cell walls with high resolution, but also correlate the detailed failure behaviour of the cell walls with the stress-strain response, therefore reveal the mechanisms of energy absorption in the mesoscopic scale. Meanwhile, the stress-strain behaviour is quite different from that of bulk foams in dimensions of enough large, indicating a strong size effect. According to the in situ observations, four failure modes in the cell-wall level were summarized, and these modes account for the mesoscopic mechanisms of energy absorption. Paralleled compression tests on bulk samples were also carried out, and it is found that both fracturing of a single cell and developing of fracture bands are defect-directed or weakness-directed processes. The mechanical properties of the brittle aluminum foams obtained from the present tests agree well with the size effect model for ductile cellular solids proposed by Onck et al. (C) 2008 Elsevier Ltd. All rights reserved.
Resumo:
本文对神农架地区广泛分布的米心水青冈林和锐齿槲栎林的种群和群落学特征、干扰历史、更新策略、生物量、生产量及元素循环特征进行了研究。得到如下结论: 1 米心水青冈林是神农架地区山地垂直分布的地带性植被类型,主要群落学特征为:(1)建群种明显,该区域主要有2种类型,即米心水青冈林和米心水青冈、锐齿槲栎林;(2)群落结构简单,但物种组成丰富,在6600m~2样地中出现高等植物(不含苔藓植物)77科150属271种,组成种类以蔷薇科、百合科、忍冬科、虎耳草科、樟科、杜鹃花科和壳斗科为主;(3)群落乔木层(占重要值的12%)和灌木层(占盖度的15%)中含有一定比例的常绿树种;(4)群落生活型以高位芽植物(70.89%)占绝对优势,其次为地面芽植物(15.50%)和地下芽植物(12.92%)。 2 米心水青冈是多主干的树种,萌枝现象普遍,但萌枝数量不同地点差异较大。通过萌枝产生的枝群体平均密度为257 ± 99.3n•hm~(-2)。枝群体的年龄结构表现为“幼龄个体数目较多型”和“中国年龄阶段数目较多型”,并且有较多的枝群体表现出一致的年龄结构。从整个群落米心水青冈的年龄结构来看,表现出发展型种群的特点。枝群体的分布格局为随机分布。9丛米心水青冈完整的年轮分析结果表明,它们萌枝的时间不是边疆的,而与森林的受干扰有关。根据83个圆盘和生长锥芯资料,米心水青冈在萌枝后成长为乔木层或林冠层的过程中,径向生长表现为5种模式。这是丛株内竞争的结果。萌枝在米心水青冈林的维持和发展过程中,具有重要的生态学作用。 3 锐齿槲栎林是神农架地区山地垂地分布的地带性植被类型,主要群落学特征为:(1)建群种明显,该区域主要有2种类型,即锐齿槲栎林和锐齿槲栎、米心水青冈林;(2)群落乔木层和灌木层中含有一定比例的常绿树种,和暖温带的落叶栎林有较大差异;(3)群落物种组成丰富,不仅具有典型的温带科属,还有典型亚热带分布的科属,组成种类主要以蔷薇科、百合科、忍冬科、虎耳草科、山茱萸科、杜鹃花科、壳斗科和樟科;(4)生活型以高位芽植物(66.32%)占绝对优势,其次为地面芽(23.51%)和地下芽(9.47%)植物。 4 通过样地调查、树干解析及直径分析法,对米心水青冈林和锐齿槲栎林受压和释压历史及更新策略进行了研究。米心水青冈直径生长表现为5种模式。而锐齿槲栎只表现为2种模式。85.9 ± 6.9%的米心水青冈有过受压过程,平均受压2.1 ± 0.8次,平均受压时间为47 ± 24.1a,最长受压时间73a,平均释压次数为1.6 ± 0.7次,平均释压时间为23 ± 21.5a,而60.83%的锐齿槲栎都均有1次受压。平均受压时间为19 ± 14a,受压后没有表现出释压过程。结合高生长和径向生长,认为米心水青冈是耐阴树种,它的更新策略是在林下形成苗性萌枝,在有林窗形成时释压生长进入乔木层;而锐齿槲栎是不耐阴树种,它的更新策略是通过产生大量种子,当有大的林窗时,幼苗在林窗内生长逐步进入乔木层。 5 神农架地区102-130a成熟米心水青冈林的生物量在251.31-358.63T•hm~(-2)之间,平均为288.70 ± 48.30T•~(-2),20-60a锐齿槲栎林群落生物量在134.85-301.20T•hm~(-2),平均为231.60 ± 78.10T•hm~(-2)。虽然米心水青冈林和锐齿槲栎林灌木层草本层及藤本植物组成很丰富,但二种类型森林生物量的95%以上集中在乔木层。乔木层生物量主要集中在少数优势种中。在米心水青冈林生物量从大到小的序列中,前5种植物分别占乔木层总生物量58.67%-96.37%不等,同样锐齿槲栎林前5种植物占群落生物量的68.13%-95.26%。常绿植物占乔木层生物量的比例变化较大,米心水青冈林中占2.85-18.70%,锐齿槲栎林中一般常绿植物占0.8-9.98%,只有1个锐齿槲栎林样地常绿植物(主要是粉白杜鹃)占乔木层生物量的44.04%。米心水青冈林生物量根冠比为0.27 ± 0.05,锐齿槲栎林为0.21 ± 0.06。神农架地区米心水青冈林的生物量,在成熟的欧洲水青冈林及日本的水青冈林生物量范围之内,而锐齿槲栎林生物量远远大于我国温带落叶栎林的生物量。 6 神农架地区102-130a米心水青冈林生产量范围在1857-2786g•m~(-2)•a~(-1),平均为2330 ± 397 g•m~(-2)•a~(-1)。20-60a锐齿槲栎林的生产量范围在1319-2521 g•m~(-2)•a~(-1),平均为1930 ± 498 g•m~(-2)•a~(-1)。米心水青冈林和锐齿槲栎林乔木层生产量占群落总生产量的95%以上,乔木层各器官生产量大小顺序为叶> 树干> 枝和根,其中叶生产量占乔木层的一半以上,达53.87 ± 2.72%(米心水青冈林)和57.31 ± 6.23%(锐齿槲栎林)。在乔木层生产量从大到小的序列中,前5种植物平均占乔木层总生产量的81.03 ± 13.94%(米心水青冈林,范围在62.75%-92.66%)和84.23 ± 9.68%(锐齿槲栎林,范围在68.54-95.11%)。米心水青冈林和锐齿槲栎林群落地下部分生产量占总生产量的比例分别为11.29 ± 1.02%和9.22 ± 2.72。和我国其它地区地带性植被类型相比。米心水青冈林和锐齿槲栎生产量是较高的,和亚热带绿阔叶林生产量接近,但在器官分配上两者差异较大。 7 米心水青冈林和锐齿槲栎林土壤均呈酸性。其中锐齿槲栎林地土壤酸性更强。土壤元素特征表现为Al>C>K>Mg>Ca>N>S、P的特点,富铝化作用明显。8种元素在群落优势植物不同部位含量差异较大,N、P、K、Ca、Mg基本上是以叶片含量最高,树干或根中最低。仅从叶片来看,元素特征表现为C>Ca、N>K>Mg>S>P、Al。优势植物的C/N和C/P显著高于暖温带落叶阔叶林优势植物。8种元素在米心水青冈林和锐齿槲栎林中积累量分别为147.09 ± 25.60和116.00 ± 37.63 Mg hm~(-2)a~(-1),其中97%以上积累在群落乔木层。两种森林类型各元素的积累量都表现为C>Ca, N> K> Mg> P> S> Al的特点。米心水青风林和锐齿槲栎林8种元素的年存留量分别为6263 ± 90.8和5946 ±246 kg hm~(-2)a~(-1),其中N、P、K、Ca、Mg 5种主要营养元素的存留量分别为179.7 ± 18.2和169.4 ± 23.5kg hm~(-2) a~(-1)。两种森林类型各元素的存留量都表现为C> N> Ca> K> Mg> S> P> Al。
Resumo:
Six-period 4 nm GaN/10 nm AlxGa1-xN superlattices with different Al mole fractions x were prepared on (0001) sapphire substrates by low-temperature metal-organic chemical vapor deposition. The linear electro-optic (Pockels) effect was studied by a polarization-maintaining fiber-optical Mach-Zehnder interferometer system with an incident light wavelength of 1.55 mu m. The measured electro-optic coefficients, gamma(13)=5.60 +/- 0.18 pm/V, gamma(33)=19.24 +/- 1.21 pm/V (for sample 1, x=0.3), and gamma(13)=3.09 +/- 0.48 pm/V, gamma(33)=8.94 +/- 0.36 pm/V (for sample 2, x=0.1), respectively, are about ten times larger than those of GaN bulk material. The enhancement effect in GaN/AlxGa1-xN superlattice can be attributed to the large built-in field at the interfaces, depending on the mole fraction of Al. (C) 2007 American Institute of Physics.
Resumo:
In scattering calculations using the T-matrix method, the calculation of the T-matrix involves multiplication and inversion of matrices. These two types of matrix operations are time-consuming, especially for the matrices with large size. Petrov et al. [D. Petrov, Y. Shkuratov, G. Videen, Opt. Lett. 32 (2007) 1168] proposed an optimized matrix inversion technique, which suggests the inversion of two matrices, each of which contains half the number of rows. This technique reduces time-consumption significantly. On the basis of this approach, we propose another fast calculation technique for scattering in the T-matrix method, which obtains the scattered fields through carrying out only the operations between matrices and the incident field coefficient. Numerical results show that this technique can decrease time-consumption by more than half that of the optimized matrix inversion technique by Petrov et al. (c) 2008 Elsevier B.V. All rights reserved.
Resumo:
贮氢合金是镍一金属氢化物电池的核心材料,其综合性能的改善是提高镍一金属氢化物电池性能的关键。本研究以探索镍一金属氢化物电池新型负极材料为目的,以非ABS型贮氢合金为研究对象,采用X射线衍射、Rietveld分析、恒电流充/放电、P-C-T曲线及线性微极化等方法,从基础和潜在应用等方面详细研究了非ABS型合金的结构与电化学性能。对La-Ni体系中非ABS型二元合金的结构和电化学性能的研究表明,LaNi_(228)具有最优异的高倍率充电性能;La_2Ni_7合金电极的高倍率放电性能最佳;La_7Ni_3在低温条件下表现出较好的放电性能。然而,所有得到的La-Ni合金电极容量远低于其理论容量。因此,必须通过进一步研究,如元素取代、热处理、表面处理等来提高其电化学容量。对RENi_3(RE=La,Ce,Pr,Nd,Sm,Gd,Th,Dy,Ho,Er,Y)研究表明:YNi_3合金因其具有最大的晶胞体积,最小的密度,而表现出最好的高倍率充/放电性能及低温放电性能,但其高温放电性能需要进一步提高,以满足实际应用的要求。用Al、Mn、Ti、Fe、Sn、Si、Cr、M。、Cu和Co十种元素取代Ni进行了大量的配方筛选工作。得到了大量的实验数据,并发现LaNi_(3.7)Al_(0.3)合金电极电化学放电容量最高,达290.8mAh/g;LaNi_(3.7)Mo_(0.3)合金电极的高倍率放电性能最好,在以4200mA/g的电流密度下进行放电时,其放电容量仍达到145.8mA/g;而I镍一金属氢化物电池新型负极材料研究镍一金属氢化物电池新型负极材料的研究Al的取代会使合金电极性能对温度不敏感。以我们的实验为基础,进一步进行合金配方的微调,具有可能开发出具有实用价值的贮氢合金的潜力。在Ar保护下用真空电弧炉熔炼合成了四种Lal一xMg:(NICoAI)3.6体系贮氢合金,制成姐卜Ni电池负极,通过恒电流充/放电方法研究了其电化学性能。结果表明:Lal一xMg:(NiCoAI)3.6体系金属氢化物电极较容易活化,室温下具有优异的高倍率放电性能,在以4200mA/g电流放电时,La卜汉gx(NICoAI)36合金电极的放电容量是ABS型合金电极的3倍,达152hah/g,显示出良好的动力学特性。R,入1兮Ni(R:raree田劝,Ca,Y)型合金因能吸引/释放1.8一1.87%质量的HZ而被认为是种很有希望的贮氢合金。但其吸/放氢平台过高,循环寿命短。如何提高Rh厦g剑19循环稳定性是这类合金能否成功商业化的关键。研究发现,Co能够显著提高ABS型合金电极的循环寿命,但其价格太贵。人们发现Al在提高电极寿命方面与C。有类似的作用,但Al元素的添加因其在碱性电解质的作用下在电极表面易生成致密的氧化膜而不利于氢的扩散,进而对高倍率放电性能不利。入物在提高电极表面活性,改善其高倍率放电性方面作用明显。本工作在前面的基础上用Al和MO联合取代Ni,以期待同时改善La一Mg一Ni一Co合金的循环稳定性和高倍率放电性能。详细研究了La07Mg03Ni切一(A105Mo05)x(x:o,0.2,0.4,0.6,0.8)系列贮氢合金的晶体结构和电化学性能。X射线衍射及Rietveld分析发现:所有La07Mg03Ni4D一x(A105Mo05)x合金均为包含PuNi3结构的六方LaZMgNig相、CaCus结构的LaNis主相及L匆Ni7,LaN儿和LaNi杂相的多相结构。合金中La(La,Mg)剑19相及LaNis相的晶格参数及晶胞体积均随合金中Al和Mo含量的增加而增大。用电化学方法测得的RC一T曲线显示:Al和'fo部分取代Ni降低了氢的平台压力。随合金中Al和Mo含量的增加,电极的电化学容量从329.7(x=0)、徽橇毓孺鑫盆一11瀚加至365.物A吨(=0.6)后又降低到351.3毗吨(x=0.8)。当以1200m刀g的电流密度进行放电时,其I{RD从62.0%沁0)增加到82.1%沁0.8)。线性微极化结果显示:Al和Mo的添加增大了合金表面的交换电流密度,因而也改善了合金电极的高倍率放电性能。另外,Al和M。取代合金中的Ni增大了氢在电极合金中的扩散系数(D),改善了La07Mgo3Ni4。一x(Alo5M。。5)x(X=o,0.2,0.4,0.6,0.8)合金电极的低温放电性能(LTD)。
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制备了3种结构的器件:A:ITO/SiO2/Alq3/Al,B:ITO/Alq3/SiO2/Al,C:ITO/SiO2/Alq3/SiO2/Al。对于器件A和B,在正向偏压(ITO接正极)下才能观察到发光;而对于器件C,在正向和反向偏压下都可以观察到发光。随着电压升高,器件B和C产生的蓝色发光相对绿光逐渐增强。这主要是由于SiO2中的加速电子碰撞激发Alq3发光层产生热电子,并与空穴形成电子空穴对,复合产生蓝光;而对于器件A,在反向偏压下被热电子碰撞激发出的空穴与正向偏压下从Al电极进入的电子复合形成激子,产生绿色发光。这些结构的器件发光不但可来源于电子与积累的空穴复合,而且也来自固态阴极射线发光。
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Geometry optimization and harmonic vibrational frequency calculations have been performed on the (X) over bar (2)A(1) state of NO2 and (X) over bar (1)A(1) state of NO2-. Franck-Condon analyses and spectral simulations were carried out on the NO2((X) over bar (2)A(1))-NO2-((X) over bar (1)A(1)) photo detachment process. In addition, the equilibrium geometry parameters, r(NO)= 1.248 +/- 0.005 Angstrom and angle(ONO) 116.8 +/- 0.5degrees, of the (X) over bar (1)A(1) state of NO2-, are derived by employing an iterative Franck-Condon analysis procedure in the spectral simulation. Our conclusions regarding the anion geometry suggest a reinterpretation of the results of Woo et al. (C) 2004 Published by Elsevier B.V.
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比较系统地研究了 AB2 型 Laves相合金 Zr0 .9Ti0 .1Ni0 .1Mn0 .7V0 .3 M0 .1( M=None,Ni,Mn,V,Co,Cr,Al,Fe,Mo,Si,C,Zn,Cu和 B)的相结构和电化学性能以及高温和低温放电性能等 .结果表明 ,1 4种合金均具有六方 C1 4型 Laves相的主相晶体结构 ,同时 ,含有少量立方 C1 5型 Laves相和一些由 Zr.9Ni11及 Zr Ni组成的非 Laves相 ;添加 V和 Mn可提高 AB2 合金的放电容量 ;添加 B和 Mn则显著提高了 AB2 合金的高倍率放电性能和低温放电容量 ;添加 Al,C,Si和 Co对合金电极的循环稳定性改善明显 ;而 Mn,Ni,V,Fe,Cu,Mo和 B等却不同程度地降低了循环稳定性 ;添加 Si,Mo,V,Cr和 Al可明显改善合金电极的自放电性能 ;添加 Si,Cr,V可显著改善 AB2 合金电极的高温放电性能 .讨论了各种添加元素影响合金性能的可能原因.
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alpha-Al2O3:C crystal shows excellent thermoluminescence (TL) and optically stimulated luminescence (OSL) properties but the real role carbon plays in this crystal is still not clearly understood so far. In this work, alpha-Al2O3:C crystal doping with different amounts of carbon were grown by the temperature gradient technique, and TL and OSL properties of as-grown crystals were investigated. Additionally, a mechanism was proposed to explain the role of carbon in forming the TL and OSL properties of alpha-Al2O3:C. TL and OSL intensities of as-grown crystals increase with the increasing amount of carbon doping in the crystal, but no shift is found in the glow peak location at 465 K. As the amount of carbon doping in the crystals decreases, OSL decay rate becomes faster. With the increase in heating rate, the integral TL response of as-grown crystals decreases and glow peak shifts to higher temperatures. TL response decrease rate increases with the increasing amount of carbon doping in the crystals. All the TL and OSL response curves of as-grown crystals show linear-sublinear-saturation characteristic, and OSL dose response exhibits higher sensitivity and wider linear dose range than that of TL. The crystal doping with 5000 ppm carbon shows the best dosimetric properties. Carbon plays the role of a dopant in alpha-Al2O3:C crystal and four-valent carbon anions replace the two-valent anions of oxygen during the crystal growth process, and large amounts of oxygen vacancies were formed, which corresponds to the high absorption coefficient of F and F+ centers in the crystals.
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The thermal stability of Nd60Fe20Co10Al10 bulk metallic glass (BMG) has been studied by differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), isochronal dilatation and compression tests. The results show that the glass transition of the BMG takes place quite gradually between about 460 and 650 K at a heating rate of 0.17 K/s. Several transformation processes are observed during continuous heating with the first crystallization process beginning at about 460 K, while massive crystallization takes place near the solidus temperature of the alloy. The positive heat of mixing between the two major constituents, Nd and Fe, and, consequently, a highly inhomogeneous composition of the attained amorphous phase are responsible for the anomalous thermal stability in this system. (C) 2002 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved.
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The aim of this study was to investigate the effect of temperature on tribological properties of plasma-sprayed Al-Cu-Fe quasicrystal (QC) coating after laser re-melting treatment. The laser treatment resulted in a more uniform, denser and harder microstructure than that of the as-sprayed coatings. Tribological experiments on the coatings were conducted under reciprocating motion at high frequency in the temperature range from 25 to 650 degreesC. Remarkable influence of temperature on the friction behavior of the coating was recorded and analyzed. Microstructural analysis indicated that the wear mechanisms of the re-melted QC coatings changed from abrasive wear at room temperature, to adhesive wear at 400 degreesC and severe adhesive wear at 650 degreesC owing to the material transfer of the counterpart ball. It was also observed that the ratio of the icosahedral (i)-phase to beta-Al-50(Fe,CU)(50) phase in the coating was higher after test at 400 'C than that at 650 'C. The variation of the ratio UP of coating and of the property of the counterpart ball and coating with the temperature are the two main factors influencing the wear mechanisms and value of the friction coefficient.
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Anodic bonding of Pyrex glass/Al/Si is an important bonding technique in micro/nanoelectromechanical systems (MEMS/NEMS) industry. The anodic bonding of Pyrex 7740 glass/Aluminum film/Silicon is completed at the temperature from 300 degrees C to 375 degrees C with a bonding voltage between 150 V and 450 V. The fractal patterns are formed in the intermediate Al thin film. This pattern has the fractal dimension of the typical two-dimensional diffusion-limited aggregation (2D DLA) process, and the fractal dimension is around 1.7. The fractal patterns consist of Al and Si crystalline grains, and their occurrences are due to the limited diffusion, aggregation, and crystallization of Si and Al atoms in the intermediate Al layers. The formation of the fractal pattern is helpful to enhance the bonding strength between the Pyrex 7740 glass and the aluminum thin film coated on the crystal silicon substrates.