Study of n=2, Delta n=0 transition of Be-, B-, C-, N- and O-like sequence in the beam-foil spectrum of titanium

The foil-excited the spectrum of highly stripped titanium ions between 12-40 nm has been studied. Titanium ions of 80 and 120 MeV were provided by the HI-13 tandem accelerator at the China Institute of Atomic Energy. GIM-957 XUV-VUV monochromator was refocused to get highly-resolved spectra. Our experimental results and the published spectral data of laser-produced plasma show agreement in nearly all cases within +/- 0.03 nm. The spectra contained some weak or strong lines previously unclassified. These spectral lines mainly belong to 2s2p(2) for TiXVIII, 2p(3) for TiXVIII, 2s2p(3) for TiXVII, 2p(6)4p for Ti XII and 2p(6)3d for Ti XII transitions.

Multi-electron processes in C-13(6+) ions with neon collisions in energy region 4.15-11.08 keV/u

The cross-section ratios of double-, triple-, quadruple-, and the total multi-electron processes to the single electron capture process sigma(DE)/sigma(SC), sigma(TE)/sigma(SC), sigma(QE)/sigma(SC) and sigma(ME)/sigma(SC)) as well as the relative ratios among reaction channels in double-electron active, triple-electron active and quadruple- electron active are measured in C-13(6+) -Ne collision in the energy region of 4.15-11.08 keV/u by employing position-sensitive and time-of-flight coincident techniques. It is determined that the cross-section ratios sigma(DE)/sigma(SC), sigma(TE)/sigma(SC), sigma(QE)/sigma(SC) and sigma(ME)/sigma(SC) are approximately the constants of 0.20 +/- 0.03, 0.16 +/- 0.04, 0.06 +/- 0.02 and 0.42 +/- 0.05. These values are obviously smaller than the predictions of the molecular Coulomb over-the-barrier model (MCBM) [J. Phys. B 23 (1990) 4293], the extended classical over-the-barrier model (ECBM) [J. Phys. B 19 (1986) 2925] and the semiempirical scaling laws (SL) [Phys. Rev. A 54 (1996) 4127]. However, the relative ratios among partial processes of DE, TE and QE are found to depend on collision energy, which suggests that the collision dynamics depends on the collision velocity. The limitation of velocity-independent character of ECBM, MCBM and SL is undoubtedly shown.

Shell effect on stabilization processes following multi-electron transfer in slow Arq+-Ar (g=6-9, 11) collisions

We experimentally investigate the shell effect on the stabilization processes following the multi-electron transfer in slow collisions of Arq+-Ar (q = 6-9, It) The relative cross-section ratios of multi-electron transfer and of the subsequent stabilization with respect to single-electron capture are measured meanwhile compared with the theoretical results predicted by the classical over-barrier model. Our result indicates that the multi-electron transfer is dominant when the projectile charge is large and the subsequent stabilization shows a dramatic variation if the projectile L-shell configuration becomes open. It shows that the subsequent stabilization processes of multiply excited scattering ions have a strong dependence on the projectile shell. (C) 2010 Elsevier BV All rights reserved.

Measurement of the total reaction cross section for the mirror nuclei N-12 and B-12

The mirror nuclei N-12 and B-12 are separated by the Radioactive Ion Beam Line in Lanzhou (RIBLL) at HIRFL from the breakup of 78.6 MeV/u N-14 on a Be target. The total reaction cross-sections of N-12 at 34.9 MeV/u and B-12 at 54.4 MeV/u on a Si target have been measured by using the transmission method. Assuming N-12 consists of a C-11 core plus one halo proton, the excitation function of N-12 and B-12 on a Si target and a C target were calculated with the Glauber model. It can fit the experimental data very well. The characteristic halo structure for N-12 was found with a large diffusion of the protons density distribution.

丰中子新核素238Th的合成、鉴别和230Ac b 延发裂变的观测

新核素的合成及衰变性质的研究一直是核物理科学的前沿领域，它对于人类拓广对原子核运动规律的认识有着十分重要的意义。本文首先概述了新核素合成的意义、方法，并简要阐述了一种奇异的衰变方式—β~-延发裂变，为实验部分的论述提供理论基础。在实验部分，本文阐述了用放射化学方法研究了钍、钡、镭等复杂反应产物的化学分离。通过在Th的分离中引用PMBP萃取和反萃体系，并采用氧化还原体系有效地去除了绝大多数杂质元素，特别是非常好的去除了碘和溴离子的沾污，较好地完成了Th与其它反应产物的分离。对Ba、Ra的分离主要采用快速的阳离子交换流程，达到了满意的分离效果。对用中能~(18)O离子束照射铀、钍的反应产物进行分离，对分离出的钍、钡、镭样品进行了γ（X）单谱和时间序列谱测量。并对记录下来的样品的谱图进行了分析。使用上述方法，我们在兰州重离子加速器（HIRFL）上用~(18)O离子照射重铀酸铵靶，通过多核子转移反应，首次合成并鉴别了新核素不相识~(238)Th。 同时通过不同的反应道产生~(237)Th，并对~(237)Th的半衰期进行了测定；在HIRFL上用~(18)O离子照射氧化钍靶对~(230)Ra的子体~(230)Ac的β~-延发裂变现象进行了观测，在被Ra样品爆光的云母径迹探测器上观察到了两个裂变径迹，从ThO_2靶中用三次BaCl_2沉淀法分离出钡、使用γ谱学这技术测定了十多个Ba的放射性同位素的截面。

230Ac的 b 延发裂变的观测及新核素合成

第一部分：β延发裂变（βDF）是一种稀有的核衰变模式,它在天体物理学和研究中具有重要价值;为研究远离β稳定线核素提供了可能性,是研究新核素合成的新台阶.第二部分：采用放射化学分离法从中能<'18>O离子辐照过的天然铀靶以及钍靶中分离出放射性Ba同位素,用高分辨的HPGe探测器测量Ba部分的γ射线谱,对测得的时间累计谱进行分析,用常规的计算产额生成截面的方法得到了Ba同位素的生成截面,并对其中的一些截面数据进行了讨论.第三部分：在中子发生器上用14-15MeV的中子轰击天然白金箔,通过<'198>Pt(n,2p）反应产生<'197>Os.使用两台HPGe探测器做γ（X）单谱和X-γ-t符合测量.对测得的数据进行了分析,结果显示我们合成并鉴定了新丰中子同位素<'197>Os,确定它的半衰期为2.8±0.5min.第四部分：用<'133>Ba作示踪剂对Ba在不锈钢片上的分子镀进行了研究.对在异丙醇溶液中的影响Ba分子镀的因素：电镀时间和电流密度等做了条件实验.在电流密度为4.0～6.0mA/cm<'2>,沉积时间30min的实验条件下,可在不锈钢片上获得厚度为0.5～1.0mg/cm<'2>的Ba镀层,也确定了Ba的电镀效率.

20Na、23Al、24Si的b＋缓发粒子发射及相关的天体反应率的实验研究

以兰州放射性束流线装置(RIBLL)为依托,利用弹核碎裂机制产生了远离稳定线的核素,通过研究一些放射性核素<'20>Na、<'23>Al、<'24>Si的β<'+>缓发粒子特性,并结合核结构的测量,初步研究了<'16>O(α,γ)<'20>Ne、<'22>Na(p,γ)<'23>Mg以及<'23>Mg(p,γ)<'24>Al反应.实验测量到了β<'+>缓发母核(先驱核)的半衰期,缓发粒子的能谱和相对强度,并根据壳模型计算指定了部分激发能级的自旋,进而得到了它们的相对共振强度以及热核反应率等.通过实验,我们测量了5.627,5.788,6.725MeV等几个<'20>Ne<'*>的低能缓发α粒子能级,得到<'20>Na的其半衰期T<,1/2>=459±7ms,给出了10.584MeV和10.843MeV的两个能级的相对共振强度分别为0.59eV、1.2eV,计算了其直接俘获的贡献和低能共振态对反应率的贡献;对于<'22>Na(p,γ)<'23>Mg反应,我们重点测量了<'23>Mg的靠近<'22>Na+p俘获阈附近的能级,将探测器的探测阈降低到了200KeV左右,并新发现了一条激发能级具有缓发质子的特性,其能量为8.916MeV(衰变质子能量为1.337MeV),为了验证测量结果的准确性,我们进行了第二次测量,结果证实了8.916MeV及9.598MeV能级具有缓发质子特性,其中9.598MeV能级的缓发质子在2000年被K.Perajarvi等发现,并又新测量到了能量为8.990,9.060,9.138,9.374MeV的四个能级也存在缓发质子特性.实验得到<'24>Si的衰变半衰期为104±10ms,第一次测量到<'24>Mg低能的几个衰变质子谱线,它们在天体物理中具有重要的作用.

UV-B辐射增强对长白山五种藓类植物生长的影响

对生长在中国长白山的5种藓类植物——垂枝藓、拟垂枝藓、塔藓、星塔藓和高山金发藓分别以辐射强度为0.2(自然光照,对照)、3.0(紫外线中等辐射强度)和6.0kJ.m-2.d-1(高剂量辐射强度)的UV-B照射40d后,测定其株高、生物量及叶绿素含量.结果表明:中等和高强度的UV-B辐射使拟垂枝藓和塔藓的株高、生物量和叶绿素含量分别下降了32.3%、62.4%、81.3%和21.4%、59.4%、62.8%,其相对生长速率均为负值;高剂量UV-B辐射处理下垂枝藓的生物量稍有上升,而高山金发藓地下部分的生物量增加1倍,但叶绿素含量变化不明显.高山金发藓和垂枝藓抵抗UV-B辐射的能力较强,拟垂枝藓和塔藓对UV-B辐射较敏感.

Bulk ultrafine binderless (W0.4Al0.6)C prepared by high pressure sintering

Pure (W0.4Al0.6)C powder of about 1 mu m in diameter was sintered by the high pressure sintering (HPS) process without the addition of any binder phase. The microstructure, Vickers micro hardness and density versus the sintering time and temperature are well described. The most suitable sintering condition under pressure of 4.5 GPa is 1873 K for 8 min. Under this sintering condition, the hardness can reach 2295 kg mm(-2) and the relative density can reach 98.6%.

利用MALDI-TOF质谱技术研究MPEG-b-PCL两嵌段共聚物的嵌段长度及嵌段分布

利用基质辅助激光解吸电离飞行时间质谱(MALDI-TOFMS)结合源后分解(PSD)技术对甲氧基封端的聚乙二醇-b-聚己内酯(MPEG-b-PCL)两嵌段共聚物进行了结构分析.根据得到的MALDI-TOFMS谱图和PSD碎片信息清晰地确定了嵌段共聚物的嵌段长度和嵌段分布.结果表明,采用MALDI-TOFMS结合PSD技术研究这类嵌段共聚物链结构非常有效.这为更好地认识和应用这类嵌段共聚物提供了重要的依据,同时也建立了分析这类嵌段共聚物的方法.

Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound

A novel supramolecular compound 1,6-hexanediamine trimolybdate ((C6H18N2[Mo3O10], denoted as HDAMo) has been synthesized by a hydrothermal method and its structure has been characterized by elemental analyses, Fourier transform infrared (FT-IR) spectra, single-crystal X-ray diffraction (XRD) technique. This single crystal compound consists of protonated 1,6-hexanediamine (HDA) cations and polyoxometalate [Mo3O10](2-) anions. Its crystal structure belongs to monoclinic system (space group P2(1)/n) with a = 7.7508(14), b = 11.467(2), c = 16.167(3) angstrom, beta = 92.689(3)degrees, V = 143 5.3(5) angstrom(3), Z = 4 and D-ealc = 2.619 g cm(-3). The final statistics based on F-2 are GOF = 0.980, R-1 = 0.0261 and wR(2) = 0.0506 for I > 2 sigma(I). XRD analysis revealed that in the crystal structure of HDAMo, novel infinite [Mo3O10](2-) chains parallel to a axis are made up of distorted MoO6 octahedra connected by corners and edges. The protonated HDA cations occupy channels formed by [Mo(3)O3(10)](2-) Chains and exhibit strong hydrogen bond interactions to terminal and bridging oxo groups of the chains. The [Mo3O10](2-) chains linked through protonated HAD cations formed a one-dimensional network. The HDAMo compound shows novel photochromic properties, i.e., its color changes from white to reddish brown gradually under UV irradiation. XRD, FT-IR, ESR spectra and XPS are used to investigate the photochromic behavior of the compound.

Efficient synthesis of substituted tetrahydrothiopyrano[2,3-b]thiopyran-4,5-diones by a double annulation strategy from dialkenoylketene dithioacetals

An efficient synthetic procedure for substituted 2,3,6,7tetrahydrothiopyrano [2,3-b] thiopyran-4,5 -diones by a double annulation strategy is described. The ring systems are made in good yields from readily available dialkenoylketene dithioacetals in the presence of either sodium sulfide nonahydrate/N,N-dimethylformamide (DMF) or a sodium hydride/DMF/amine system.

The study of synthesis of poly(ethylene oxide)-b-poly(N,N-dimethylacrylamide) by atom transfer radical polymerization and self-assembly in selective solvents

Poly( ethylene oxide)-b-poly(N, N-dimethylacrylamide) (PEO-b-PDMA) was synthesized by successive atom transfer radical polymerization (ATRP) of N, N-dimethylacrylamide (DMA) monomer using PEO-Br macro initiators as initiator, CuBr and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazamacrocyclotetra decane (Me-6[14] aneN(4)) as catalyst and ligand. PEO-Br macroinitiator was synthesized by esterification of PEO with 2-bromoisobutyryl bromide. GPC and H-1 NMR studies show that the plot of ln([DMA](0)/[ DMA]) against the reaction time is linear, and the molecular weight of the resulting PDMA increased linearly with the conversion. Within 3 h, the polymerization can reach almost 60% of conversion. PEO-b-PDMA copolymer with low polydispersity index (M-w/M-n approximate to 1.1) is obtained. Self-assembly of PEO-b-PDMA in selective solvents is also studied. It could self-assemble into micelles in methanol/acetone (1/10, v/v) solution. TEM analyses of the PEO-b-PDMA micelles with narrow size distribution revealed that their size and shape depend much on the copolymer composition.

Structure characterization and physical properties of a complex with supramolecular architectures Co-2(2,6-DPC2Co(H2O)5 center dot 2H(2)O (DPC=2,6-pyridinedicarboxylate)

Reaction of 2,6-pyridinedicarboxylic with CoCl2 . 6H(2)O in aqueous solution give rise to a three-dimensional Complex CO2(2,6-DPC)(2)Co(H2O)(5).2H(2)O (DPC = 2,6-pyridinedicarboxylate) 1. It has been characterized by elemental analyses, infrared spectra (IR) spectrum, thermogravimetric (TG) analysis, EPR spectrum, and single crystal X-ray diffraction. The complex crystallizes in the P2(1)/c space group with a = 8.3906(3) Angstrom, b = 27.4005(8) Angstrom, c = 9.6192(4) A, alpha = 90.00degrees, beta = 98.327(2)degrees, gamma = 90.00degrees, V = 2188.20(14) Angstrom(3), Z = 4. There are two types of cobalt environments: Co(1) is coordinated by four oxygen atoms from four carboxyl groups and two nitrogen 2 atoms which are all from pdc(2). Co(2) is coordinated by six oxygen atoms, five from coordinated water molecules and one from a carboxyl of pdc(2) - of which the other oxygen atom is linked to the Co(1). The extensive intermolecular hydrogen bonds are formed in the crystal by means of the five coordinated water molecules.

Electropolymerization of azure B on a screen-printed carbon electrode and its application to the determination of NADH in a flow injection analysis system

The electrooxidation polymerization of azure B on screen-printed carbon electrodes in neutral phosphate buffer was studied. The poly(azure B) modified electrodes exhibited excellent electrocatalysis and stability for dihydronicotinamide adenine dinucleotide (NADH) oxidation in phosphate buffer (pH 6.9), with an overpotential of more than 400 mV lower than that at the bare electrodes. Different techniques, including cyclic voltammetry, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy have been employed to characterize the poly (azure B) film. Furthermore, the modified screen-printed carbon electrodes were found to be promising as an amperometric detector for the flow injection analysis (FIA) of NADH, typically with a dynamic range of 0.5 muM to 100 muM.