104 resultados para Pobal HP deprivation index


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The applications of new topological indices A(x1)-A(x3) suggested in our laboratory for the prediction of Gibbs energy values of phase transfer (water to nitrobenzene) of amine ions are described with satisfactory results. Multiple regression analysis and neural network were employed simultaneously in this study.

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The topological state and the total topological index, tau, have been tested systematically. Counterexamples are provided proving that the topological state method cannot determine classes of symmetrically equivalent atoms in a molecule fully correct. The

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in this Raper, based on distance matrix and branch vertex of atomes in a molecule, a new topological index (Y(x)) has been developed to be used in research on physical and chemical properties of alkanes. It is concluded that this index bears good structure selectivity and relativity when the results from index were compared with that of other ones.

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A new topological index, the general a(N)-index (GAI), on quantum chemistry, is described in this paper. The GAI can be applied to molecules that contain heteroatoms and multiple bonds, and performs well in distinguishing cis/trans isomers. The relationships between the GAIs and physicochemical properties of olefins and neutral phosphorus compounds were observed with satisfactory results.

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The general a(N) index (GAI) was used to characterize the cis, trans isomers of hydrocarbons. The best one-variable equations were obtained with GAI for several physicochemical properties of seven pairs of olefin cis, trans isomers. The linear correlation coefficients are in the range of 0.975 to 0.997. GAI was also compared with the other five topological indices, Randic connectivity index chi, Wiener number W, Hosoya index Z, the average distance sum connectivity J proposed by Balaban and a(N) index introduced by Yang, in correlating with the octane number (MON) of heptanes and octanes.

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The relationship between the alpha-N index and physical properties of neutral phosphorus extractants is studied. Using the general alpha-N index which could describe extractants with minute difference in structure, the good correlation between it and various physical properties of the neutral phosphorus extractants (e.g., densities, refractive index, shift ratio of paper chromatography and IR frequencies of bond P = O) is obtained. The result indicates that general alpha-N index is a good topological index of organic compounds.

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The general a(N) index is established for molecules containing heteroatoms, rings, and multiple bonds. The general a(N) index is able to describe molecules with minute differences in structure and can also reveal the properties of molecules. This theory is successfully applied to the case of neutral phosphorus extractants. Both the molecular polarity and steric effect are characterized by the general a(N) index. The relationships between these properties and the distribution ratios for extracting Y, Ce, U, and Th are also shown by the general a(N) index.

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The chemical index of alteration has been used widely for reconstruction of the palaeoclimate. However, the mechanisms and environmental factors controlling the chemical index of alteration of sediments are not yet fully understood. In this study, autocorrelations of the chemical index of alteration in nine sedimentary profiles, from both the land and the sea, spanning different geological times, are discussed. The sediments of these profiles have different origins (dust, fluvial or ocean sediments) and are from various climate situations and sedimentary environments. Autocorrelations of chemical index of alteration series are ubiquitously evident in all profiles. It is suggested here that autocorrelations may be caused by post-depositional changes such as persistent weathering and diagenesis. As a result, the chemical index of alteration may not reflect climatic conditions during the time of sediment deposition. This study strongly recommends the confirmation of the reliability and veracity of the chemical index of alteration before it is adopted to evaluate the weathering degree of parent rocks and to reconstruct the past climate. Significant autocorrelations in loess profiles were specifically observed, suggesting that the existing understanding of loess deposition in terms of climate conditions requires re-examination, and that previous reconstructions of rapid climate changes (for example, in centennial-millennial scales) should be treated with caution.

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Apostichopus japonicus is a common sea cucumber that undergoes seasonal inactivity phases and ceases feeding during the summer months. We used this sea cucumber species as a model in which to examine phenotypic plasticity of the digestive tract in response to food deprivation. We measured the body mass, gross gut morphology and digestive enzyme activities of A. japonicus before, during, and after the period of inactivity to examine the effects of food deprivation on the gut structure and function of this animal. Individuals were sampled semi-monthly from June to November (10 sampling intervals over 178 days) across temperature changes of more than 18 degrees C. On 5 September, which represented the peak of inactivity and lack of feeding, A. japonicus decreased its body mass, gut mass and gut length by 50%, 85%, and 70%, respectively, in comparison to values for these parameters preceding the inactive period. The activities of amylase, cellulase and lipase decreased by 77%, 98%, and 35% respectively, in comparison to mean values for these enzymes in June, whereas pepsin activity increased two-fold (luring the inactive phase. Alginase and trypsin activities were variable and did not change significantly across the 178-day experiment. With the exception of amylase and cellulase, all body size indices and digestive enzyme activities recovered and even surpassed the mean values preceding the inactive phase during the latter part of the experiment (October-November). Principal Component Analysis (PCA) utilizing the digestive enzyme activity and body size index data divided the physiological state of this cucumber into four phases: an active stage, prophase of inactivity peak inactivity, and a reversion phase. These phases are all consistent with previously suggested life stages for this species, but our data provide more defined characteristics of each phase. A. japonicus clearly exhibits phenotypic plasticity (or life-cycle staging) of the digestive tract during its annual inactive period. (C) 2008 Elsevier Inc. All rights reserved.

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Pigment ingestion rate (PIR) and egg production rate (EPR) of the dominant copepod Calanus sinicus, as well as chlorophyll-a concentration and phytoplankton assemblages were measured in the Bohai Sea, North China in June 1997, October 1998 and May 1999. A herbivore index (H) was also calculated as the carbon specific ratio of PIR and EPR, in order to investigate its feeding habits in the spring and autumn phytoplankton bloom respectively. On average, chlorophyll-a concentration was relatively similar (1-1.34 mg m(-3)) in the three cruises, but PIR was quite different. It was 3.24 mu g C female(-1) d(-1) in October, equivalent to one half of the PIR for June and one third of the PIR for May. Average EPR was highest in May, and quite similar during the other two months. According to H values, herbivorous feeding contributed 100% of the egg production of C. sinicus in June, 82.5% in May, but only 47.8% in October. It is possible that omnivorous feeding of C. sinicus in October was induced by a prevalence of large-sized diatoms and sufficient non-phytoplankton food resources during the autumn bloom period.

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The VEGETATION (VGT) sensor in SPOT 4 has four spectral bands that are equivalent to Landsat Thematic Mapper (TM) bands (blue, red, near-infrared and mid-infrared spectral bands) and provides daily images of the global land surface at a 1-km spatial resolution. We propose a new index for identifying and mapping of snow ice cover, namely the Normalized Difference Snow/Ice Index (NDSII), which uses reflectance values of red and mid-infrared spectral bands of Landsat TM and VGT. For Landsat TM data, NDSII is calculated as NDSIITM =(TM3 -TM5)/(TM3 +TM5); for VGT data, NDSII is calculated as NDSIIVGT =(B2- MIR)/(B2 + MIR). As a case study we used a Landsat TM image that covers the eastern part of the Qilian mountain range in the Qinghai-Xizang (Tibetan) plateau of China. NDSIITM gave similar estimates of the area and spatial distribution of snow/ice cover to the Normalized Difference Snow Index (NDSI=(TM2-TM5)/(TM2+TM5)) which has been proposed by Hall et al. The results indicated that the VGT sensor might have the potential for operational monitoring and mapping of snow/ice cover from regional to global scales, when using NDSIIVGT.

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在开放(P_水HP-DTA)在压力达800巴的范围内对钙蒙脱石-氯化钙-水体系的脱水作用共进行了三百多次实验研究。实验所需的钙蒙脱石是用1N浓度的CaCl_2溶液对初始样品怀俄明富钠蒙脱石(SWy-1)进行离子交换后产生。通过本次论文的工作深刻地认识到蒙脱石族矿物的脱水作用是受水的逸度所控制,这是一新的认识,而且相当重要,因为清楚了蒙脱石矿物脱水作用的控制因数对于我们了解许多浅部地球化学过程具有重要的意义。在CaSWy-H_2O和CaSWy体系中,蒙脱石的脱水作用是分两级进行的,其脱水温度随压力的增加而向高温区移动,尤其是在<100巴的范围内,其递增速率相当快。在相同压力下,钙蒙脱石的两级脱水温度分别高于水的蒸发温度50℃和110℃,在压力大于水的临界点时,钙蒙脱石的脱水温度增加的趋势相当缓慢。两级脱水反应的吸热谷形态随着压力的增加而发生变化。这些特点被理解为钙蒙脱石层间水的密度大于自由水的密度,其层间水具有两种不同的水组态,其组态形式随着压力的增加而发生变化,但组态之间的能量间距却不随压力的变化而变化。应用实验数据,在论文中给出了一种新的在一大气压下计算钙蒙脱石层间吸附力焓值大小的办法,共值为:ΔH_(iw),湿~I = 7.74KJ/mol, ΔH_(iw), 干~I = 8.13KJ/mol; ΔH_(iw),湿~I = 20.74KJ/mol, H_(iw), 干~I = 21.28KJ/mol。这些值也表明了使用干体系或者湿体系来研究钙蒙脱石的脱水作用基本上没有什么区别。同时也指出在常压DTA实验技术中常论及的影响DTA峰(谷)值大小和峰(谷)的形态的样品因数实质上是由于这些因数引起了围绕在样品颗粒之间的水逸度的变化所致,这是一种对样品影响因数的新认识。把CaSWy同已知重量比为0.9、1.8、5、10、20和30wt.%的氯化钙均匀混合,在实验过程中分别产生浓度为0.5M、1.8M、2.82M、5.63M、11.26和16.9M的CaCl_2-H_2O流体。同CaSWy体系相比,在CaSWy-CaCl_2体系中,由于盐的加入,使体系中水的逸度降低,在相同压力下降低了钙蒙脱石的脱水温度,其降低的量同盐的浓度成正比。在0-11.26M浓度之间钙蒙脱石的脱水温度降低速度较快,但当浓度大于或等于11.26.时盐水流体的浓度不再能降低钙蒙脱石的脱水温度,而且在较高压力下其效应更加明显。在体系中CaCl_2-H_2O流体的浓度为5.63M、11.26M和16.9M时,在一大气下钙蒙脱石脱水温度可低于水的蒸发温度。因此,在具有一定盐浓度的岩层中存在蒙脱石脱水作用会对岩层中孔隙水的水压产生缓冲作用,出现超压现象。利用实验数据,计算出了各种浓度的盐体系脱水作用的van't Hoff线方程:0%: 1np= 15.008 - 7.237 * (1000/T) (0.5M) 0.9%: 1np=14.634-6.781* (1000/T) (1M) 1.8%: 1np = 15.347-7.130 * (1000/T) (2.82M) 5%: 1np = 14.717 - 6.381 * (1000/T) (5.63M) 10%: 1np = 14.270-5.806 * (1000/T) (11.26M) 20%: 1np = 14.580 - 5.831 * (1000/T) (16.9M) 30%: 1np = 14.412 - 5.519 * (1000/T)根据这些等式求出了在不同压力、温度下各种浓度的CaCl_2-H_2O流体的水逸度系数(£)。由于至目前为止在文献中还没有这方面的实验研究报道,因而无法评价这一新方法所获得的数据的准确性。利用求得的£值,在本篇论文中建立起了不同浓度的CaCl_2-H_2O流体影响钙蒙脱石脱水温度的热力学模式:TD' = [T_1*T_D*(ΔH_(tw) + ΔH_(sv)~盐)/[T_1*(ΔG + ΔH_(dn)~水)-T_D~* (ΔH_(av)~水-ΔH_(sv)~盐)在0-1M浓度范围内,可以认为ΔH_(dh)~水≈H_(dh)~盐,等式变为:TD' = (TD*ΔH_(dh))/(ΔG + ΔH_(dh))根据这个模式,能推导出在实验浓度范围内,钙蒙脱石在盐水体系中的脱水温度。通过本次论文的实验研究知道在一般沉积盆地的埋芷条件下,钙蒙脱石矿物不会发生简单的脱水作用。在缺乏K~+和低盐度的环境中,含水相蒙脱石可稳定地存在在一定深度的地壳中因而不可忽略蒙脱石在海洋化学和俯冲带水来源中的作用。在选择处理簇射性废料的回填料(backfill)时,如其它条件相同,则应优先选择钙蒙脱石,而不是蛭石。在石油采矿和勘探工程中,因压力释放所造成的蒙脱石的脱水作用可能是使钻井变大和塌方的可能性原因之一。