CLIGEN非降水要素在黄土塬区的适用性评估

许多基于物理机制的水文和作物模型需要日序列气象数据来驱动,CLIGEN是为WEPP等模型产生气候输入文件的天气发生器,可以产生10个日序列气象变量来满足这种需要,但是其在中国的适用性需要进行评估。研究的目标是利用黄土高原陕西长武1957~2001年的气象数据评估CLIGEN产生非降水要素(最高温度、最低温度、露点温度、太阳辐射和风速)的能力。结果表明,CLIGEN对最高温度、最低温度和露点温度的模拟效果较好,对太阳辐射和极端气候事件的模拟效果较差,对风速的模拟效果最差。相关性检验表明CLIGEN很好地保持了气象要素的季节性,这对模拟农业生产是非常重要的;但是没有保留气象要素逐日的自相关和互相关性,进而导致产生的温度变化不符合连续渐变的规律。

黄土丘陵区不同恢复年限草地土壤微团粒分形特征

运用分形理论研究黄土丘陵区不同恢复年限草地土壤微团粒的粒径组成、分形维数特征及与土壤理化性质关系,使分形学在土壤微团粒性状与土壤肥力特征研究中得到进一步应用,并为评价草地生态系统土壤特征及生态恢复提供新方法。结果表明:表土层分形维数随植被恢复年限的增加而减少;剖面土壤沙粒含量越高,微团粒分形维数越低,粘粒规律相反,而粉粒与分形维数相关性不显著;土壤质地由粗到细使得分形维数由小到大变化;分形维数也可有效地表征不同植被恢复年限的草地土壤结构和养分的变化趋势;分形维数与土壤容重、非活性孔度、全磷、速效钾及氨态氮之间存在正相关性,与土壤活性孔度、孔隙比、有机质、全氮、碱解氮及硝态氮表现出负相关。

取代环戊二烯基稀土有机氯化物的合成及其反应

本文通过无水LnCl_3(Ln = Pr.Nd.Gd)与两倍摩尔的叔丁基环戊二烯基碱金属盐在THF中60－80℃反应，分离到一类新的二（叔丁基环戊二烯基）稀土氯化物（T-DuCp）_2 2net.nTHF (Ln = Pr,Nd,n = 2 Ln = Gd,n = 1)，对它们进行了元素分析。红外光谱及水鲜色质谱的表征。对于配合物（t-BuCp）_2PrCl·2THF的单晶，测定了它的晶体结构，晶体层单斜晶系P21/C空间群，晶胞参数为：a = 15.080 b = 8.855 c = 21.196A, β = 110.34°V = 2653.9A~3 δ = 4，结构分析表明此配合物是一中性的单分子配合物。最后的R = Rw = 0.058平均Pr-C.2.81 Pr-Cent 2.53A, Pr-Cl及Rr-O键长分别为2.72与2.62A。本文通过Lnel_3(Ln = Nd.Pr.Ga)与等摩尔的叔丁基环戊二烯基碱金属盐在THF中60－80℃反应，分离到一类中性的单(叔丁基环戊二烯基)稀土二氯化物，并对它们进行了元素分析，红外光谱及水鲜色质谱的表征。本文通过轻稀土元素La,Pr的三氯化物与带基钠以1:2摩尔比在THF中70－80℃反应，分离到了二带基轻稀土氯化物（CaH_7）_2LaCl.2THF及[(CqH_7)_2PrCl.THF]_2。并且对此二配合物进行了元素分析。红外光谱及水鲜色质谱的表征。对于[(CuH_7)_2PrCl.TH]_2配合物，测定了它的晶体结构，这是第一个得到结构表征的茚基稀土氯化物，晶体层于单斜晶系，P_(21)/C空间群，晶胞参数为a = 7.808 b = 17.796 c = 14.070A β = 93.97°v = 1950.31A. E = 2最后的R = 0.045. Rw = 0.039结构分析表明此配合物以中性的二聚体形式存在。平均的Pr-C.2.81 Pr-Cent 2.53. Pr-Cl.2.84H Pr-O钻长2.54A。为了进一步研究不同配体对配合物结构的影响，我们还研究了Gael_3与Nae_5Mes以1:1摩尔比在THF中的反应，分离到了两种配合物[(NaTHF)(C_5MesGd.THF)_2Cl_5]_2.6THF(I)及L_5Me_5GdCl2.3THF(II)并且对配合物（I），测定了它的晶体结构，晶体层于三斜晶系。Pi空间群。晶胞参数a = 12.183 b = 13.638 c = 17.883A, α = 110.38 β = 94.04 γ = 99.44°, V = 2721.20A, E = 1。结构分析表明，此配合物是一种以两个Na原子通过THF中的O原子而桥联的金层有机配合物，在结构上有十分新颖的特点。在此配合物分子中含有四个Gd原子及二个Na原子，Na及Gd间以Cl桥键相联结，Gd-Gd_2 = 4.033 Gdll-Na = 2.818A。最后的R = 0.04M Rw = 0.042。本文还对（t-BuCp）_2P_2Cl.2THF与NaH及LiAlH4的反应进行了初步的研究，分离到（t-Bucp）_2PrH.2THF及(t-Bucp)_2P_2RIH_4.3THF两种新的氢化物，并且对它们进行了元素分析，红外光谱的表征，对于它们水鲜产物的气相分中的H_2，用气相色谱法进行了定性表征。

Transient photocurrent investigation of photo-processes of lattice-matched MQW GaAs/AlxGa1-xAs electrode

Transient photocurrents induced by short light pulses at lattice-matched GaAs/AlxGa1-xAs multiple quantum well (MQW) electrodes were studied as a function of electrode potential. Dual exponential photocurrent decay transients were observed at various potentials. By analysis of the dual exponential decay transients, information on steady state photocurrents (I-s), surface collection of photoexcited minority carriers (G(0)) and lifetimes of surface states (T-s) was obtained. The kinetic behaviors of photoprocesses at illuminated MQW/electrolyte interface were discussed.

低温生长砷化镓光电导天线产生太赫兹波的辐射特性

研究了低温生长砷化镓光电导天线(LT-GaAs PCA)产生太赫兹(THz)波的辐射特性。利用太赫兹时域光谱(TDS)技术测量了光电导发射极在飞秒激光作用下辐射的太赫兹脉冲,得到了时域发射光谱,并通过快速傅里叶变换(FFT)得到相应的频域光谱。结果表明,低温砷化镓光电导天线产生的太赫兹波信号比飞秒激光激发半导体表面产生的太赫兹波信号具有更高的强度和信噪比;太赫兹波信号与光电导天线的偏置电压成线性关系;随着抽运激光功率的增强,太赫兹波信号增大并出现饱和。

Dynamics of Cavity Polaritons in a GaAs Quantum-well Semiconductor Microcavity

To provide the dynamics of cavity polariton in semiconductor microcavity containing GaAs quantum-well, the dispersions of the three cavity polaritons have been given by the model of three coupled oscillators, meanwhile the linewidths, group velocities and the mass of the three cavity polaritons have been demonstrated. The results indicated that because of the weight occupied by the photon, heavy hole exciton and light hole extiton in the three cavity ploariton the cavity polaritons exhibited different dynamic behaviors.

用于光纤通信的1.55μmDFB激光器的可靠性分析

对用于光纤通信的InP基1.55 μm DFB激光器的可靠性进行了研究.测试并分析了100 ℃时100 mA和150 mA 2种电流应力条件,经过1 700 h老化,测试分析了激光器特性随时间的变化情况,拟合出在100 ℃,150 mA条件下的激光器寿命在1 000 h小时左右.根据实验结果对比,提出了一种新的利用温度、电流两个加速度变量同时进行加速老化,快速估计激光器寿命并分析其可靠性的方法.对新的寿命估算方法进行了详细的讨论.

低压MOCVD外延生长InGaAsP/InP应变量子阱材料与器件应用

报道了用低压有机金属化合物化学气相沉积外延生长InGaAsP/InP应变量子阱材料,材料参数与外延条件的关系,量子阱器件的结构设计及其器件应用。用所生长的材料研制出宽接触阈值电流密度小于400 A/cm~2(腔长400 μm),DC-PBH结构阈值7～12 mA的1.3 μm量子阱激光器和宽接触阈值电流密度小于600 A/cm~2(腔长400 μm),DC-PBH结构阈值9～15 mA的1.55 μm量子阱激光器以及高功率1.3 μm量子阱发光二极管和InGaAs PIN光电探测器。

AlGaInP visible quantum well lasers for information technology

650 nm-range AlGaInP multi-quantum well (MQW) laser diodes grown by low pressure metal organic chemical vapor deposition (LP-MOCVD) have been studied and the results are presented in this paper. Threshold current density of broad area contact laser diodes can be as low as 350 A/cm(2). Laser diodes with buried-ridge strip waveguide structures were made, threshold currents and differential efficiencies are (22-40) mA and (0.2-0.7) mW/mA, respectively. Typical output power for the laser diodes is 5 mW, maximum output power of 15 mW has been obtained. Their operation temperature can be up to 90 degrees C under power of 5 mW. After operating under 90 degrees C and 5 mW for 72 hrs, the average increments for the threshold currents of the lasers at 25 degrees C and the operation currents at 5 mW (at 25 degrees C) are (2-3) mA and (3-5) mA, respectively. Reliability tests showed that no obvious degradation was observed after 1400 hours of CW operation under 50 degrees C and 2.5 mW.