Effect of surface state properties of TiO2 nanoparticle film on its photocatalytic activity

TiO2 nanoparticle film catalysts with different thicknesses were prepared by plasma-enhanced chemical vapor deposition(PECVD) method and the surfaces were subsequently treated by TiCl4 or O-2 plasma. Two kinds of TiO2 films with different surface properties were obtained. Their surface microstructures and energy levels of surface states were tested by AFM, XRD, SPS, The photocatalytic activities of the catalysts were determined via photodegradation experiments of phenol. The results demonstrated that photocatalytic activities of samples whose surface was treated by O-2 plasma were greater than those treated by TiCl4 plasma. Moreover, photodegradation ratio of phenol during the first hour catalyzed by 0. 17 mu m thickness TiO2 nanoparticle film was greater than other samples. Especially, the difference of photocatalytic activities of TiO2 nanoparticle films treated by TiCl4 or O-2 plasma was respectively explained by energy band theory.

Biological effect of rare earth (I) - Content and distribution of rare earth in normal human plasma

The content and distribution of rare earth(RE) in normal human plasma have been investigated by ultrafiltration, FPLC and ICP-MS methods, The results showed that there are trace RE in normal human plasma, and their contents are in accordance with their abundance, The RE can bond with immunoglobulin G(IgG), transferrin(Tf) and albumin(Alb) species, but mostly bond with Tf.

稀土生物效应研究(Ⅰ)──正常人血浆中稀土含量及其物种分布

采用ICP-MS及FPLC等技术研究了正常人血浆中稀土含量及其物种分布．结果表明，正常人血浆中含有痕量的稀土(总量为1.413.3μｇ/L)，每种稀土含量与其天然丰度一致；稀土物种主要集中于大分子蛋白组分中，与免疫球蛋白G(IgG)、运铁蛋白(Tf)、血清白蛋白(Alb)等均有作用，其中Tf结合稀土量较多

Structure and luminescent properties of YAG : Eu, Bi synthesized by sol-gel method

(Y1-xEux)(3)Al5O12 and (Y1-x-yEuxBiy)(3)Al5O12 were prepared by so-gel method. Their structures of the luminophor are similar to that of YAG, which is recorded on the ASTM card and belongs to a cubic system. The luminescent properties show that the reaction temperature of the current sol-gel method is in the range of 400-500 degrees C, which is lower than that of the conventional solid state reaction. The luminophors have the strongest emission intensity when the values of x and y are 0.06 and 0.013, respectively.

酚酞型聚芳醚砜(Ⅶ):K_2C0_3存在下PP/DCDPS体系聚合反应机理的研究

利用~(13)C-NMR方法研究了弱碱K_2CO_3存在下酚酞成盐反应及其与活性双卤砜亲核缩聚反应过程中的结构特征。对一系列碱性条件下酚酞(PP)与4,4'-二氯二苯砜(DCDPS)的缩聚反应的研究表明任何影响内酯结构酚酞盐生成的因素都会严重阻碍聚合反应的进行。对模型化合物存在下K_2CO_3在极性非质子溶剂中的溶解/解离行为的研究结果表明酚酞类Card。双酚与固体K_2CO_3之间可能存在着一种特殊的络合作用。基于我们系列研究结果,本文中总结提出了弱碱K_2CO_3存在下酚酞的反应机理。

Interannual fluctuations in floral longevity, pollinator visitation and pollination limitation of an alpine plant (Gentiana straminea Maxim., Gentianaceae) at two altitudes in the Qinghai-Tibetan Plateau

Prolonged floral longevity and bumblebees as dominate pollinators in alpine ecosystem have been suggested to overcome pollination limitation of alpine plants arising from the decrease of pollinator activity with increasing altitude. However, this conclusion has never been examined in the Qinghai-Tibetan Plateau (QTP), the highest and largest plateau in the world. In this study, we intended to test year-to-year correlations between floral longevity, visiting frequency and pollen limitation of this species between two populations (at 3200 m and 4000 m) of Gentiana straminea in this plateau. Pollinator exclusion elongated both male and female phases greatly at both sites, and durations of both male and female phases in natural condition varied greatly over three years. The visiting frequency of bumblebees varied greatly at the higher altitude, but seemed to be stable at the lower altitude. Seed production was pollination limited in both populations in most studied years. The floral durations, pollinator frequency and pollination limitation showed no significant and consistent variations with the increase of altitude. The previous hypothesis that the prolonged floral longevity of alpine plants can compensate for low levels of pollinator visitation therefore could not be confirmed, and our results further suggested that in the QTP platform, the altitude shows no consistent effect on the reproductive performance of this species, despite that the fluctuation of visit frequency intensified at the higher altitude.

基于DSP的CANopen通讯协议的实现

CANopen是一种开放的应用层协议,其应用可以进一步提高系统的可靠性、通讯效率及灵活性,而且可以使产品具有很好的兼容性。本文采用CANopen通讯协议实现了CAN总线DSP系统与上位机CAN卡之间的通讯,并通过测试实验验证了信息传递的可靠性,保证了全数字网络化伺服驱动系统中对电机控制的准确性和实时性。

基于C8051的运动控制卡研制和应用

本文针对排爆机器人手臂多关节联动控制的需要,开发了一种具有高集成度的基于C8051单片机和CAN总线的运动控制卡。介绍了运动控制卡的原理及实施方案,同时给出了运动控制卡在机器人平台的应用实例。在排爆机器人平台上的应用表明该运动控制卡具有较高的精度及很好的可靠性和实时性。

仿人机器人腰机构控制及分析实验平台研究

介绍了一种新型的仿人机器人两自由度腰部结构,给出了该机构两个伺服电机的PID控制策略,建立了基于PC机CAN卡的网络控制平台,该平台可实现腰部机构的实时控制及实时机构控制响应特性分析,该平台还具有扩展性强、成本低的特点。

卷烟条盒包装质量检测机器视觉系统设计

为了避免人眼对产品外观质量检测时,人眼视觉疲劳所产生的产品错检、漏检,提出了基于机器视觉的烟支条盒包装质量检测系统的设计。该系统由光源、相机、图像采集卡和工业控制计算机组成视觉系统处理单元,应用定位配准、边缘检测和斑点分析等图像处理算法完成对产品缺陷的检测。该视觉检测系统已经在烟厂得到了实际应用,对今后开发类似的基于机器视觉的产品外观质量检测系统具有一定的参考价值和指导意义。

车道收费系统中USB接口通信卡的设计

带USB接口的设备使用方便,发展迅速,文章结合高速公路车道收费系统中的实际问题,详细介绍了设计一个USB接口通信卡的过程,包括电路设计、器件选择、固件设计、驱动程序及其应用程序设计。

基于DSRC的多功能不停车收费系统

DSRC标准是ISO/TC204制定的智能交通系统(ITS)中车—路信息通讯的协议。采用双片式ETC电子标签结合双界面IC卡的储值卡方案形成的多功能不停车收费系统,充分兼容了当前国内普遍应用的IC卡半自动收费方式,集中了IC卡收费系统和ETC收费系统的优点,方便、快捷、通行能力强,并解决了收费口的交通拥挤现象。