Analysis of the strengthening and toughening of a biomaterial interface

Based on the transmission electron micrographs of nacre, the existence of mineral bridges in the organic matrix interface is confirmed. It is proposed that the microarchitecture of nacre should be considered as a "brick-bridge-mortar" (BBM) arrangement rather than traditional "brick and mortar" (BM) one. Experiments and analyses indicate that the mineral bridges effectively affect the strength and toughness of the interfaces in nacre. Comparison with a laminated composite with BM structure, SiC/BN, shows that the pattern of the crack extension and the toughening mechanism of the two materials are different. This reveals that the mineral bridges play a key role in the toughening mechanisms of nacre, which gives a conceptual guidance in material synthesis.

Upconversion and fluorescence spectral studies of Er3+/Yb3+-codoped Bi(2)Q(3)-GeO2-Ga(2)Q(3)-Na2O glasses

The absorption spectra and upconversion fluorescence spectra of Er3+/-Yb3+-codoped natrium-gallium-germanium-bismuth glasses are measured and investigated. The intense green (533 and 549 nm) and red (672 nm) emission bands were simultaneously observed at room temperature. The quadratic dependence of the green and red emission on excitation power indicates that the two-photon absorption processes occur. The influence of Ga2C3 on upconversion intensity is investigated. The intensity of green emissions increases slowly with increasing Ga2O3 content, while the intensity of red emission increases significantly. The possible upconversion mechanisms for these glasses have also been discussed. The maximum phonon energy of the glasses determined based on the infrared (IR) spectral analysis is as low as 740 cm(-1). The studies indicate that Bi2O3-GeO2-Ga2O3-Na2O glasses may be potential materials for developing upconversion optical devices (c) 2006 Published by Elsevier B.V.

乳酸脱氢酶 LDH 同功酶在猕猴属四种动物正常血清中的含量比较

用聚丙烯酰胺凝胶电泳 PAGE 和瑞典LKB-2202型激光光密度扫描仪, 分析测定了猕猴属中恒河猴(Macacamulatta), 红面猴(M.arctiodes), 熊猴(M.assamensis)和平顶猴(M.nemestrina)等四个种正常血清乳酸脱氢酶(LDH)同功酶谱型及含量变化. 结果表明: 这四个种正常血清的LDH同功酶及A、B两种亚基的含量存在着差异. 其中恒河猴与平顶猴之间的差异相对较大, 熊猴与红面猴之间的差异相对较小. 该文讨论了这些差异与这四种猴的分类地位的关系。

梁子湖湿地自然保护区生物多样性研究

根据1999～2001年的野外调查数据,研究了湖北鄂州梁子湖自然保护区的生物多样性资源,并对其进行了评价。结果表明:有浮游藻类71种,高等植物331种,浮游动物89种,底栖动物49种,鱼类94种,两栖类8 种,爬行类15种,鸟类166种,兽类21种。其中:国家重点保护野生动物25种,占湖北省同类总种数的22.93％;湖北省省级重点保护野生动物64种,占湖北省同类总种数的44.75％;国家重点保护植物4种。认为梁子湖自然保护区水质污染轻,生态系统完整、自然,生物多样性十分丰富,在长江中下游湿地中具典型性和代

一种基于速率的发布/订阅系统的准入控制机制

提出了基于内容发布／订阅系统的一种准入控制机制RacsCBPS来保障客户端的服务质量．首先分析了基于内容发布／订阅系统中实现准入控制机制的难点，给出了RacsCBPS的基本模型，在此基础上，提出了基于覆盖关系的资源需求计算方法和以订阅分发路径为基础的准入控制算法．RacsCBPS在不影响发布／订阅系统松散耦合性的情况下，能够有效地解决因系统资源不足而导致的事件过载问题，同时为系统提供了不同的准入准则，以便在系统资源利用率和服务质量保证程度之间作出不同的权衡．最后通过实验验证了准入控制机制的有效性和相应的系统资源利用率．

基于PLSA模型的文本分割

文本分割在信息提取、文摘自动生成、语言建模、首语消解等诸多领域都有极为重要的应用·基于PLSA模型的文本分割试图使隐藏于片段内的不同主题与文本表面的词、句对建立联系·实验以汉语的整句作为基本块,尝试了多种相似性度量手段及边界估计策略,同时考虑相邻句重复的未登录词对相似值的影响,其最佳结果表明,片段边界的识别错误率为6·06%,远远低于其他同类算法·

沈阳市城镇扩展时空格局及其驱动力

利用多时相TM影像,采用GIS空间分析和景观格局分析相结合的方法,对沈阳市辖区城镇扩展的时空分异特征和城镇景观格局演变进行了分析,并对其驱动力进行了探讨.结果表明:1988—2004年间,沈阳市辖区城镇面积持续增加,扩展强度逐渐增强,2000—2004年间的城镇扩展规模和强度达到最大;城镇扩展具有明显的空间分异特征,市区西南方向是城镇扩展的主方向,近郊及各级经济开发区是扩展的主要区域;城镇景观格局日趋复杂,城镇发展紧凑程度降低;城镇景观格局演变与城镇扩展特征关系密切,表现出时空分异特征;工业化发展与开发区建设、政府政策与城市规划以及交通基础设施建设是沈阳市辖区城镇扩展与城镇景观格局演变的主要驱动力.

Ion-Responsive Behavior of Ionic-Liquid Surfactant Aggregates with Applications in Controlled Release and Emulsification

We propose a simple but efficient, rapid, and quantitative ion-responsive micelle system based on counter-anion exchange of a surfactant with an imidazolium unit. The ion-exchange reaction results in the amphiphilic-to-hydrophobic transition of the imidazolium salt, leading to the destruction of the micelles, which has been successfully applied to control led release and emulsification.

Electronic structures and chemical bonding in 4d transition metal monohalides

Bond distances, vibrational frequencies, dipole moments, dissociation energies, electron affinities, and ionization potentials of NIX (XM = Y-Cd, X = F, Cl, Br, I) molecules in neutral, positively, and negatively charged ions were studied by density functional method, B3LYP. The bonding patterns were analyzed and compared with both the available data and across the series. It was found that besides ionic component, covalent bonds are formed between the 4d transition metal s, d orbitals, and the p orbital of halogen. For both neutral and charged molecules, the fluorides have the shortest bond distance, iodides the longest. Although the opposite situation is observed for vibrational frequency, that is, fluorides have the largest value, iodides the smallest. For neutral and anionic species, the dissociation energy tends to decrease with the increasing atomic number from Y to Cd, suggesting the decreasing or weakening of the bond strength. For cationic species, the trend is observed from Y to Ag.

港西地区河流相砂岩油藏剩余油分布研究

The Gangxi oil field has reached a stage of high water production. The reservoir parameters, such as reservoir physical characteristics, pore structure, fluid, have obviously changed. This thesis therefore carries out a study of these parameters that control reservoir characteristics, physical and chemical actions that have taken place within the reservoirs due to fluid injection, subsequent variations of reservoir macroscopic physical features, microscopic pore structures, seepages, and formation fluid properties. This study rebuilds a geologic model for this oil field, establishes a log-interpreting model, proposes a methodology for dealing with large pore channels and remnant oil distribution, and offers a basis for effective excavation of potential oil, recovery planning, and improvement of water-injection techniques. To resolve some concurrent key problems in the process of exploration of the Gangxi area, this thesis carries out a multidisciplinary research into reservoir geology, physical geography, reservoir engineering, and oil-water well testing. Taking sandstone and flow unit as objects, this study establishes a fine geologic model by a quantificational or semi-quantificational approach in order to understand the remnant oil distribution and the reservoir potential, and accordingly proposes a plan for further exploration. By rebuilding a geological model and applying reservoir-engineering methods, such as numerical simulation, this thesis studies the oil-water movement patterns and remnant-oil distribution, and further advances a deployment plan for the necessary adjustments and increase of recoverable reserves. Main achievements of this study are as follows: 1. The Minghazhen Formation in the Gangxi area is featured by medium-sinuosity river deposits, manifesting themselves as a transitional type between typical meandering and braided rivers. The main microfacies are products of main and branch channels, levee, inter-channel overflows and crevasse-splay floodplains. The Guantao Group is dominantly braided river deposit, and microfacies are mainly formed in channel bar, braided channel and overbank. Main lithofacies include conglomerate, sandstone, siltstone and shale, with sandstone facies being the principal type of the reservoir. 2. The reservoir flow unit of the Gangxi area can be divided into three types: Type I is a high-quality heterogeneous seepage unit, mainly distributed in main channel; Type II is a moderate-quality semi-heterogeneous seepage unit, mainly distributed in both main and branch channels, and partly seen within inter-channel overflow microfacies; Type III is a low-quality, relatively strong heterogeneous seepage unit, mainly distributed in inter-channel overflow microfacies and channel flanks. 3. Flow units and sedimentary microfacies have exerted relatively strong controls on the flowing of underground oil-water: (1) injection-production is often effective in the float units of Type I and II, whilst in the same group of injection-production wells, impellent velocity depends on flow unit types and injection-production spacing; (2) The injection-production of Type III flow unit between the injection-production wells of Type I and II flow units, however, are little effective; (3) there can form a seepage shield in composite channels between channels, leading to inefficient injection and production. 4. Mainly types of large-scale remnant-oil distribution are as follows: (1) remnant oil reservoir of Type III flow unit; (2) injection-production well group of remnant oil area of Type III flow unit; (3) remnant oil reservoirs that cannot be controlled by well network, including reservoir featured by injection without production, reservoir characterized by production without injection, and oil reservoir at which no well can arrive; (4) remnant oil area where injection-production system is not complete. 5. Utilizing different methods to deal with different sedimentary types, sub-dividing the columns of up to 900 wells into 76 chronostratigraphic units. Four transitional sandstone types are recognized, and contrast modes of different sandstone facies are summarized Analyzing in details the reservoirs of different quality by deciphering densely spaced well patterns, dividing microscopic facies and flow units, analyzing remnant oil distribution and its effect on injection-production pattern, and the heterogeneity. Theory foundation is therefore provided for further excavation of remnant oil. Re-evaluating well-log data. The understanding of water-flood layers and conductive formations in the Gangxi area have been considerably improved, and the original interpretations of 233 wells have changed by means of double checking. Variations of the reservoirs and the fluid and formation pressures after water injection are analyzed and summarized Studies are carried out of close elements of the reservoirs, fine reservoir types, oil-water distribution patterns, as well as factors controlling oil-gas enrichment. A static geological model and a prediction model of important tracts are established. Remaining recoverable reserves are calculated of all the oil wells and oil-sandstones. It is proposed that injection-production patterns of 348 oil-sandstones should be adjusted according to the analysis of adaptability of all kinds of sandstones in the injection-production wells.