Methane aromatization in the absence of an added oxidant and the bench scale reaction test

A bench scale reaction test for methane aromatization in the absence of an added oxidant was performed and its reaction result evaluated based on the carbon balance of the system. The result was compared with those obtained from the micro-reaction test to ensure the accuracy of the internal standard analyzing method employed in this paper. The catalytic performances of modified Mo/HZSM-5 catalysts were examined. It was found that pre-treatment by steam on HZSM-5 weakened the serious deposition of coke, and pre-impregnation of n-ethyl silicate on HZSM-5 could improve the conversion of CH4, but had little effect on coke formation. A low temperature activation procedure including pre-reduction of the catalyst with methane prevents the zeolite lattice from being seriously destroyed by high valence state Mo species when the Mo loading is high. It was suggested that Mo2C species detected by XRD spectra was the active phase for CH4 aromatization.

获取无意识结构知识的机制:主观熟悉感与刺激重复结构在人工语法学习中的作用

The nature of the distinction between conscious and unconscious knowledge is a core issue in the implicit learning field. Furthermore, the phenomenological experience associated with having knowledge is central to the conscious or unconscious status of that knowledge. Consistently, Dienes and Scott (2005) measured the conscious or unconscious status of structure knowledge using subjective measures. Believing that one is purely guessing when in fact one knows indicates unconscious knowledge. But unconscious structural knowledge can also be associated with feelings of intuition or familiarity. In this thesis, we explored whether phenomenological feelings, like familiarity, associated with unconscious structural knowledge could be used, paradoxically, to exert conscious control over the use of the knowledge, and whether people could obtain repetition structure knowledge. We also investigated the neural correlates of awareness of knowing, as measured phenomenologically. In study one, subjects were trained on two grammars and then asked to endorse strings from only one of the grammars. Subjects also rated how familiar each string they felt and reported whether or not they used familiarity to make their grammaticality judgment. We found subjects could endorse the strings of just one grammar and ignore the strings from the other. Importantly, when subjects said they were using familiarity, the rated familiarity for test strings consistent with their chosen grammar was greater than that for strings from the other grammar. Familiarity, subjectively defined, is sensitive to intentions and can play a key role in strategic control. In study two, we manipulated the structural characteristic of stings and explored whether participants could learn repetition structures in the grammatical strings. We measured phenomenology again and also ERPs. Deviant letters of ungrammatical strings violating the repetition structure elicited the N2 component; we took this to be an indication of knowledge, whether conscious or not. Strings which were attributed to conscious categories (rules and recollection) rather than phenomenology associated with unconscious structural knowledge (guessing, intuition and familiarity) elicited the P300 component. Different waveforms provided evidence for the neural correlates of different phenomenologies associated with knowledge of an artificial grammar.

不确定性类型对概率表达和概率判断的影响

The present research firstly reviewed the experimental literature on probability expression and probability judgment, hypothesizing that individuals’ preference of probability expressions (verbal probability vs. numerical probability) and tendency for overextremity in probability judgment might differ with respect to different types of uncertainty. Five studies were conducted to test this hypothesis. In Study 1, questionnaires were used to explore the communication preference among Chinese-speaking people. Study 2 adapted the View of Uncertainty Questionnaire to explore the difference of verbal answers to three kinds of uncertainty. Study 3 and Study 4 used methods of the paper-and-pencil questionnaire and the laboratory experiment, respectively, to test the effects of uncertainty types on the preference of probability expressions and on the tendency for over-extreme probability judgment. Finally, Study 5 focused on individuals’ preference of probability expressions under various kinds of scenarios. The results were as follows: 1. The Communication Model Preference paradox phenomenon appears to be even more pronounced in the Chinese culture than in American English cultural settings. 2. The Chinese prefer more verbal probability expressions when communicating uncertainty in a weather-forecasting context than in a general context. 3. Sample groups with lower level of westernization tend to give more extreme answers and less probabilistic answers. 4. Types of uncertainty did have effects on individuals’ tendency for over-extreme probability judgment: under a traditional probability judgment task, people tend to be more over-extreme on internal uncertainty events than on external uncertainty events; however, this result is reversed under a gambling task. 5. Individuals’ preference for verbal probability expressions is more salient on internal uncertain events than on external uncertain events.

中美大学生归因偏差的跨文化研究

This research systematically compared Chinese undergraduates with American undergraduates on four kinds of attributional bias: correspondent bias, siuational overattribution, intergroup attributional bias and self-serving attributional bias, and examined the effect of the implicit theories reflecting the cultures on attributional bias. First is analyzed three pairs of opposite implicit theories: dispositionalist theory and situationalist theory, generality and particularity, stressing the positive evaluation of self and despising the positive evaluation of self. It developed the Modern Implicit Theories Inventory and Traditional Implicit Theories Inventory to measure these implicit theories, and the results showed these inventories had satisfactory validity and reliability, and they were suitable for the group comparison of Chinese implicit theories with European-American. At the same time through the test it found Chinese undergraduates agreed all these opposite implicit theories more than American undergraduates. Second, it studied Chinese and American undergraduates' attributional accuracy on locus of causality. The results showed: Chinese and American undergraduates both had the correspondent bias under the different salient situational constraints, and the degree of Chinese and American undergraduates' correspondent bias under the different salient situational constraints had no significant difference' Chinese and American undergraduates both showed the situational overattribution; Chinese undergraduates had more the correspondent bias and situational overattribution than American undergraduates. Third, on the research of Chinese and American undergraduates' intergroup attributional bias, it found Chinese and American undergraduates both had no intergroup attributional bias among kin, friends and strangers, while they both show some favorable outcome effects for these three group actors. The favorable outcome effects were significant on the attributional dimensions of locus of causality and controllability for strangers' behavior, and stability for kin and friends' behavior rating by Chinese undergraduates, and stability for friends' behavior rating by American undergraduates. Fourth, it explored Chinese and American undergraduates' self-serving attributional bias, and the result indicated that Chinese and American undergraduates both showed significant self-serving attributional bias: for outcome effects, Chinese undergraduates' self-serving attributional bias were reflected on the attributional dimensions of locus of causality, stability, controllability and globality, and American undergraduates were reflected on the attributional dimensions of locus of causality, stability and globality; for categorization effects, both Chinese and American undergraduates' self-serving attributional bias were reflected on attributional difference between self's negative behavior and others', but Chinese undergraduates were embodied on the attributional dimensions of locus of causality, stability and globality while American undergraduates were reflected on the attributional dimensions of stability and globality. It also found Chinese undergraduates had more self-serving attributional bias than American undergraduates. This was reflected on the attributional dimensions of locus of causality, stability and controllability for outcome effects, and for categorization effects, locus of causality, stability and globality rating for self and others' negative behavior. All studies indicated that Chinese and American undergraduates' implicit theories had no significant effects on all their four attributional bias. These findings' potentially important implications were discussed and the further research was suggested.

印象形成中同化和对比效应研究

Impression formation is an important aspect of person perception and has important interpersonal consequences. There are assimilation and contrast effects in impression formation and is still considerable debate regarding the best way to account for them. This present research used trait-implying sentences as priming materials, trait inferences sever as self-generated primes, examined the effect of different trait knowledge in assimilation and contrast effects. Experiment 1 determined the priming and target stimuli of this research by pretest. In experiment 2, participants read trait-implying sentences and resulted in trait inference as self-generated primes, examined the influence of trait activation on impression formation. The results indicated that participants instructed to memorize trait-implying sentences showed assimilation effect, whereas participants instructed to form impression from trait-implying sentences showed contrast effect. Difference to previous studies that emphasized the impact of awareness of the prime in impression formation, this research paid attention to the impact of different trait knowledge that resulted from trait inference. Experiment 3 studied the influence of actor salience on impression formation. The results indicated that when trait-implying sentences that described actors with names and were accompanied with photos of the actors, participants showed contrast under both memorization and impression instructions. Experiment 4 studied the influence of attribution context on assimilation and contrasts. The results showed that contrast ensued when trait-implying sentences were accompanied with the information that suggested a person attribution, whereas assimilation ensued when that information suggested a situation attribution, independent of processing goals. Experiment 5 made a direct test of the effect of different trait knowledge in impression formation. The results discovered that when abstract trait concepts were activated they act as a general interpretation frame in encoding stage, whereas when specific actor-trait links were activated, the activated information is likely to be used as a comparative standard in judgment stage. All studied indicated that there are two types of activated trait knowledge in trait inference: abstract trait concepts versus specific actor-trait links. When trait inference activated abstract trait concepts, the activated information serves as interpretation frame and lead to assimilation effect during impression formation, when trait inference activated specific actor-trait links, the activated information is more likely to be used as a comparative standards and resulted in contrast effects. These findings have important implications for understanding the mechanism of impression formation and practical values for interpersonal communication.

Electrode catalysts behavior during direct ethanol fuel cell life-time test

In the present paper, a 60 h life-time test of a direct ethanol fuel cell (DEFC) at a current density of 20 mA cm(-2) (the beginning 38 h) and 40 mA cm(-2) (the last 22 h) was carried out. After the life-time test, the MEA could not achieve the former performance. X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy dispersive X-ray analysis (EDX) were employed to characterize the anode and cathode catalyst before and after the life-time test. The XRD and TEM results showed that the particle size of the anode catalyst increased from 2.3 to 3.3 nm and the cathode from 3.0 to 4.6 nm. The EDX results of PtSn/C anode catalysts before and after the life-time test indicated that the content of the oxygen and tin, especially the content of the platinum, decreased prominently after the life-time test. The results suggest that the agglomeration of electrocatalysts, the destruction of the anode catalyst together with the fuel/water crossover from anode to cathode concurrently contribute to the performance degradation of the DEFC. (C) 2005 Elsevier B.V. All rights reserved.