Synthesis, crystal structure, and thermal property of a novel supramolecular assembly: (NH42810424)(CHNO) O-[H(V)O(]2H)4(10)28(2), constructed from decavanadate and caffeine

A novel 3D supramolecular assembly constructed from decavanadate and caffeine building blocks, (NH4)(2)(C8H10N4O2)(4)[H4V10O28].2H(2)O (1), has been synthesized in aqueous solution and characterized by elemental analysis, IR, H-1 NMR, V-51 NMR, TG-DTA, and single crystal X-Ray diffraction. The compound 1 crystallizes in monoclinic system, space group P2(1)/n, a = 15.801(1) Angstrom, b = 12.914(1) Angstrom, c = 15.913(2) Angstrom, beta = 113.55degrees, V = 2976.4 (5) Angstrom(3), Z = 2, R = 0.0498 with 6818 reflections. Water molecules, ammonium ions, and caffeine act as "cement" linking the polyanions into 1D chain along the c-axis by hydrogen bonding. In compound 1, extensive hydrogen-bond contacts and strong pi-pi interactions lead to an ordered 3D supramolecular framework. TG-DTA curves indicate that the weight loss of the complex can be divided into three stages.

对达曼光栅进行二维扩展的矩形孔径光栅设计

介绍一种二元光学元件的设计方法.为了克服达曼光栅在二维设计上的局限性,采取均匀采样的矩形孔径编码方式进行优化设计.结果表明:与达曼光栅相比,不仅可将总衍射效率提高10%以上,还可得到更多样的二维设计图样,只是输出点阵均匀度略低于达曼光栅.因此,在均匀度要求不太高的高强光束变换中,这种二值型位相光栅的设计方法对于设计二维衍射图样十分简便有效,且其计算结果易于加工制作,具有很高的应用价值.

p Dissipative operator

In this paper the authors prove that the generalized positive p selfadjoint (GPpS) operators in Banach space satisfy the generalized Schwarz inequality, solve the maximal dissipative extension representation of p dissipative operators in Banach space by using the inequality and introducing the generalized indefinite inner product (GIIP) space, and apply the result to a certain type of Schrodinger operator.

Static and fatigue failure behavior of carbon-fiber reinforced epoxy composite-materials with edge notch

A study of carbon fiber reinforced epoxy composite material with 0° ply or ±45°ply(unnotched or with edge notch) was carried out under static tensile and tension-tensioncyclic loading testing. Static and fatigue behaviour and damage failure modes in unnotched/notched specimens plied in different manners were analysed and compared with each other.A variety of techniques (acoustic emission, two types of strain extensometer, high speed pho-tography, optical microscopy, scanning electron microscope, etc.) were used to examine thedamage of the laminates. Experimental results show that when these carbon/epoxy laminateswith edge notch normal to the direction of the load are axially loaded in static or fatiguetension, the crack does not propagate along the length of notch but is in the interface (fiberdirection). The notch has no substantial effect on the stresses at the unnotched portion. Thedamage failure mechanism is discussed.

在役设备材料弹塑性力学参数测定方法综述——小冲杆实验力学研究进展之一

20多年以来,采用小型试件的小冲杆试验技术来测量在役设备材料的各种力学参数已经取得了很大进展,这个方法已经用来确定材料的弹性模量、屈服强度、塑性性能、抗拉强度、韧-脆转变温度、断裂韧度、蠕变性能和黏塑性性能等各种力学性能。由于从小冲杆试验的测量结果来确定材料的力学性能是一个反问题,因此,与此有关的反问题分析方法也得到了相应的发展。本文系统综述小冲杆试验的测量技术及从测量数据来确定材料弹塑性参数的各种经验方法和计算方法,例如有限元分析和参数法、反向有限元法、有限元和反方法、反向识别和人工神经网络、有限元优化和试验变形形状以及杂交反方法等。

热障涂层材料性能和失效机理研究进展

热障涂层材料破坏由大尺度屈曲和层离机制产生，而这些机制又是微裂纹形核、扩展及相互连通结果的积累。由于特殊制备工艺和使用环境，材料性能涉及到许多特殊机制。近半个世纪的研究，人们对其性能有了充分认识。综述近几年的研究结果，内容包括：热生长氧化现象及其热力学描述；热生长应力与材料失效的联系；材料破坏机理与性能控制参数组织的联系；微缺陷演化产生的材料屈曲和层离所需的能量释放率；破坏准则、服役寿命预计模型和评价标准等。

Influence Of Micro-Impurity On Protein Crystal Growth Studied By The Etch Figure Method

The investigation of the effect of micro impurity on crystal growth by optical microscopy has been validated. The results showed that the growth rate of a lysozyme crystal was affected even if the concentration of impurity of fluorescent-labeled lysozyme (abbreviation, F-lysozyme) was very small. Different concentrations of F-lysozyme had different effects on crystal growth rate. The growth rate decreased much more as F-lysozyme concentration increased. The density of incorporated F-lysozyme on different grown layers of a lysozyme crystal during crystal growth was obtained from the results of flat-bottomed etch pits density. (C) 2008 Elsevier B.V. All rights reserved.

Mechanism study of femtosecond laser induced selective metallization (FLISM) on glass surfaces

We investigate the mechanism of selective metallization on glass surfaces with the assistance of femtosecond laser irradiation followed by electroless plating. Irradiation of femtosecond laser makes it possible to selectively deposit copper microstructures in the irradiated area on glass surfaces coated with silver nitrate films. The energy-dispersive X-ray (EDX) analyses reveal that silver atoms are produced on the surface of grooves formed by laser ablation, which serve as catalysis seeds for subsequent electroless copper plating. (C) 2008 Elsevier B.V. All rights reserved.

Transverse evolution of a plasma channel in air induced by a femtosecond laser

We investigate the evolution of filamentation in air by using a longitudinal diffraction method and a plasma fluorescence imaging technique. The diameter of a single filament in which the intensity is clamped increases as the energy of the pump light pulse increases, until multiple filaments appear. (c) 2006 Optical Society of America.

一种新的光刻机多成像质量参数的原位检测技术

随着光刻特征尺寸的不断减小，尤其是随着分辨力增强技术的使用，像质参数的原位检测已成为先进的投影光刻机中不可或缺的功能。然而现有的每种技术均只能检测有限的几种像质参数。提出了一种新的基于像传感器的光刻机多成像质量参数原位检测（MIQM）技术。该技术通过对原有的测量模型进行修正和扩展，从而在精确测茸低阶成像质量参数的同时能高精度地测量高阶成像质量参数。此外，该技术是基于空间像测量的像质参数原位检测技术，从而具有速度快、稳定性好等优点。通过该技术的低阶像质参数测量精度与原有技术相近，而高阶像质参数测量重复精度优

A high-speed image sensing technique with adjustable frame rate based on an ordinary CCD

In the sinusoidal phase modulating interferometer technique, the high-speed CCD is necessary to detect the interference signals. The reason of ordinary CCD's low frame rate was analyzed, and a novel high-speed image sensing technique with adjustable frame rate based on ail ordinary CCD was proposed. And the principle of the image sensor was analyzed. When the maximum frequency and channel bandwidth were constant, a custom high-speed sensor was designed by using the ordinary CCD under the control of the special driving circuit. The frame rate of the ordinary CCD has been enhanced by controlling the number of pixels of every frame; therefore, the ordinary of CCD can be used as the high frame rate image sensor with small amount of pixels. The multi-output high-speed image sensor has the deficiencies of low accuracy, and high cost, while the high-speed image senor with small number of pixels by using this technique can overcome theses faults. The light intensity varying with time was measured by using the image sensor. The frame rate was LIP to 1600 frame per second (f/s), and the size of every frame and the frame rate were adjustable. The correlation coefficient between the measurement result and the standard values were higher than 0.98026, and the relative error was lower than 0.53%. The experimental results show that this sensor is fit to the measurements of sinusoidal phase modulating interferometer technique. (c) 2007 Elsevier GmbH. All rights reserved.