Phase transition and transition kinetics of a thermotropic poly(amide-imide) derived from 70% pyromellitic dianhydride, 30% terephthaloyl chloride, and 1,3-bis[4-(4 '-aminophenoxy)cumyl]benzene

The phase transition and transition kinetics of a liquid crystalline copoly(amide-imide) (PAI37), which was synthesized from 70 mol% pyromellitic dianhydride, 30 mol% terephthaloyl chloride, and 1,3-bis[4-(4'-aminophenoxy)cumyl]benzene, was characterized by differential scanning calorimetry, polarized light microscopy, X-ray diffraction, and rheology. PAI37 exhibits a glass transition temperature at 182 degreesC followed by multiple phase transitions. The crystalline phase starts to melt at similar to 220 degreesC and forms smectic C (S-C) phase. The Sc phase transforms into smectic A (S-A) phase when the temperature is above 237 degreesC. The S-C to S-A transition spans a broad temperature range in which the S-A phase vanishes and forms isotropic melt. The WARD fiber pattern of PAI37 pulled from the anisotropic melt revealed an anomalous chain orientation, which was characterized by its layer normal perpendicular to the fiber direction. The transition kinetics for the mesophase and crystalline phase formation was also studied.

Green synthesis of nanowire-like Pt nanostructures and their catalytic properties

We reported a simple and effective green chemistry route for facile synthesis of nanowire-like Pt nanostructures atone step. In the reaction, dextran acted as a reductive agent as well as a protective agent for the synthesis of Pt nanostructures. Simple mixing of precursor aqueous solutions of dextran and K2PtCl4 at 80 degrees C could result in spontaneous formation of the Pt nanostructures. Optimization of the experiment condition could yield nanowire-like Pt nanostructures at 23:1 molar ratio of the dextran repeat unit to K2PtCl4.

Synthesis and chirooptical properties of optically active poly(ester imide)s based on axially asymmetric 1,1 '-binaphthyls

A series of optically active poly(ester imide)s (PEsI's) has been synthesized by the polycondensation reactions of new axially asymmetric dianhydrides, that is, (R)-2,2'-bis(3,4-dicarboxybenzoyloxy)-1,1'-binaphthyl dianhydride and (S)-2,2'-bis(3,4-dicarboxybenzoyloxy)-1,1'-binaphthyl dianhydride, and various diamines with aromatic, semiaromatic, and aliphatic structures. The polymers have inherent viscosities of 0.45-0.70 dL/g, very good solubility in common organic solvents, glass-transition temperatures of 124-290 degreesC, and good thermal stability. Wide-angle X-ray crystallography of these polymers shows no crystal diffraction. In comparison with model compounds, an enhanced optical rotatory power has been observed for the repeat unit of optically active PEsI's based on aromatic diamines, and it has been attributed to a collaborative asymmetric perturbation of chiral 1,1'-binaphthyls along the rigid backbones.

Gas transport properties of a series of cardo polyarylethers

Gas transport of H-2, CO2, O-2, N-2, and CH4 in a series of cardo polyarylethers were examined over a temperature range of 30 similar to 100 degreesC. These polymers include three poly(aryletherketone)s, two poly(arylethersulfone)s, and one poly(aryletherketoneketone). It was found that the large length/diameter ratio of the polymer repeat unit for cardo polyaryletherketoneketone (PEKK-C) and strong intermolecular interaction in hydrogen-bonded polyarylethersulfone (PES-H) and hydrogen-bonded polyaryletherketone (PEK-H) resulted in a considerable increase in gas permselectivity. Alkyl-substituted polyaryletherketone (PEK-A), bearing a pendant bulky propyl group on the cardo ring, simultaneously exhibited 62.5% higher H-2 permeability and 59.8% higher H-2/N-2 permselectivity than unmodified poly(aryletherketone) (PEK-C). The causes of the trend were interpreted in terms of chain packing density, segmental motion ability, steric factor, and intermolecular interaction of polymers, together with gas kinetic diameter and critical temperature data.

A study of the crystallographic equivalence of ether and ketone groups in poly(aryl ether ketone)s

Crystallographic equivalence of ether and ketone in all para-substituted PAEKs crystallized in form I was discussed in this paper. In a word, crystallographic equivalence between ether and ketone groups is tenable when polymer contains only phenyl rings in the repeat unit. If a polymer contains a diphenyl group in the repeat unit, two cases should be distinguished. In the case of PEDEKK and PEEKDK, crystallographic equivalence between ether and ketone linkages is untenable, However, in the case of PEDK and PEDEKDK, crystallographic equivalence between ether and ketone linkages is still tenable.

Poly(phenylene sulfide-tetraaniline): The soluble conducting polyaniline analogue with well-defined structures

A novel conducting polymer poly(phenylene sulfide-tetraaniline) (PPSTEA), with tetraaniline (TA) and phenylene sulfide (PS) segments in its repeat unit, has been synthesized through an acid-induced polycondensation reaction of 4-methylsulfinylphenyl-capped tetraaniline. The new polymer, which represents the first soluble conducting polyaniline analogue with well-defined structure, has high molecular weight, good solubility in common solvents, and good film-forming properties. Its electrical property is analogous to polyaniline. The conductivity of preliminarily, protonic-doping PPSTEA is up to 10 degrees S/cm. This synthetic strategy appears to be general for developing novel well-defined polyaniline analogue containing much longer fixed conjugation length.

Variation of crystallographic parameters in PEEKK with heat treatment temperature

Using the wide-angle X-ray diffraction method, the variation of crystallographic parameters of poly(aryl ether ether ketone ketone) (PEEKK) has been studied in different heat treatment temperatures. All the reflections and their intensities as well as their Miller indices are presented in detail according to an orthorhombic system. The investigation indicates that the unit cell parameters a, b, c and the unit cell volume V systematically decrease with increasing heat treatment temperature. This variation is interpreted by the change of conformation of polymer molecular chains during thermal treatment. The results calculated from the formula of degree of crystallinity (W-c,W-x) for PEEKK, which was derived based on X-ray scattering intensity theory and the graphic multipeak resolution method, are compatible with the density measurement (W-c,W-d) and calorimetry (W-c,W-h) values. (C) 1997 Elesevier Science Ltd.

Analysis of tandem repeats in the genome of Chinese shrimp Fenneropenaeus chinensis

Through random sequencing, we found a total of 884000 base-pairs (bp) of random genomic sequences in the genome of Chinese shrimp (Fenneropenaeus chinensis). Using bio-soft Tandem Repeat Finder (TRF) software, 2159 tandem repeats were found, in which there were 1714 microsatellites and 445 minisatellites, accounting for 79.4% and 20.6% of repeat sequences, respectively. The cumulative length of repeat sequences was found to be 116685 bp, accounting for 13.2% of the total DNA sequence; the cumulative length of microsatellites occupied 9.78% of the total DNA sequence, and that of minisatellites occupied 3.42%. In decreasing order, the 20 most abundant repeat sequence classes were as follows: AT (557), AC (471), AG (274), AAT (92), A (56), AAG (28), ATC (27), ATAG (27), AGG (18), ACT (15), C (11), AAC (11), ACAT (11), CAGA (10), AGAA (9), AGGG (7), CAAA (7), CGCA (6), ATAA (6), AGAGAA (6). Dinucleotide repeats, not only in the aspect of the number, but also in cumulative length, were the preponderant repeat type. There were few classes and low copy numbers of repeat units of the pentanucleotide repeat type, which included only three classes: AGAGA, GAGGC and AAAGA. The classes and copy numbers of heptanucleotide, eleven-nucleotide and thirteen-nucleotide primer-number-composed repeats were distinctly less than that of repeat types beside them.

油气勘探中的弱磁异常提取与区域场分析

Petroleum and natural gas is an important strategic resources. The short of the reserves will block the development of economy and threaten the safety of nation, along with the main oil fields of our country coming to the height of power and splendor of the exploitation and exploration. Therefore, it makes a great sense to inaugurate new explorative field and increase the reserves of petroleum and natural gas. Magnetic exploration is a main method of geophysics exploration. the developing observation apparatus and the perfect processing method provide wide space for magnetic exploration in these years. The method of magnetic bright spot is an application of magnetic exploration. The vertical migration of the hydrocarbon changes physical and chemical environment above the hydrocarbon reservoir, the new environment make tervalent iron translate into bivalent iron, that produce small scale magnetic anomaly, that is magnetic bright spot. The method of magnetic bright spot explores oil and gas field by the relation between the hydrocarbon and magnetic anomaly. This paper systemically research to pick-up and identify magnetic bright spot combining an oil field item, then point out advantaged area. In order to test the result, the author use the seismic information to superpose the magnetic bright spot, that prove the magnetic bright spot is reliable. then, the author complete a software to pick and identify the magnetic bright spot. The magnetic basement is very important to research forming and evolvement of the basin, especially, it is a crucial parameter of exploring residual basin in the research on pre-Cenozoic residual. This paper put forward a new method to inverse the interface of the magnetic layer on the basis of previous work, that is the method of separation of magnetic field step by step. The theory of this method is to translate the result of magnetic layer fluctuation to the result of magnetization density change, and the magnetic layer is flat, the paper choose thickness of magnetic layer as unit thickness, and define magnetic layer as a unit-thickness layer in order to convenient calculation, at the same time, define the variational magnetization density as equivalent magnetic density. Then we translate the relation between magnetic field and layer fluctuation to the relation between magnetic field and equivalent magnetic density, then, we can obtain the layer fluctuation through calculating equivalent magnetic density. Contrast to conventional parker method, model experimentation and example checkout prove this method is effective. The merit of this method is to avoid flat result in a strongly fluctuant area because of using a uniform average depth, the result of this method is closer to the fact, and this method is to inverse equivalent magnetic density, then translate equivalent magnetic density to layer fluctuation, this lays a foundation to inverse variational magnetic density in the landscape orientation and portrait.

Direct Numerical Simulation of a Spatially Evolving Supersonic Turbulent Boundary Layer at Ma=6

Direct numerical simulation is carried out for a spatially evolving supersonic turbulent boundary layer at free-stream Mach number 6. To overcome numerical instability, the seventh-order WENO scheme is used for the convection terms of Navier-Stokes equations, and fine mesh is adopted to minimize numerical dissipation. Compressibilty effects on the near-wall turbulent kinetic energy budget are studied. The cross-stream extended self-similarity and scaling exponents including the near-wall region are studied. In high Mach number flows, the coherence vortex structures are arranged to be smoother and streamwised, and the hair-pin vortices are less likely to occur.

Dns Of Compressible Turbulent Boundary Layer Around A Sharp Cone

Direct numerical simulation of the turbulent boundary layer over a sharp cone with 20 degrees cone angle (or 10 degrees half-cone angle) is performed by using the mixed seventh-order up-wind biased finite difference scheme and sixth-order central difference scheme. The free stream Mach number is 0.7 and free stream unit Reynolds number is 250000/inch. The characteristics of transition and turbulence of the sharp cone boundary layer are compared with those of the flat plate boundary layer. Statistics of fully developed turbulent flow agree well with the experimental and theoretical data for the turbulent flat-plate boundary layer flow. The near wall streak-like structure is shown and the average space between streaks (normalized by the local wall unit) keeps approximately invariable at different streamwise locations. The turbulent energy equation in the cylindrical coordinate is given and turbulent energy budget is studied. The computed results show that the effect of circumferential curvature on turbulence characteristics is not obvious.

High efficiency tandem organic light-emitting devices with Al/WO3/Au interconnecting layer

An interconnecting layer of Al (2 nm)/WO3 (3 nm)/Au (16 nm) was studied for application in tandem organic light-emitting devices. It can be seen that the Al/WO3/Au structure plays the role of an excellent interconnecting layer. The introduction of WO3 in the connection unit significantly improves the device efficiency as compared to the case of Al/Au. Thus, the current efficiency of the two-unit tandem devices is enhanced by two factors with respect to the one-unit devices. The green two-unit tandem device of indium tin oxide/MoO3/4,4(')-N,N-'-bis[N-(1-naphthyl)-N-phenyl-amino]biphenyl(NPB)/tris(8-hydroxylquinoline) aluminum (Alq(3)):10-(2-benzothiazolyl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]benzopyrano[6,7,8-ij]quinolizin-11-one (C545T)/Alq(3)/LiF/Al/WO3/Au/MoO3/NPB/Alq(3):C545T/Alq(3)/LiF/Al showed a maximum current efficiency of 33.9 cd/A and a power efficiency of 12.0 lm/W.

Phase identification in a series of liquid crystalline TPP polyethers and copolyethers having highly ordered mesophase structures. 6. Structure changes from smectic to columnar phases in a series of copolyethers containing odd and even numbers of methylene units in equal molar composition

A series of liquid crystalline copolyethers has been synthesized from 1-(4-hydroxy-4'-biphenyl)-2-(4-hydroxyphenyl)propane and different alpha,omega-dibromoalkanes [coTPP(n/m)]. In this report, coTPPs having n = 5, 7, 9, 11 and m = 12 are studied, which represent copolyethers having both varying odd number and a fixed even number of methylene units. The compositions were fixed at an equal molar ratio (50/50). These coTPPs(nlm) show multiple phase transitions during cooling and heating in differential scanning calorimetry experiments. The undercooling dependence of these transitions is found to be small, indicating that these transitions are close to equilibrium, Although the coTPPs possess a high-temperature nematic (N) phase, the periodicity order along the chain direction is increasingly disturbed when the length of the odd-numbered methylene units decreases from n 11 to 5. in the coTPPs(5/12, 7/12, and 9/12), wide-angle X-ray diffraction experiments at different temperatures show that, shortly after the N phase formation during cooling, the lateral molecular packing improves toward a hexagonal lattice, as evidenced by a gradual narrowing of the scattering halo. This process represents the possible existence of an exotic N phase, which serves as a precursor to the columnar (Phi(H)) phase. A further decrease in temperature leads to a (PH phase having a long-range ordered, two-dimensional hexagonal lattice. In coTPP(11/12), the phase structures are categorized as highly ordered and tilted, smectic and smectic crystal phases, similar to homoTPPs, such as the smectic F (S-F) and smectic crystal G (SCG) phases. An interesting observation is found for coTPP(9/12), wherein a structural change from the high-temperature Phi(H) phase to the low-temperature S-F phase occurs. It can be proven that, upon heating, the well-defined layer structure disappears and the lateral packing remains hexagonal. The overall structural differences in this series of coTPPs between those of the columnar and highly ordered smectic phases are related to the disorders introduced into the layer structure by the dissimilarity of the methylene unit lengths in the comonomers.

孤岛油田中二北区Ng3～6储层建筑结构与油水分布规律研究

The reservoir of Zhongerbei region in Gudao Oilfield is a typical fluvial facies deposit, its serious heterogeneity of the reservoir caused the distribution of remaining oil in mature reservoirs is characterized by highly scattered in the whole field, and result to declination of production, tap potential and stabilize production is more difficult. Reservoir modeling based on lay scale can not fulfill requirement. How to further studied reservoir heterogeneity within the unit and establish the finer reservoir modeling is a valid approach to oil developing. The architectural structure elements analysis is the effectively method to study reservoir heterogeneity. Utilize this method, divide the reservoirs of Gudao Oilfield into ten hierarchies. The priority studying is sixth, seven hierarchies, ie single sand layers sand bodies By the identification of sixth, seven hierarchies, subdivide the reservoir to the single genetic unit. And to subdivide by many correlation means, such as isometry and phase transition, accomplish closure and correlation of 453 wells.Connectting fluvial deposit pattern, deposition characteristic with its log, build the inverting relation between “sedimentary facies” and “electrofacies” The process emphasize genetic communication and collocation structure of genetic body in space. By detailed architecture analyses sandbodies’ structure, this paper recognize seven structure elements, such as major channel, abandoned channel, natural levee, valley flat, crevasse splay, crevasse channel and floodplain fine grain.Combination identification of architectural structure elements with facieology and study of deposition characteristic, can further knowing genesis and development of abandoned channel. It boost the accuracy to separation in blanket channel bodies distribution, and provide reference to retrieving single channel boundary. Finally, establish fine plane and section construction. On basis architectural structure map, barrier beds and interbeds isopach map and mini-structure map, considering single thin layers to be construction unit, the main layer planimetric maps have drawn and the inner oil-water boundary have revealed. All account that architectural structure elements control remaining oil distribution in layer, and develop the study on architectural structure elements to direct horizontal well is succesful.