Spin split cyclotron resonance in GaAs quantum wells

The cyclotron resonance (CR) of electrons in GaAs/AlGaAs quantum wells is investigated theoretically to explain a recent CR experiment, where two CR peaks were observed at high magnetic fields when both spin-up and spin-down states of the lowest Landau level are occupied. Our theoretical model takes into account the conduction band non-parabolicity, the electron bulk longitude-optic-phonon coupling, and the self-consistent subband structure. A good agreement is found.

Spin splitting modulated by uniaxial stress in InAs nanowires

We theoretically study the electronic structure, spin splitting, effective mass, and spin orientation of InAs nanowires with cylindrical symmetry in the presence of an external electric field and uniaxial stress. Using an eight-band k center dot p theoretical model, we deduce a formula for the spin splitting in the system, indicating that the spin splitting under uniaxial stress is a nonlinear function of the momentum and the electric field. The spin splitting can be described by a linear Rashba model when the wavevector and the electric field are sufficiently small. Our numeric results show that the uniaxial stress can modulate the spin splitting. With the increase of wavevector, the uniaxial tensile stress first restrains and then amplifies the spin splitting of the lowest electron state compared to the no strain case. The reverse is true under a compression. Moreover, strong spin splitting can be induced by compression when the top of the valence band is close to the bottom of the conductance band, and the spin orientations of the electron stay almost unchanged before the overlap of the two bands.

Interface energy and its influence on interface fracture between metal and ceramic thin films in nanoscale

A theoretical model about the size-dependent interface energy between two thin films with different materials is developed by considering the chemical bonding contribution based on the thermodynamic expressions and the structure strain contribution based on the mechanical characteristics. The interface energy decreases with reducing thickness of thin films, and is determined by such available thermodynamic and mechanical parameters as the melting entropy, the melting enthalpy, the shear modulus of two materials, etc. The predicted interface energies of some metal/MgO and metal/Al2O3 interfaces based on the model are consistent with the results based on the molecular mechanics calculation. Furthermore, the interface fracture properties of Ag/MgO and Ni/Al2O3 based on the atomistic simulation are further compared with each other. The fracture strength and the toughness of the interface with the smaller structure interface energy are both found to be lower. The intrinsic relations among the interface energy, the interface strength, and the fracture toughness are discussed by introducing the related interface potential and the interface stress. The microscopic interface fracture toughness is found to equal the structure interface energy in nanoscale, and the microscopic fracture strength is proportional to the fracture toughness. (C) 2010 American Institute of Physics. [doi:10.1063/1.3501090]

Dynamics of morphological changes for mitochondrial fission and fusion

Mitochondria experience continuous fusion and fission in a living cell, but their dynamics remains poorly quantified. Here a theoretical model was developed, upon a simplified population balance equation (PBE), to predict the morphological changes induced by mitochondrial fission and fusion. Assuming that both fission and fusion events are statistically independent, the survival probability of mitochondria staying in the fission or fusion state was formulated as an exponentially-decayed function with time, which depended on the time-dependent distribution of the mitochondrial volume and the fission and fusion rates. Parametric analysis was done for two typical volume distributions. One was Gamma distribution and the other was Gaussian distribution, derived from the measurements of volume distribution for individual mitochondria in a living cell and purified mitochondria in vitro. The predictions indicated that the survival probability strongly depended on morphological changes of individual mitochondria and was inversely correlated to the fission and fusion rates. This work provided a new insight into quantifying the mitochondrial dynamics via monitoring the evolution of the mitochondrial volume.

Modeling and optimization for separation of ionic solutes in pressurized flow capillary electrochromatography

By manipulation of applied pressure or voltage, pressurized flow capillary electrochromatography (P-CEC) permits unique control of selectivity for ionic solutes. A simple mathematical model has been developed to describe the quantitative relationship between the electrochromatographic retention factor (k(*)) of charged solutes and the applied voltage and pressure. The validity of the model was verified experimentally with hydrophilic interaction mode CEC (HI-CEC). On the basis of the model developed, it was found that the value of k(*) could be predicted accurately using only a limited number of data points from the initial experiments at different voltages or pressures. Correlation between the experimentally measured and calculated k(*) was excellent, with a correlation coefficient greater than 0.999. Optimization for the separation of peptides by P-CEC was also performed successfully on the basis of the proposed model.

Collisional quantum interference effect on rotational energy transfer in an atom-diatom system

The theoretical model of collisional quantum interference (CQI) in intramolecular rotational energy transfer is described in an atom-diatom system, based on the first Born approximation of time-dependent perturbation theory and considering a long-range interaction potential. The relation between differential and integral interference angles is obtained. For the CO A(1)Pi (v = 0)/e(3)Sigma (-)(v = 1)-He collision system, the calculated integral interference angles are consistent with the experimental values. The physical significance of interference angle and the essential factors it depends on as well as the influence of the short-range interaction on CQI are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

Transient state of chiral recognition in a binary mixture of cyclodextrins in capillary electrophoresis

The transient state (as the defined point where no enantioseparation is obtained in a dual chiral selector system) of chiral recognition of aminoglutethimide in a binary mixture of neutral cyclodextrins (CDs) was studied by capillary electrophoresis (CE). The following three dual selector systems were used: alpha-cyclodextrin (alpha-CD) and beta-cyclodextrin (beta-CD); alpha-CD and heptakis(di-O-methyl-beta-cyclodextrin) (DM-beta-CD); alpha-CD and heptakis(tri-O-methyl-beta-cyclodextrin) (TM-beta-CD). The S-(-) enantiomer of the analyte was more strongly retained in the presence of either alpha-CD or TM-beta-CD at pH 2.5, 100 mM phosphate buffer, while the R-(+) enantiomer was more strongly retained in the presence of either P-CD or DM-P-CD. In the more simple case, the elution order is invariably kept if the enantiomers have the same elution order in either one of the two hosts of the binary mixture. In contrast, the elution order may be switched by varying the concentration ratio of two hosts that produce opposite elution order for this particular analyte. In such a dual selector system, the enantioselectivity will disappear at the transient state at a certain ratio of host,:host, Moreover, the migration times of the two enantiomers with host, alone (diluted in buffer) is approximately equal to the migration times at the corresponding concentration of host, alone (diluted in buffer), where the ratio of concentrations of host,:host, is the same as in the binary mixture at the transient state. As found by nuclear magnetic resonance experiments, the analyte is forming a 1:1 complex with either one of the CDs applied. From this finding, a theoretical model based on the mobility difference of the two enantiomers was derived that was used to simulate the transient state. (C) 2000 Elsevier Science B.V. All rights reserved.

水分和氮磷水平对小麦碳同位素分辨率和水分利用效率的影响

依据盆栽试验数据 ,利用植物稳定性碳同位素分辨率的理论模型 ,研究了水分和氮磷营养对小麦叶片碳同位素分辨率 (Carbon- isotope discriminationΔ)的影响。结果表明 :水分差异引起碳同位素分辨率较大变异 ,碳同位素分辨率随土壤相对含水量 (Soil relative water content)的提高而提高 ,在土壤相对含水量为 6 0 %～ 70 %条件下碳同位素分辨率最高。缺水时磷水平提高 ,碳同位素分辨率提高。水分利用效率 (Water use efficiency)与碳同位素分辨率关系受土壤水分和养分水平的影响。缺水条件下水分利用效率与碳同位素分辨率之间为负相关 ,充分供水下为正相关 ;在低氮水平下的关系不明显 ,施氮 15 0 kg· hm- 2时相关性显著。

The application of the MPB4 theory to the interface between between two immiscible electrolyte solutions .4. The differential capacitance of the water/nitrobenzene interface in the presence of 2:2 electrolyte

We have developed a new theoretical model based on the MPB4 theory to calculate the differential capacitance of the interface of 0.05mol/L MgSO4 in water and 0.1mol/L TBATPB in nitrobenzene. Our results coincide with the experimental values very well. It indicates that our model may describe well the structure of ITIES not only in the presence of 1:1 electrolyte but also in the presence of 2:2 electrolyte.

Kinetics of electrocatalytic ascorbic acid at ultramicroelectrode modified by Eastman-AQ polymer containing tris(2,2-'-bipyridine) osmium(III/II) complexes as electron-transfer centers

The theoretical model[17] of an ultramicroelectrode modified with a redox species film is used as the diagnostic tool to characterize the catalytic oxidation of ascorbic acid at carbon fiber ultramicrodisk electrodes coated with an Eastman-AQ-Os(bpy)(3)(2+) film. The electrocatalytic behavior of ascorbic acid at the ultramicroelectrode modified by an Eastman-AQ polymer containing tris(2,2'-bipyridine) osmium(III/II) as mediators is described. In order to determine the five characteristic currents quantitatively, the radius of the ultramicroelectrode and the concentration of ascorbic acid are varied systematically. The kinetic zone diagram has been used to study the electrocatalytic system. This system with 0.5-2.75 mM ascorbic acid belongs to SR + E case, and the concentration profiles of the catalyst in the film are given in detail. Finally, optimizing the design of catalytic system is discussed.

Effective properties of graded elliptical cylindrical composites

The effective property has been investigated theoretically in graded elliptical cylindrical composite's consisting of inhomogeneous graded elliptical cylinders and an isotropic matrix under external uniform electric field. As a theoretical model, the dielectric gradient profile in the elliptical cylinder is modeled by a power-law function of short semi-axis variable parameter (xi(2) - 1) in the elliptical cylindrical coordinates, namely epsilon(i)(xi) = c(k) (xi(2) - 1)(k), where c(k) and k are the parameters, and xi is the long semi-axis space variable in an elliptical cylindrical inclusion region. In the dilute limit, the local analytical potentials in inclusion and matrix regions are derived exactly by means of the hyper-geometric function, and the formulas are given for estimating the effective dielectric responses under the external lfield along (x) over cap- and (y) over cap -directions, respectively. Furthermore, we have demonstrated that our effective response formulas can be reduced to the well-known results of homogeneous isotropic elliptical cylindrical composites if we take the limit k -> 0 in graded elliptical cylindrical composites. (c) 2006 Elsevier B.V. All rights reserved.

渤海湾盆地济阳坳陷东部走滑构造特征及其对油气成藏的影响研究

研究区位于郯庐断裂中段与济阳坳陷的构造结合部，区内走滑构造广泛发育，主要的走滑断裂有7条，分别是郯庐断裂带的东西两支、垦东断层、孤东断层、长堤断层、埕东断层和发育于垦东凸起中部的浅层走滑构造带。走滑构造带与油气富集带有着明显的对应关系。 通过对研究区内二维、三维地震测线和平面构造图的精细解释和分析，分别揭示了各走滑断裂在平面、剖面和三维空间上的构造形态。根据走滑断裂及其伴生构造的平面和剖面上的几何学特征，将研究区内的走滑断裂划分为三种类型：成熟型走滑断裂、隐伏型走滑断裂、不连续型的走滑断裂。 从理论模式研究入手，推导了拉分盆地中盆地的走滑速率与沉降速率之间的关系，证实了走滑速率同盆地的几何形状参数、最大沉降深度和盆地的沉降速率存在着稳定的数值关系。通过对莱州湾地区潍北凹陷基底沉降历史的分析，建立了潍北凹陷沉降速率与郯庐断裂中段走滑速率之间的经验关系式，进而求出郯庐断裂中段新生代右行走滑位移量的大小为40km。 运用2DMove软件，对研究区内四条典型剖面进行构造复原，计算出了各条剖面每个时期的伸展参数，对研究区构造活动强度进行了定量分析，揭示了研究区的构造演化规律。通过运用Ansys软件进行有限元模拟，恢复了晚白垩世晚期-古近纪早期研究区内的构造应力场和应变场，揭示了扭张作用是研究区内走滑断层开始走滑的主要原因。 通过上述分析，结合对究区内近几年勘探开发成功和失败的实例分析，全面探讨了走滑活动对于油气成藏“生”、“储”、“盖”、“圈”、“运”、“保”各因素的影响。

Clay surface modification and its coagulation of red tide organisms

Surface modification of montmorillonite by means of Mg2+ insertion reaction has been studied and a positively charged montmorillonite has been prepared. The effects of preparation temperature and Mg2+ concentration on the positive charge property of the clay and on the clay coagulating Heterosigma akashiwo have been studied. The results showed that the modified clay enhanced the coagulation and the used amount decreased to 1/5-1/10 of the original. The removal rates of Heterosigma akashiwo were correlated positively with positive charge on the clay in accordance with theoretical model.

面向CNT基纳米器件的DEP装配实验研究

碳纳米管(Carbon nanotube,CNT)由于独特的纳米结构以及优异的物理、化学特性,在纳米器件领域具有广阔的应用前景。有效的CNT的操控与装配方法对于其在上述领域的研究应用是至关重要的。为此,本文在分析非均匀电场条件下CNT所受介电泳(Dielectrophoresis,DEP)力模型的基础上,构建了基于DEP力的CNT装配实验系统。本文进行了多壁碳纳米管(MWNTs)的装配实验;并测试了MWCNTs束的电特性。

波动方程模拟与偏移的实用化方法研究

Along with the widespread and in-depth applications in petroleum prospecting and development, the seismic modeling and migration technologies are proposed with a higher requirement by oil industrial, and the related practical demand is getting more and more urgent. Based on theories of modeling and migration methods for wave equation, both related with velocity model, I thoroughly research and develop some methods for the goal of highly effective and practical in this dissertation. In the first part, this dissertation probes into the layout designing by wave equations modeling, focusing on the target-oriented layout designing method guided by wave equation modeling in complicated structure areas. It is implemented by using the fourth order staggered grid finite difference (FD) method in velocity-stress 2D acoustic wave equations plus perfectly matched layer (PML) absorbing boundary condition. To design target-oriented layout: (a) match the synthetic record on the surface with events of subsurface structures by analyzing the snapshots of theoretical model; (b) determine the shot-gather distance by tracking the events of target areas and measuring the receiving range when it reaches the surface; (c) restrict the range of valid shot-gather distance by drawing seismic windows in single shot records; (d) choose the best trace distance by comparing the resolution of prospecting targets from the simulated records with different trace distance. Eventually, we obtained the observation system parameters, which achieve the design requirements. In the second part, this dissertation presents the practical method to improve the 3D Fourier Finite Difference (FFD) migration, and carefully analyzes all the factors which influence 3D FFD migration’s efficiency. In which, one of the most important parameters of migration is the extrapolating step. This dissertation presents an efficient 3D FFD migration algorithm, which use FFD propagator to extrapolate wavefields over big layers, and use Born-Kirchhoff interpolator to image wavefields over small layers between the big ones. Finally, I show the effectiveness of this hybrid migration method by comparing migration results from 3D SEG/EAGE model with different methods.